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材料导报  2019, Vol. 33 Issue (Z2): 584-589    
  高分子与聚合物基复合材料 |
烟炱对MoDDP和MoDTC减摩性能的影响
苏鹏, 熊云, 范林君, 李泽振
陆军勤务学院油料系,重庆 401311
Effect of Diesel Soot on Anti-friction Performance of MoDDP and MoDTC
SU Peng, XIONG Yun, FAN Linjun, LI Zezhen
Department of Oil Engineering, Army Logistic University of PLA, Chongqing 401311
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摘要 在SRV IV摩擦磨损试验机上,采用球-盘接触方法,考察了烟炱对二烷基二硫代磷酸钼(MoDDP)和二烷基二硫代氨基甲酸钼(MoDTC)减摩性能的影响,借助扫描电子显微镜及能谱仪(SEM/EDX)、X射线光电子能谱仪等分析手段,探讨了烟炱对两种有机钼减摩剂减摩性能影响的原因。结果表明,烟炱会降低MoDDP和MoDTC的减摩效果,使其减摩效果不稳定。对比两者在含烟炱柴油机油中的减摩效果发现,MoDTC优于MoDDP。烟炱对两种有机钼减摩剂减摩性能影响的原因为:一是烟炱会刮擦破坏摩擦副表面的反应膜;二是烟炱改变了两种减摩剂的摩擦化学反应,生成了含Mo-C类物质。
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苏鹏
熊云
范林君
李泽振
关键词:  烟炱  减摩性能  MoDDP  MoDTC  反应膜    
Abstract: The anti-friction of two kinds of organo-molybdenum friction modifier MoDDP and MoDTC were investigated by using ball-disc reciprocating mode on the SRV IV oscillating reciprocating friction and wear tester. The scanning electron microscopy/energy-dispersive X-ray detector (SEM/EDX), X-ray photoelectron spectroscopy (XPS) were used to probe the mechanism that diesel soot made the organo-molybdenum friction modifier efficiency. Results indicate that, diesel soot could significantly reduce the anti-friction property of MoDDP and MoDTC, making its anti-friction property unstable. Comparing the friction reduction effect of the two friction modifier in soot-contained diesel engine oil, MoDTC is supe-rior to MoDDP. The reason for the effect of diesel soot on anti-friction performance of the two kinds of organic molybdenum friction modifier is that:firstly, the soot will scrape the reaction film and destroy the surface of the friction pair; secondly, the soot changes the tribochemical reaction of the two antifriction agents, resulting in the formation of substances contained Mo-C.
Key words:  diesel soot    anti-friction property    MoDDP    MoDTC    reaction film
               出版日期:  2019-11-25      发布日期:  2019-11-25
ZTFLH:  TH117  
基金资助: 全军后勤科研计划重点项目(BX214C006);重庆高校优秀成果转化资助项目(KJZH17139)
通讯作者:  xy0000001@sina.cn   
作者简介:  苏鹏,2018年6月毕业于中国人民解放军陆军勤务学院,获得工学博士学位。主要从事润滑油添加剂、摩擦化学方面的研究。
熊云,陆军勤务学院,教授。主要从事油品应用研究。
引用本文:    
苏鹏, 熊云, 范林君, 李泽振. 烟炱对MoDDP和MoDTC减摩性能的影响[J]. 材料导报, 2019, 33(Z2): 584-589.
SU Peng, XIONG Yun, FAN Linjun, LI Zezhen. Effect of Diesel Soot on Anti-friction Performance of MoDDP and MoDTC. Materials Reports, 2019, 33(Z2): 584-589.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2019/V33/IZ2/584
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