高分子与聚合物基复合材料
|
氧化铁增强二氧化硅补强天然橡胶的性能与机理
刘宏超,王启方,梁志雄,汪月琼,彭政,余和平
中国热带农业科学院农产品加工研究所,农业农村部热带作物产品加工重点实验室,湛江 524001
Properties and Mechanism of Fe2 O3 Strengthening SiO2 Reinforced Natural Rubber
LIU Hongchao, WANG Qifang, LIANG Zhixiong, WANG Yueqiong, PENG Zheng, YU Heping
Key Laboratory of Tropical Crop Products Processing of Ministry of Agriculture and Rural Affairs, Agricultural Products Processing Research Institute of Chinese Academy of Tropical Agricultural Sciences, Zhanjiang 524001
摘要 为了研究砖红壤对天然橡胶特有的补强作用机理,模拟砖红壤的主要成分和比例,将不同添加量的SiO2 、Fe2 O3 和Al2 O3 经混合、研磨及高温烧结等工序制成混合粉体作为橡胶补强剂,并通过混炼加入天然橡胶中,考察砖红壤中对天然橡胶产生补强作用的主要成分和机理。结果表明,在有Fe2 O3 存在的混合料中,天然橡胶的补强效果明显,且随着Fe2 O3 的比例增大,硫化胶的拉伸强度和撕裂强度增大,补强效果逐渐加强。
关键词:
砖红壤
氧化铁
天然橡胶
补强作用
Abstract: In order to research the reinforcing mechanism of latosol on natural rubber, the main composition and proportion of latosol were simulated. The mixed powders of SiO2 , Fe2 O3 and Al2 O3 were prepared by mixing, grinding and high-temperature sintering. The mixed powders were added into rubber as reinforcing agents to investigate the main components and reinforcing mechanism of latosol. The results show that the reinforcement effect of natural rubber is obvious with the mixed powers contain Fe2 O3 , and the reinforcement effect is gradually strengthened with the increasing proportion of Fe2 O3 .
Key words:
latosol
Fe2 O3
natural rubber
reinforcement
出版日期: 2019-11-25
发布日期: 2019-09-16
基金资助: 海南省自然科学基金(518QN287)
作者简介: 刘宏超,中国热带农业科学院农产品加工研究所助理研究员。2010年6月,获得广东海洋大学工学硕士学位,毕业后于现单位工作,主要从事天然橡胶应用基础研究。 余和平, 1986年毕业于兰州大学化学系物理化学专业。现为中国热带农业科学院农产品加工研究所研究员,主要从事天然橡胶应用基础研究。
引用本文:
刘宏超, 王启方, 梁志雄, 汪月琼, 彭政, 余和平. 氧化铁增强二氧化硅补强天然橡胶的性能与机理[J]. 材料导报, 2019, 33(22): 3842-3846.
LIU Hongchao, WANG Qifang, LIANG Zhixiong, WANG Yueqiong, PENG Zheng, YU Heping. Properties and Mechanism of Fe2 O3 Strengthening SiO2 Reinforced Natural Rubber. Materials Reports, 2019, 33(22): 3842-3846.
链接本文:
http://www.mater-rep.com/CN/10.11896/cldb.18100005
或
http://www.mater-rep.com/CN/Y2019/V33/I22/3842
[1]
Stickney P B. Falb R D. Rubber Chemistry and Technology, 1964, 37(5), 1299.
[2]
Wolff S. Rubber Chemistry and Technology, 1996, 69(3), 325.
[3]
Watson W F. Industrial and Engineering Chemistry, 1955,47(6), 1281.
[4]
Wolff S. Kautschuk und Gummi Kunststoffe, 1981, 34(4), 280.
[5]
Brinke J W, Dehnath S C. Composites Science and Technology, 2003, 63(8), 1165.
[6]
Giger G. Lipongski M. Revue Generale du Caoutchouc, 1957, 34, 473.
[7]
Meng Qingyan, Li Zhiping, Deng Weiyong. China Rubber Industry, 1987, 34(4), 91(in Chinese).孟庆岩,黎志平,邓维用. 橡胶工业,1987,34(4),91.
[8]
Liu Hongchao, Wang Qifang, Zeng Zongqiang, et al. China Rubber Industry, 2013, 60(9), 537(in Chinese).刘宏超,王启方,曾宗强,等. 橡胶工业,2012,60(9),537.
[9]
Guan Junfang, Cheng Feifei, Chen Yang. Bulletin of the Chinese Cera-mic Society, 2014,33(4),720(in Chinese).管俊芳, 程飞飞, 陈阳.硅酸盐通报, 2014,33(4), 720.
[1]
Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells [J]. Materials Reports, 2018, 32(3): 337
-356
.
[2]
Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts [J]. Materials Reports, 2018, 32(3): 362
-367
.
[3]
Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials [J]. Materials Reports, 2018, 32(3): 368
-372
.
[4]
Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review [J]. Materials Reports, 2018, 32(3): 398
-404
.
[5]
Haoqi HU,Cheng XU,Lijing YANG,Henghua ZHANG,Zhenlun SONG. Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy [J]. Materials Reports, 2018, 32(3): 453
-460
.
[6]
Anmin LI,Junzuo SHI,Mingkuan XIE. Research Progress on Mechanical Properties of High Entropy Alloys [J]. Materials Reports, 2018, 32(3): 461
-466
.
[7]
Yongtao TAN, Lingbin KONG, Long KANG, Fen RAN. Construction of Nano-Au@PANI Yolk-shell Hollow Structure Electrode Material and Its Electrochemical Performance [J]. Materials Reports, 2018, 32(1): 47
-50
.
[8]
Guiqin HOU,Yunkai LI,Xiaoyan WANG. Research Progress of Zinc Ferrite as Photocatalyst [J]. Materials Reports, 2018, 32(1): 51
-57
.
[9]
Jing WANG,Hongke LIU,Pingsheng LIU,Li LI. Advances in Hydrogel Nanocomposites with High Mechanical Strength [J]. Materials Reports, 2018, 32(1): 67
-75
.
[10]
Xia WANG,Liping AN,Xiaotao ZHANG,Ximing WANG. Progress in Application of Porous Materials in VOCs Adsorption During Wood Drying [J]. Materials Reports, 2018, 32(1): 93
-101
.
Viewed
Full text
Abstract
Cited
Shared
Discussed