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材料导报  2022, Vol. 36 Issue (15): 21040122-5    https://doi.org/10.11896/cldb.21040122
  无机非金属及其复合材料 |
烧结温度对石棉矿山废石制备微晶玻璃析晶性能的影响
刘全1,2, 孙红娟1,2,*, 彭同江1,2,3, 王璨1,2
1 固体废物处理与资源化教育部重点实验室,四川 绵阳 621000
2 西南科技大学矿物材料与应用研究所,四川 绵阳 621000
3 西南科技大学分析测试中心,四川 绵阳 621000
Effect of Sintering Temperature on Crystallization Properties of Glass-ceramics Prepared from Asbestos Mine Waste Rock
LIU Quan1,2, SUN Hongjuan1,2,*, PENG Tongjiang1,2,3, WANG Can1,2
1 Key Laboratory of Solid Waste Treatment and Resource Recycle, Ministry of Education, Mianyang, 621000, Sichuan, China
2 Institute of Mineral Materials and Application, Southwest University of Science and Technology, Mianyang, 621000, Sichuan, China
3 Analytical and Testing Center, Southwest University of Science and Technology, Mianyang, 621000, Sichuan, China
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摘要 以大洪沟石棉矿山废石为原料,采用直接烧结法制备了以镁橄榄石为主晶相、顽火辉石为副晶相的微晶玻璃。采用多种现代分析测试手段,研究了烧结温度(1 150~1 325 ℃)对微晶玻璃析晶的晶相、显微结构及性能的影响。结果表明:随着烧结温度的升高,晶相种类不会受到影响,但含量会发生变化,顽火辉石的含量逐渐增加,镁橄榄石晶相的含量略微减少;微晶玻璃中的晶粒长大,晶粒间形成相互交织咬合的结构。所制备的微晶玻璃理化性能较优,在烧结温度为1 300 ℃时,其线收缩率、体积密度和抗折强度达到最大,分别为11.2%、2.78 g/cm3和95 MPa,吸水率最小,为0.03%。
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刘全
孙红娟
彭同江
王璨
关键词:  石棉矿山废石  微晶玻璃  直接烧结  镁橄榄石  顽火辉石    
Abstract: The glass-ceramics with forsterite as the main crystalline phase and enstatite as the secondary crystalline phase were prepared by direct sintering method using waste rock from Dahonggou asbestos mine as raw material. The effects of the sintering temperature (1 150—1 325 ℃) on the crystalline phase, microstructure and properties of crystallization of glass-ceramics were investigated by using various modern analytical testing methods. The results show that with the increase of sintering temperature, the type of crystalline phase is not affected, but the content changes. The content of enstatite gradually increases, and the content of forsterite slightly decreases; the grains in glass-ceramics grow up, and the interwoven occlusal structure is formed among the grains. The glass-ceramics prepared at the sintering temperature of 1 300 ℃ show the optimal physical and chemical properties, of which the linear shrinkage rate, the volume density and the flexural strength are the largest at 11.2%, 2.78 g/cm3 and 95 MPa, respectively,and the water absorption is the smallest at 0.03%.
Key words:  mine waste rock    glass-ceramic    direct sintering    forsterite    enstatite
出版日期:  2022-08-10      发布日期:  2022-08-15
ZTFLH:  X754  
基金资助: 国家重点研发项目(2018YFC1802902)
通讯作者:  *sunhongjuan@swust.edu.cn   
作者简介:  刘全,2019年7月毕业于绵阳师范学院,获得工学学士学位,现为西南科技大学环境与资源学院硕士研究生,在孙红娟教授的指导下进行研究。目前主要研究领域为工业固体废弃物资源化利用。
孙红娟,1995/09—1999/06 西南科技大学,环境与资源学院矿物岩石材料专业,本科/学士;2000/09—2002/12,西南科技大学,环境与资源学院矿产评查与勘探专业,研究生/硕士;2006/09—2011/06,四川大学,材料科学与工程学院纳米技术与纳米材料,研究生/博士。现任西南科技大学教授、博士研究生导师。中国矿物复合材料专业委员会委员,中国硅酸盐学会非金属矿分会理事,中国矿物岩石地球化学学会矿物材料专业委员会委员,中国地质学会矿物专业委员会委员,四川省纳米协会副理长。主要从事纳米矿物材料的制备及应用、石墨烯材料的制备与应用、固体废物资源化处理等研究。主持国家自然科学基金项目3项、省部级项目8项、企业合作项目25项等。在国内外知名学术刊物和学术会议上发表学术论文150余篇,其中EI、SCI收录80余篇,出版专著1部。
引用本文:    
刘全, 孙红娟, 彭同江, 王璨. 烧结温度对石棉矿山废石制备微晶玻璃析晶性能的影响[J]. 材料导报, 2022, 36(15): 21040122-5.
LIU Quan, SUN Hongjuan, PENG Tongjiang, WANG Can. Effect of Sintering Temperature on Crystallization Properties of Glass-ceramics Prepared from Asbestos Mine Waste Rock. Materials Reports, 2022, 36(15): 21040122-5.
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http://www.mater-rep.com/CN/10.11896/cldb.21040122  或          http://www.mater-rep.com/CN/Y2022/V36/I15/21040122
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