Effect of CuO Doping on Electrical Properties of YBCO Ceramics
ZHOU Hongming1,2, WANG Boyi1, LI Jian1,2, CHENG Minghui1
1 School of Materials Science and Engineering,Central South University,Changsha 410083 2 Hunan Zhengyuan Institute for Energy Storage Materials and Devices,Changsha 410083
Abstract: Based on traditional solid-phase sintering method, three elements, Y1Ba2Cu3O7-x(YBCO) ceramics as functional phase, glass powder as sintering aids and copper(Ⅱ) oxide (CuO) doping as dopant, can be made into the product—the CuO doped YBCO ceramics. Its microstructure, phase composition and electrical properties have been studied by SEM, XRD, EDS, micro ohm instrument and high temperature alternating humidity test chamber. The study has found that doping CuO can reduce the oxygen defects in the crystal structure of YBCO; as the CuO content increases from 0% to 3%, the ceramic density increases gradually while the resistivity decreases obviously; as the content of CuO is more than 3%, the ceramic density decreases gradually while the resistivity increases obviously; with the increase of CuO content, temperature coefficient of resistance (TCR) shifts from negative to positive gradually, and the TCR is becoming smaller and smaller; when the doping amount of CuO is 3%, the sample has the best comprehensive electrical properties—the resistivity is 1.55×10-4 Ω·m and the resistance temperature coefficient is -1 470×10-6 /℃.
1 Iida K, Badu N H, Shi Y, et al. Superconductor Science Technology,2005,18(11),1421. 2 Wei Bo, Lv Zhe, Huang Xiqiang, et al. Journal of the Europen Society,2006,26(13),2827. 3 Yang Deli. The molecular sieve and oxygen permeation membrane stu-dies—The fundamental studies on oxygen diffusioon characteristics, application, substitituton and doping of Y1Ba2Cu3O7-x.Ph. D. thesis, Zhengzhou University,China,2003(in Chinese). 杨德利.Y1Ba2Cu3O7-x氧扩散特性、应用及掺杂替代的基础研究—分子筛透氧膜研究.博士学位论文,郑州大学,2003. 4 Takenaka T, Nagata H, Hiruma Y, et al. Journal Electroceramics,2007,19(4),259. 5 Cooper J R, Obertelli S D, CarringtonA, et al. Physical Review B,1991,44,12086. 6 Awana V P S, Malik S K, Yelon W B. Physica C Superconductivity,1996,262(3-4),272. 7 Hsiang H, Fan L,Cheng H. Journal of Alloys and Compounds,2015,650,835. 8 Qin J, Zhang W, Liu Z, er al.International Journal of Modern Physics B,2015,29(10),1540027. 9 Zhang Feijin, Zhu Xiaoyun. Materials Review A: Review papers,2013,14(2),81(in Chinese). 张飞进,朱晓云.材料导报:综述篇,2013,14(2),81. 10 Kanoun O. IEEE Transactions on Instrumentation and Measurement,2000,49(4),901. 11 Hu Junsui, Tang Zhenlan, Du Yongguo, et al. Precious Metals,2007,28(2),1(in Chinese). 胡君遂,唐珍兰,堵永国,等.贵金属,2007,28(2),1. 12 Du Yongguo, Zhang Weijun, Hu Junsui, et al. Hybrid Microelectronic Technology,2003,14(3),109(in Chinese). 堵永国,张为军,胡君遂,等.混合微电技术,2003,14(3),109. 13 堵永国,张为军,李刚,等.中国,02139895.X,2005. 14 李旭琼,骆颖,刘心宇,等.中国,201010137147.7,2010. 15 银锐明,张晓琪,银舜生.中国,200810143397.4,2008. 16 Zhang Qin. Study on heating resistance pasters of YBCO thick film. Master’s thesis, University of Electronic Science and Technology of China, China,2011(in Chinese). 张琴.YBCO厚膜发热电阻浆料研究.硕士学位论文,电子科技大学,2011. 17 Shi Yu, Liu Xinyu, Li Chuan, et al. Electronic Components and Mate-rials,2010,29(6),7. 18 Zhao Xiayan, Yuan Changlai, Huang Jinyue, et al. Electronic Components and Materials,2010,29(2),17. 19 Pathak L C. Ceramics International,2006,30(3),417. 20 Zhang Qin, Yang Chuanren, Zhang Jihua, et al. Piezoeletrics and Acoustooptics,2011,33(4),628(in Chinese). 张琴,杨传仁,张继华,等.压电与声光,2011,33(4),628. 21 Park J H, Park J G, Kim B K.Materials Research Bulletin,2002,37,305. 22 Yoo J H, Hong J I, Suh S. Sensors Actuators,1999,78,168. 23 Zang Fengming.Piezoelectrics and Acoustooptics,1998,20(5),358(in Chinese). 臧凤明.压电与声光,1998,20(5),358. 24 Park S H, Ahn C W.Japanese Journal of Applied Physics,2004,43(8B),1072
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2019, Vol. 33 
