HUO Yonglin1,2, HUO Jichuan1,2,3, ZHANG Xingquan1,2,3, QIN Guilu2
1 State Key Laboratory of Environmental Friendly Energy and Materials, Southwest University of Science and Technology, Mianyang 621010,Sichuan, China 2 School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010,Sichuan, China 3 Analysis and Testing Center, Southwest University of Science and Technology, Mianyang 621010,Sichuan, China
Abstract: Basalt, a basic volcanic rock, is an important component of the oceanic and continental crust of the earth, and the natural resources are very rich. In addition to the dense compressive strength of its structure and good weathering resistance, basalt also has good wear resistance, high hardness, low draft, poor electrical conductivity, strong compression resistance, low crushing value, strong corrosion resistance, high sli-ding coefficient, and other natural properties. The excellent performance of basalt make is it suitable for use in highways, railways, airport runways, cement mixtures, preparation of concrete building materials, building decoration materials and production of basalt fiber, rock wool, cast stone, scales and basic materials for radioactive waste immobilition. Herein, the mineral and chemical composition of basalt and its physical and chemical properties are summarized, which is followed by a overview of research progress on the development and utilization of basalt fiber, rock wool, cast stone, scale, high-level radioactive waste glass and glass ceramic solidification, cement mixture and concrete admixture, and coarse progress. Overall, this review intends to provide a preliminary database for the comprehensive and efficient utilization of basalt resources and further guide the exploration of new materials based on basalt.
作者简介: 霍泳霖,2017年6月毕业于昆明理工大学,获得工学学士学位。现为西南科技大学材料科学与工程学院硕士研究生,在张行泉讲师、霍冀川教授的指导下进行研究。目前主要研究方向为玄武岩玻璃及玻璃陶瓷。 霍冀川,环境友好能源材料国家重点实验室PI团队负责人,教授、博士研究生导师,目前主要从事玄武岩及纤维、放射性废物处理处置材料的研究。享受国务院政府特殊津贴,四川省有突出贡献的优秀专家。主持和参加863计划、支撑计划、国防及四川省等科研项目20多项。以第一或通讯作者身份在Journal of Materials Chemistry A、Journal of Alloys and Compounds、RSC Advances、Royal Society Open Scie-nce、Chinese Journal of Structural Chemistry等学术期刊发表论文150余篇,获中国授权或公开美国发明专利20余项,出版学术专著2部,参与制定并执行的地方及兵器行业标准3项。
引用本文:
霍泳霖, 霍冀川, 张行泉, 秦桂璐. 玄武岩的开发利用进展[J]. 材料导报, 2022, 36(6): 20080281-11.
HUO Yonglin, HUO Jichuan, ZHANG Xingquan, QIN Guilu. Development and Utilization of Basalt. Materials Reports, 2022, 36(6): 20080281-11.
1 Lai S C. Petrology of magmatic rocks (second edition), Higher Education Press, China,2016 (in Chinese). 赖绍聪. 岩浆岩岩石学(第二版),高等教育出版社, 2016. 2 Cao H L, Yan Y W, Yue L P, et al. Basalt fiber, National Defense Industry Press, China,2017 (in Chinese). 曹海琳,晏义伍,岳利培,等.玄武岩纤维,国防工业出版社, 2017. 3 Liu J X, Cui Y, Yang J P, et al. Journal of Yanshan University, 2017, 41(4),323 (in Chinese). 刘建勋, 崔瀛, 杨剑平,等.燕山大学学报, 2017, 41(4), 323. 4 Zhao Wen. Railway Investigation and Surveying, 2009 (5),60 (in Chinese). 赵文.铁道勘察,2009 (5), 60. 5 Ding B M, Zhang L, Liu J Q. China Mining Magazine, 2019, 28(10), 1 (in Chinese). 丁宝明,张蕾,刘嘉麒.中国矿业, 2019, 28(10), 1. 6 Meng X, Tian X Q, Bai Y F. Development Guide to Building Materials, 2019,17(20),9 (in Chinese). 孟欣,田学勤,白云峰.建材发展导向, 2019, 17(20),9. 7 Sun Z Y, Li M. Advanced Materials Industry, 2019 (1),16 (in Chinese). 孙哲余,黎明.新材料产业, 2019 (1),16. 8 Yu S F, Tan L, Sun Z H, et al. Glass Fiber, 2019 (4), 36 (in Chinese). 于守富, 谭良, 孙振海, 等.玻璃纤维, 2019 (4),36. 9 Wu Y K, Yu S F, Zheng P Q. Fiber Glass, 2019 (6),1 (in Chinese). 吴永坤,于守富,郑佩琪.玻璃纤维, 2019 (6), 1. 10 Qian B Z. Synthetic Fiber in China, 2019, 48(1), 7 (in Chinese). 钱伯章.合成纤维,2019, 48(1),7. 11 Yang K. Advanced Materials Industry, 2018, 299(10),32 (in Chinese). 杨堃.新材料产业, 2018, 299(10), 32. 12 Fiore V, Scalici T, Di Bella G, et al. Composites Part B, 2015, 74, 74. 13 Sun M S, Cai G M, Zhang L, et al. Hi-tech Fiber & Application, 2012, 37(3),26 (in Chinese). 孙苗莎, 蔡光明, 张雷,等.高科技纤维与应用, 2012, 37(3),26. 14 Yuan Z Y, Wang C H, Liu J H. Keji Zhifu Xiangdao, 2012(20),97 (in Chinese). 袁忠月, 王超会, 刘剑虹. 科技致富向导, 2012(20),97. 15 Gao J. Researchon basalt fiber aged in acid, alkali and relative humidity environment. Master's Thesis, Donghua University, China, 2016(in Chinese). 高杰. 玄武岩纤维在酸碱及相对湿度环境下的老化性研究. 硕士学位论文, 东华大学, 2016. 16 Ding N. Study on alkaline resistance of basalt fiber and glass fiber and bending properties of TRC. Master's Thesis, Dalian University of Techno-logy, China, 2016 (in Chinese). 丁宁. 玄武岩和玻璃纤维的耐碱性及TRC弯曲性能的研究. 硕士学位论文, 大连理工大学, 2020. 17 Wang Y Z. Acta Mineralogica Sinica, 2019, 39(6), 664(in Chinese). 王跃忠.矿物学报, 2019, 39(6),664. 18 Pu Q L. West-China Exploration Engineering, 2020(1), 156(in Chinese). 蒲庆隆.西部探矿工程, 2020 (1),156. 19 Su Y H. West-China Exploration Engineering, 2019(3), 118(in Chinese). 苏永虎. 西部探矿工程, 2019 (3), 118. 20 Zhang J, Xu X M, Liu Z L. Hi-tech Fiber & Application, 2019(3), 52 (in Chinese). 张剑,徐小明,刘作磊. 高科技纤维与应用, 2019 (3), 52. 21 Zhang M S, Xu J B, Fei G C, et al. China Resources Comprehensive Utilization, 2019, 37(12), 51 (in Chinese). 张明胜,许家斌,费光春,等.中国资源综合利用, 2019, 37(12), 51. 22 Chen X F. Study on high strength of continuous basalt fiber. Ph.D. Thesis, Southeast University, China, 2018 (in Chinese). 陈兴芬. 连续玄武岩纤维的高强度化研究. 博士学位论文, 东南大学, 2018. 23 Tatarintseva O S, Khodakova N N. Glass and Ceramics, 2010, 67, 165. 24 Franzson H, Erlendsson O, Hardarson B S, et al. In: Greenbas sustai-nable fibres from basalt mining, Nordic Councilo of Ministers, Copenha-gen, 2017. 25 Li J J, Dang X A. Materials Science and Technology, 2009, 17 (2), 211 (in Chinese). 李建军,党新安.材料科学与工艺, 2009, 17(2), 211. 26 Liu J X, Yang J P, Chen M R, et al. Thermochimica Acta, 2018, 660, 56. 27 Wang Y T, Bai Z M, Yu S B, et al. China Non-metallic Mining Industry, 2020(1), 23 (in Chinese). 汪溢汀,白志民,余思彬,等.中国非金属矿工业导刊, 2020 (1), 23. 28 Bai Z M, Deng Y X. Physical chemistry of silicate,Chemical Industry Press, China, 2018 (in Chinese). 白志民, 邓雁希. 硅酸盐物理化学,化学工业出版社, 2018. 29 Ernst W G. Tectonophysics, 1982, 86(4), 401. 30 Huang Q. Study on dendrite of diopside-albite-anorthite system (Di-Ab-An) by rapid cooling crystallization. Master's Thesis, China University of Geosciences, China,2003(in Chinese). 黄琼. 透辉石-钠长石-钙长石体系(Di-Ab-An)快速冷却结晶的枝晶研究. 硕士学位论文, 中国地质大学, 2003. 31 Huo Y L, Qin G L, Huo J H, et al. Glass, 2020,47(5),1(in Chinese). 霍泳霖, 秦桂璐, 霍冀川, 等. 玻璃, 2020, 47(5), 1. 32 Dan X, Xi X Y, Ma P C. Composites Part A: Applied Science and Manufacturing, 2019, 119, 127. 33 Cui S L. High-tech fiber, China Textile Press, China, 2016 (in Chinese). 崔淑玲.高技术纤维,中国纺织出版社, 2016. 34 Zu Q, Zhao Q. High performance glass fiber, National Defense Industry Press, China, 2017 (in Chinese). 祖群,赵谦.高性能玻璃纤维, 国防工业出版社, 2017. 35 Kang M. In: The First International Conference on Basalt Fibers and Composite. Nanjing, 2019, pp. 15. 36 Wang L, Chen Y, Li Z W.FRP/Composites, 2000 (6), 22(in Chinese). 王岚, 陈阳, 李振伟. 玻璃钢/复合材料, 2000 (6), 22. 37 Sun G, Zhang Z G. Modern Manufacturing Technology and Equipment, 2019 (4), 206 (in Chinese). 孙刚, 张志刚.现代制造技术与装备, 2019 (4),206. 38 Zhang S Z, Zhao F, Lyu S Y, et al. Guizhou Geology, 2018, 35(1), 20 (in Chinese). 张胜泽, 赵锋, 吕绍玉, 等. 贵州地质, 2018, 35(1), 20. 39 Wang X L. Construction & Design for Project, 2020(7), 161 (in Chinese). 王晓磊.工程建设与设计, 2020 (7),161. 40 Liu C, Ding M L. Thermal Insulations & Energy-Saving Technology, 2011(4),14 (in Chinese). 刘春, 丁明龙.保温材料与节能技术, 2011(4),14. 41 Abdulkerim Yörükoglua, Fatih Akkurtb, Serdar Çulhaa. Construction and Building Materials, 2020, 243,1. 42 Zhang Q. Jiangxi Building Materials, 2018, 239(14),7 (in Chinese). 张庆.江西建材, 2018, 239(14),7. 43 Zhang X Y. Journal of China Academy of Building Materials Science, 1991,3 (4), 66(in Chinese). 张筱园.中国建筑材料科学研究院学报, 1991, 3(4), 66. 44 He F.Preparation and application of glass ceramics,Chemical Industry Press, China, 2017 (in Chinese). 何峰.微晶玻璃制备与应用, 化学工业出版社, 2017. 45 Chen W C, Zhang X Y.Journal of the Chinese Ceramic Society, 1982, 10(4), 454 (in Chinese). 陈文彩,张筱园.硅酸盐学报, 1982, 10(4), 454. 46 Xi W. China Non-metallic Mining Industry, 2020 (3), 32 (in Chinese). 奚旺.中国非金属矿工业导刊, 2020 (3), 32. 47 Tang Y S, Chen F. Jiangsu Geology, 1993, 17(3-4), 220 (in Chinese). 唐炎森,陈芳.江苏地质, 1993, 17(3-4),220. 48 Wang Y R. Ceramics, 1996(5), 25 (in Chinese). 王玉荣.陶瓷, 1996 (5), 25. 49 霍泳霖, 霍冀川, 张行泉. 中国专利, CN201911170176.0, 2019. 50 LuizaF Lima, PedroQ Mantas,AnaM Segadães, et al. Journal of Non-Crystalline Solids, 2020, 538, 120019 51 Sun S. Preparation of basalt slag glass-ceramics. Master's Thesis, Jiangsu University, China, 2010 (in Chinese). 孙帅. 玄武岩矿渣微晶玻璃的制备研究.硕士学位论文,江苏大学,2010. 52 Wu Z H, Duan Z X. Modern Paint and Finishing, 2010, 13 (7), 21(in Chinese). 吴宗汉,段志新.现代涂料与涂装, 2010, 13(7),21. 53 Xu Q X. Shanghai Coatings, 2002, 40 (4), 8 (in Chinese). 许求鑫.上海涂料, 2002, 40(4), 8. 54 Cui X H, Zhang X C, Liu X D, et al. Modern Paint and Finishing, 2018, 21(4), 25 (in Chinese). 崔向红, 张晓臣, 刘晓东, 等. 现代涂料与涂装, 2018, 21(4), 25. 55 Gai C T. Preparation and properties of basalt flake modified epoxy coa-tings. Master's Thesis, Harbin Engineering University, China, 2016 (in Chinese). 盖春涛. 玄武岩鱗片改性环氧涂料的制备及性能研究. 硕士学位论文, 哈尔滨工程大学, 2016. 56 Yang Z J, Qiao C X, Gu Y Z, et al. Composites Science and Engineering, 2020 (4), 28 (in Chinese). 杨中甲,乔彩霞,顾轶卓,等.复合材料科学与工程, 2020 (4), 28. 57 Ojovan M I, Lee E. An Introduction to Nuclear Waste Immobilisation, Elsevier, Amsterdam, 2005. 58 Donald I. Waste Immobilisation in Glass and Ceramic Based Hosts: Radioa-ctive, Toxic and Hazardous Wastes, Wiley-Blackwell, Chichester, 2010,pp. 1. 59 Lutze W, Ewing R C. Radioactive Wasteforms for the Future, North Holland, Amsterdam, 1988. 60 Wu L. Science and Technology Innovation Herald, 2016, 13(5), 66 (in Chinese). 吴浪.科技创新导报, 2016, 13(5), 66. 61 Chen J, Wen M F. In: National Annual Meeting of Applied Chemistry. Changchun, 2013, pp. 1 (in Chinese) 陈靖, 文明芬. 全国应用化学年会. 长春,2013, pp.1. 62 Sheng J W, Luo S G. Journal of the Chinese Ceramic Society, 1997(1),83 (in Chinese). 盛嘉伟, 罗上庚.硅酸盐学报, 1997(1), 83. 63 Xu K. Rare Metals Letters, 2016, 35(7), 481. 徐凯.中国材料进展, 2016, 35(7), 481. 64 Ducassea T, Gourgiotisb A, Pringle E, et al. Applied Geochemistry, 2018, 97, 19. 65 Sun Y P, Wang H L, Chu J, et al. Journal of Inorganic Materials, 2019,34 (4), 461 (in Chinese). 孙亚平, 王洪龙, 褚 健,等.无机材料学报,2019, 34(4), 461. 66 Zhao J,Liu H F, Zhang X Q, et al. Ceramics International, 2020, 46(7), 9968. 67 Meng C. Study on the structure and chemical stability of ceramic solidified bodies of radionuclides in spent fuel reprocessing. Ph.D. Thesis, Zhejiang University, China, 2016(in Chinese). 孟成. 乏燃料后处理中放射性核素的陶瓷固化体的结构与化学稳定性研究.博士学位论文, 浙江大学, 2016. 68 Zou Q L, Lai Z Y, Lu Z Y. Atomic Energy Science and Technology, 2012, 46(11), 31 (in Chinese). 邹秋林, 赖振宇, 卢忠远.原子能科学技术, 2012, 46(11), 31. 69 Zhang C Z, Zhang B S. Radiation Protection, 1997(6), 417 (in Chinese). 张传智, 张宝善.辐射防护, 1997(6), 417. 70 Luo S G. Chinese Journal of Nature, 1998(2),87 (in Chinese). 罗上庚.自然杂志, 1998(2),87. 71 Yuan X N, Zhang Z T, Cai X N, et al. Atomic Energy Science and Technology, 2015, 49(2),240 (in Chinese). 袁晓宁, 张振涛, 蔡溪南,等.原子能科学技术, 2015, 49(2), 240. 72 霍冀川, 霍泳霖, 张行泉, 等. 中国专利, CN110335695A, 2019. 73 霍泳霖, 霍冀川, 张行泉.中国专利,CN110845143A,2020 74 Huo J C, Huo Y L, Zhang X Q, et al. U.S. patent, US16854817, 2020. 75 Donald I W, Metcalfe B L, Taylor R N J. Journal of Materials Science, 1997, 32(22),5851. 76 Chen C Q, Mou S B, Chen Y A. Science and Technology of Overseas Building Materials, 2003, 24(1), 9 (in Chinese). 陈长青,牟善彬, 陈雁安.国外建材科技, 2003, 24(1), 9. 77 Wu Z W, Lian H Z.High performance concrete, China Railway Press, China, 1999 (in Chinese). 吴中伟, 廉慧珍. 高性能混凝土,中国铁道出版社, 1999. 78 Chen D Y, Tang K J, Liu L B, et al. China Concrete and Cement Pro-ducts, 2011 (6), 5 (in Chinese). 陈德玉,唐凯靖,刘来宝, 等.混凝土与水泥制品, 2011 (6), 5. 79 Pan S Q. Cement Technology, 1999 (5), 39(in Chinese). 潘淑琴.水泥技术, 1999 (5), 39. 80 Zhang Q Z. Cement Technology, 2006(1),82(in Chinese). 张启中.水泥技术, 2006(1), 82. 81 Mu S B, Sun Z Y, Chen Y A. Cement, 1995 (9),10 (in Chinese). 牟善彬,孙振亚,陈雁安.水泥, 1995 (9),10. 82 Luo B Y, Wei G, Sha Y H, et al. Cement Technology, 1997(1), 33(in Chinese). 骆秉银, 魏广, 沙延和,等.水泥技术, 1997(1), 33. 83 Liu L B, Tang K J, Zhang L H, et al. Cement, 2013 (9), 7 (in Chinese). 刘来宝, 唐凯靖, 张礼华, 等.水泥,2013 (9), 7. 84 Cai P. Study on adaptability of cement and concrete admixtures with basalt mixture. Master's Thesis, Southwest University of Science and Technology, China, 2017(in Chinese). 蔡攀. 以玄武岩混合材的水泥与混凝土外加剂适应性研究. 硕士学位论文, 西南科技大学, 2017. 85 Zhang N N, Li Y L, Liu J H, et al. Bulletin of the Chinese Ceramic So-ciety, 2020, 39(7), 7 (in Chinese). 张楠楠,李云龙,刘锦红,等.硅酸盐通报, 2020, 39(7), 7. 86 Ma Q Q, Chen P, Zou X P, et al. Cement Engineering, 2013(5), 89 (in Chinese). 马清清,陈平,邹小平,等.水泥工程, 2013 (5), 89. 87 Qiao H X, Chen Z C, Liang J K, et al. Journal of Architecture and Civil Engineering, 2019, 36 (1), 48 (in Chinese). 乔宏霞,陈志超,梁金科,等.建筑科学与工程学报, 2019, 36(1), 48. 88 Sun M. Analysis and research on influencing factors of crushing value of basalt aggregate on asphalt pavement. Master's Thesis, Changsha University of Science and Technology, China,2016 (in Chinese). 孙明. 沥青路面玄武岩集料压碎值影响因素分析研究. 硕士学位论文, 长沙理工大学, 2016. 89 Cui N Q. Communications Science and Technology Heilongjiang, 2016 (2), 30 (in Chinese). 崔能群.黑龙江交通科技, 2016 (2), 30. 90 Fei J W, Han F. Road Engineering, 2018 (6),77 (in Chinese). 费建文,韩飞.道路工程, 2018(6), 77. 91 Ai C F, Hu C, Tu L B, et al. S Journal of China & Foreign Highway, 2012, 32 (3), 312 (in Chinese). 艾长发, 胡超, 屠凌波, 等.中外公路, 2012, 32(3), 312. 92 Dong Y S, Hou Y, Zhou X L. Highway, 2020(3), 232 (in Chinese). 董元帅,侯芸,周绪利.公路, 2020(3), 232. 93 Lei J N, Liu Q C. Nonferrous Metals Abstract, 2016, 31(6), 67(in Chinese). 雷爵能, 刘奇川. 资源信息与工程, 2016, 31(6), 67. 94 Shan R, Hu X G. Subgrade Engineering, 2020 (1), 1 (in Chinese). 单瑞, 胡兴国.路基工程, 2020 (1), 1. 95 Chen X Z. Commercial Concrete, 2016(99), 55 (in Chinese). 陈向哲. 商品混凝土, 2016 (99),55. 96 Wang R, Chang H, Wang Y. Shanxi Architecture, 2014, 40 (12), 130 (in Chinese). 王瑞, 常贺, 王雁.山西建筑, 2014, 40(12),130. 97 Yang J D, Zhang X H, Li Y. In: Proceedings of the Fifth International Symposium on RCC Dam (Part Ⅰ). Guiyang, 2007,pp. 472 (in Chinese). 杨金娣,张细和,李勇.第五届碾压混凝土坝国际研讨会.贵阳,2007 ,pp. 472. 98 Huang S G, Chen J J, Wang J X, et al. Materials Reports B: Research Papers, 2020, 34(12),24045 (in Chinese). 黄守刚,陈进杰,王建西,等,材料导报:研究篇,2020,34(12), 24045.