Abstract: The adhesion force between aggregate and asphalt binder is one of the important indicators of asphalt mixture performance, which has important effect on the durability of the road. The adhesion force between aggregate is influenced by many factors. In order to investigate the inf-luence of the inherent components of the aggregate on the adhesion force between aggregate and asphalt binder, the probe tip of the atomic force microscope (AFM) was modified: use the main compounds in aggregate to make small ball probe tips so as to measure the adhesion of the asphalt surface. Obtaining aggregates from the quarry attached to the road engineering project under construction, combined with X-ray fluorescence spectrometer (XRF) analysis and macro MTS pull-out test to investigate the effect of aggregate composition on aggregate-asphalt adhesion and conduct a comprehensive evaluation. The conclusion indicates that the adhesion between aggregate and asphalt binder includes physical adsorption and chemical adsorption. Large adhesion force occurs between Al2O3 and asphalt binder, the results measured at the nano level show that there is a strong intermolecular attraction between SiO2 and asphalt binder, while the intermolecular attraction between CaCO3 and asphalt binder is weak. The macro-level measurement results show that chemisorption has a stronger effect on the adhesion between aggregate and asphalt binder and the alkaline aggregate combined with asphalt binder have a stronger ability to resist water damage. The result has certain guiding significance of aggregate screening in road engineering.
1 Wang X D. Study on the influence of aggregate lithology and micro characteristics on the road performance of asphalt mixtures. Master's Thesis, Jilin University, China, 2011(in Chinese). 王旭东. 集料岩性及微观特征对沥青混合料路用性能的影响研究. 硕士学位论文, 吉林大学, 2014. 2 Zhang C X, Chen H X, Li Y, et al. Materials Reports, 2013, 27(S2),293(in Chinese). 张晨旭, 陈华鑫, 李毅, 等. 材料导报, 2013, 27(专辑22),293. 3 Wang D Y, Wang P. Highway Engineering, 2017, 42(6),69(in Chinese). 王端宜, 王鹏. 公路工程, 2017, 42 (6),69. 4 Binning G, Quate C F. Gerber C. Physical Review Letters,1986, 56(9),930. 5 Gaskin J. On bitumen microstructure and the effects of crack healing. Ph.D. Thesis, University of Nottingham, UK, 2013. 6 Liu K F, Deng L F, Zhen J Y, et al. Chinese Journal of Materials Research, 2016, 30(10),773(in Chinese). 刘克非, 邓林飞, 郑佳宇, 等. 材料研究学报, 2016, 30(10),773. 7 Wu Z H, Chen J, Fu Q S, et al. Materials Reports A: Review Papers, 2013, 28(8),62(in Chinese). 吴召洪, 陈建, 附青山, 等. 材料导报: 综述篇, 2014, 28(8),62. 8 Li Y J, Yang J, Tan T. Construction and Building Materials, 2015, 101,159. 9 Rafiqul A, Tarefder, ASCE M, et al. Journal of Materials in Civil Engineering, 2010, 22(7),714. 10 Lv X B, Fan W Y, Wang J Q, et al. Construction and Building Mate-rials, 2019, 207,422. 11 Lyne A L, Wallqvist V, Birgisson B. Fuel,2013, 113,248. 12 Chen A Q, Liu G Q, Zhao Y L, et al. Construction and Building Mate-rials, 2018, 167,177. 13 Pei Z S. Analysis of microscopic characteristics and influencing factors of aging asphalt surface based on AFM. Master's Thesis, Harbin Institute of Technology, China, 2016(in Chinese). 裴忠实. 基于AFM的老化沥青表面微观特征及影响因素分析. 硕士学位论文, 哈尔滨工业大学, 2016. 14 Huang S C, Robertson R E. Road Materials and Pavement Design, 2006,7(2),179. 15 Wang W N, Xu Q J, Zhou S X, et al. Materials Reports A: Review Papers, 2019, 33(7),2197(in Chinese). 王威娜, 徐青杰, 周圣雄, 等. 材料导报: 综述篇, 2019, 33(7),2197. 16 Zhang C. Experimental study on shear mechanical properties of asphalt-aggregate interface. Master's Thesis, Hefei University of Technology, China, 2017(in Chinese). 张超. 沥青-集料界面剪切力学性能试验研究. 硕士学位论文, 合肥工业大学, 2017. 17 Song L, An C F, Huang M. Journal of Building Materials, 2019, 22(3),440(in Chinese). 宋亮,安传峰,黄美. 建筑材料学报, 2019, 22(3),440. 18 Fischer H, Stadler H, Erina N. Journal of Microscopy, 2013, 250(3),210. 19 Yu X K, Burnham N A, et al. Fuel, 2013, 113,443. 20 Xie S N. Research on asphalt structure and adhesion properties of asphalt surface at normal temperature. Master's Thesis, Harbin Institute of Technology, China, 2017(in Chinese). 解赛楠. 常温域沥青表面纳观构造及粘附特性研究. 硕士学位论文, 哈尔滨工业大学, 2017. 21 Xu M, Yi J, Feng D, Huang Y, et al. Applied Materials & Interfaces, 2016, 8(19),12393. 22 Fan X H, Xue Z H. Bulletin of the Chinese Ceramic Society, 2019, 38(5),1477(in Chinese). 樊兴华, 薛振华. 硅酸盐通报, 2019, 38(5),1477. 23 Chen S, Lei Y, Li G, et al. Journal of China & Foreign Highway, 2010, 30(6),226(in Chinese). 陈实,雷宇,李刚,等. 中外公路, 2010, 30(6),226. 24 Gong X B. Unified model of asphalt pavement material and mechanical behavior in multi-scale domain. Ph.D. Thesis, Harbin Institute of Technology, China, 2017(in Chinese). 龚湘兵. 沥青路面材料多尺度域力学行为及统一模型. 博士学位论文, 哈尔滨工业大学, 2017. 25 Pang X X. Analysis of asphalt and aggregate adhesion based on AFM and surface energy principles. Master's Thesis, Harbin Institute of Technology, China, 2015(in Chinese). 庞骁奕. 基于AFM与表面能原理的沥青与集料粘附特性分析. 硕士学位论文, 哈尔滨工业大学, 2015. 26 Zhou W F. Study on asphalt and aggregate interface adhesion, Master's Thesis, Chang'an University, China, 2002(in Chinese). 周卫峰. 沥青与集料界面粘附性研究. 硕士学位论文, 长安大学, 2002. 27 Amir M. Ali K. Construction and building material, 2013, 38,423. 28 Little D N, Jones D R. In: National Seminar in Moisture Sensitivity. California,2003,pp.37. 29 Qin C L. In: Conference Record of the 2019 World Transport Convention. Beijing, 2019,pp.1382(in Chinese). 秦成林. 2019世界交通运输大会论文集. 北京,2019,pp.1382. 30 Robertson R E. Transportation Research Circular, 2000, 499,38.