Research Progress on Mechanical and Corrosion Properties of Zn-Cu-Ti Alloys
SUN Lili1,2, CHEN Liangyuan1,2, WANG Yong1,2, ZHANG Xuyun1,2, XU Dekui3
1 School of Mechanical Science and Engineering, Northeast Petroleum University, Daqing 163318, China; 2 Heilongjiang Key Laboratory of Petroleum and Petrochemical Multiphase Treatment and Pollution Prevention, Daqing 163318, China; 3 Oil Production Engineering Research Institute of Daqing Oilfield Company Limited, Daqing 163453, China
Abstract: Zn-Cu-Ti alloys are zinc-based alloys with a very broad application prospect. The addition of Cu and Ti elements to the zinc matrix can effectively improve the hardness and creep resistance of the materials. The good comprehensive mechanical properties of the Zn-Cu-Ti alloys are comparable to those of copper alloys, but also exhibit lower density. The Zn-Cu-Ti alloys can inherit the excellent corrosion resistance of zinc, and already have replaced the traditional galvanized sheets. The roof covering materials of Zn-Cu-Ti alloys can be extended by several times in the atmospheric environment. China's zinc reserves and production are both in the top positions in the world. However, Zn-Cu-Ti alloys have a very low proportion in the application of zinc. Firstly, most of Zn-Cu-Ti alloys are processed into coiled sheets for building wall panels and roofing materials, the application fields are limited. There are many deficiencies in the processing of domestic Zn-Cu-Ti alloys, however, the high-quality coils always need to be imported. Secondly, Zn-Cu-Ti alloys have excellent corrosion resistance in natural atmospheric environment, but the study of corrosion mechanism in special corrosion environment is unclear. In addition, the mechanical properties of Zn-Cu-Ti alloys are poor in high temperature and low temperature environments, and the research on the mechanical properties of Zn-Cu-Ti alloys has not yet reached a unified conclusion. These limit the application of the Zn-Cu-Ti alloys in other fields. In recent years, the modification technology of zinc alloys has actively been explored. The newly developed die-casting parts of zinc alloys are precise and complex in shape, which used to make bearings, molds, wear-resistant and shock-absorbing parts. Now it has been confirmed that the machining and heat treatments process will change the size and distribution of the compound phase, the solid solubility of metal ions in Zn-Cu-Ti alloys. When selecting the reasonable process parameters, the mechanical and corrosion resistance of the alloys will be improved to a certain extent. The increasing the content of Cu can increase the hardness and tensile strength of the alloys. Ti can improve the toughness of the zinc alloys. The addition of Cr, Mg and rare earth elements will change the phase composition and grain size of the alloys. The corrosion layer structure and the mechanical property of the alloys can be improved under certain conditions. During the period of the experiments, the experimental designs include changing the proportion of alloys composition, adding other metal elements, improving the preparation process, and heat treatments process. The corrosion testing mainly include the self-corrosion, electrochemical corrosion and stress corrosion cracking tests of the alloys under different environments. In addition to the measurements of microstructure and phase composition, the analytical methods also include the analysis of corrosion resistance of alloys by the density of corrosion layer and the establishment of mathematical model. Zn-Cu-Ti alloys will also become high-quality alternative materials for electrical materials, hardware materials, automotive parts and coating materials. In future, the proportion of Zn-Cu-Ti alloys in the consumption structure of zinc will gradually increase. Based on the characteristics of Zn-Cu-Ti alloys, this paper describes the research progress of mechanical properties and corrosion resistance of Zn-Cu-Ti alloys at home and abroad, and also summarizes the basic theoretical research results of the preparation process, molding process and corrosion of Zn-Cu-Ti alloys. Combined with the application prospect of Zn-Cu-Ti alloys, the application value of Zn-Cu-Ti alloys is expected to be more widely. The research in this paper provides a necessary reference for the development and application of Zn-Cu-Ti alloys.
Hu Y X.Hunan Metallurgy,1984(5),29(in Chinese).胡贻信. 湖南冶金,1984(5),29.2 Yang F, Liang Y C, Kuang Y J, et al.Corrosion and Protection,2017,38(10),767(in Chinese).杨帆,梁永纯,匡尹杰,等.腐蚀与防护,2017,38(10),767.3 Ding X M, Zhou S H, Ye B, et al.Materials Reports A:Review Papers,2017,31(2),38(in Chinese).丁学明,周素洪,叶兵,等.材料导报:综述篇,2017,31(2),38.4 Osuch P, Walkowicz M, Knych T, et al.Key Engineering Materials. Trans Tech Publications,2016,682,380.5 Sun W, Yang S, Yu X, et al.E.U. patent application, EP20140833491.2018.6 王建华,吉宏祥,邵伯金,等.中国专利,CN107604280A,2018.7 Wei H G, Li W W.Shanghai Nonferrous Metals,2015,36(1),1(in Chinese).魏华光,李伟文.上海有色金属,2015,36(1),1.8 梁振西,康壮苏,李紫跃,等.中国专利,CN106319424A,2017.9 Wang L N, Meng Y, Liu L J, et al.Journal of Metals,2017,53(10),1317(in Chinese).王鲁宁,孟瑶,刘丽君,等.金属学报,2017,53(10),1317.10 Tang Y P, Hong L, Jin Y C, et al.Materials Protection,2014,47(5),43(in Chinese).唐谊平,洪良,金源超,等.材料保护,2014,47(5),43.11 Chen D J, Pan M, Lin Q, et al.New Technology & New Process,2018(2),14(in Chinese).陈端杰,潘觅,林巧,等.新技术新工艺,2018(2),14.12 Zhang X M, Xiao L R, Wen Y N, et al.Journal of Materials Science and Engineering,2010,28(4),576(in Chinese).张喜民,肖来荣,温燕宁,等.材料科学与工程学报,2010,28(4),576.13 Chen X, Yang D, Tian M J, et al.Special Casting & Nonferrous Alloys,2015,35(6),669(in Chinese).陈行,杨灯,田明杰,等.特种铸造及有色合金,2015,35(6),669.14 Boczkal G, Mikułowski B.Archives of Metallurgy and Materials,2015,60,2355.15 Villegas-Cardenas J D, Saucedo-Muñoz M L, Lopez-Hirata V M, et al.Materials Research,2014,17,1137.16 Savaşkan T, Hekimoğlu A P, Pürçek G, et al.Tribology International,2004,37,45.17 Elzanaty H.International Journal of Research in Engineering & Technology,2014,2,55.18 Deng M, Jia S G, Song K X, et al.Transactions of Materials and Heat Treatment,2014,35(8),31(in Chinese).邓猛,贾淑果,宋克兴,等.材料热处理学报,2014,35(8),31.19 Huang Y, Xu H.Material Sciences,2016,6,65.20 Li X Y, Lu Y L, Wang J, et al.Journal of Materials Engineering,2018,46(1),67(in Chinese).李晓燕,卢雅琳,王健,等.材料工程,2018,46(1),67.21 Perez-Bustamante R, Perez-Bustamante F, Carreno-Gallardo C, et al.Microscopy and Microanalysis,2018,24,2270.22 Pourbahari B, Mirzadeh H, Emamy M, et al.Journal of Materials Engineering and Performance,2018,27,1327.23 Huang Y, Gan W, Kainer K U, et al.Journal of Magnesium and Alloys,2014,2,1.24 Ji S Y, Liang S H, Song K X, et al.The Chinese Journal of Nonferrous Metals,2016,26(8),1649(in Chinese).冀盛亚,梁淑华,宋克兴,等.中国有色金属学报,2016,26(8),1649.25 Wu C, Sun Y, Fan S, et al.Journal of Phase Equilibria and Diffusion,2018,39,130.26 Wu M W, Tsao L C, Shu G J, et al.Materials Science and Engineering: A,2012,538,135.27 Sha J, Yang C, Liu J, et al.Scripta Materialia,2010,62,859.28 Xiao Y F, Zhou N F, Wu L, et al.Heat Treatment of Metals,2017,42(4),22(in Chinese).肖逸锋,周年丰,吴靓,等.金属热处理,2017,42(4),22.29 Zarpelon L M C, Banczek E P, Martinez L G, et al.Advances in Mate-rials Science and Engineering,2018,11,1.30 He L J, Wang J Z, Wang C B, et al.Hot Working Technology,2009,38(19),1(in Chinese).何力佳,王建中,王春波,等.热加工工艺,2009,38(19),1.31 Gomes L F, Silva B L, Garcia A, et al.Metallurgical and Materials Transactions A,2017,48(4),1841.32 Geng Z J, Xiao L R, Cai Z Y, et al.Mining and Metallurgical Enginee-ring,2012,32(5),101(in Chinese).耿占吉,肖来荣,蔡圳阳,等.矿冶工程,2012,32(5),101.33 Wang Y, Xiao L R, Wan L, et al.Special Casting and Nonferrous Alloys,2012,32(11),1054(in Chinese).王艳,肖来荣,万磊,等.特种铸造及有色合金,2012,32(11),1054.34 Yuan D, Gao H B, Sun X J, et al.Aeronautical Manufacturing Technology,2018,61(10),40(in Chinese).袁丁,高华兵,孙小婧,等.航空制造技术,2018,61(10),40.35 Yu Y, Tang S, Guo X B, et al.Iron & Steel,2006,41(11),50(in Chinese).于洋,唐帅,郭晓波,等.钢铁,2006,41(11),50.36 Liu Z Q, He M, Zhao J, et al.China Mechanical Engineering,2015,26(3),403(in Chinese).刘战强,贺蒙,赵建,等.中国机械工程,2015,26(3),403.37 Ji S, Liang S, Song K, et al.Journal of Materials Research,2017,32,3146.38 Xu X Q, Li D F, Guo S L, et al.Transactions of Nonferrous Metals Society of China,2012,22,1075.39 Xu X Q, Li D F, Guo S L, et al.Advanced Materials Research. Trans Tech Publications,2011,291,635.40 Xu X Q, Li D F, Guo S L, et al.Transactions of Nonferrous Metals Society of China,2012,22(1),1606.41 Ma X Y, Li Z H, Li J, et al.Metallurgical Information Review,2011(6),41(in Chinese).马晓艺,李灼华,李戬,等.冶金信息导刊,2011(6),41.42 Tan Y, Lin X F, Zhang S D, et al.Nonferrous Metals Science and Engineering,2015,6(6),57(in Chinese).谭颖,林向飞,张世道,等.有色金属科学与工程,2015,6(6),57.43 Quintana M J, García J O, González R, et al.Dyna,2016,83,77.44 Xiao L R, Zhang X M, Wang Y, et al.The Chinese Journal of Nonferrous Metals,2011,21(11),2775(in Chinese).肖来荣,张喜民,王艳,等.中国有色金属学报,2011,21(11),2775.45 Osuch P, Walkowicz M, Mamala A, et al.Rudy i Metale Nieżelazne Recykling,2015,60,508.46 Liu Y W, Wang Z Y, Cao G W, et al.The Chinese Journal of Nonferrous Metals,2015,25(2),375(in Chinese).刘雨薇,王振尧,曹公望,等.中国有色金属学报,2015,25(2),375.47 Ni Y, Wu G G, Yan Y F, et al.Surface Technology,2018,47(2),182(in Chinese).倪雅,吴国光,闫远方,等.表面技术,2018,47(2),182.48 Cole I S, Muster T H, Lau D, et al.Journal of the Electrochemical Society,2010,157,213.49 Venkatraman M S, Cole I S, Emmanuel B, et al.Electrochimica Acta,2011,56,8192.50 Thomas S, Cole I S, Gonzalez-Garcia Y, et al.Journal of Applied Electrochemistry,2014,44,747.51 Bos C B, Schnitger H C, Zhang X, et al.Corrosion Science,2006,48,483.52 Wang Y H, Xiao L R, Zhao X J, et al.Materials and Corrosion,2016,67,297.53 Ji S, Liang S, Song K, et al.Materials Science,2016,31,408.54 Arenas M A, de Damborenea J.Surface and Coatings Technology,2005,200,2085.55 Cole I S.Materials,2017,10,1288.56 Thomas S, Birbilis N, Venkatraman M, et al.Corrosion,2012,68,1.57 Macdonald D D, Ismail K M, Sikora E, et al.Journal of the Electroche-mical Society,1998,145,3141.58 Spence J W, Haynie F H.Corrosion Testing and Evaluation: Silver Anniversary Volume,1990,1000,208.59 Graedel T E.Corrosion Science,1996,38,2153.60 Wang Y H, Xiao L R, Geng Z J, et al.Corrosion and Protection,2013,34(5),410(in Chinese).王彦红,肖来荣,耿占吉,等.腐蚀与防护,2013,34(5),410.61 Liu W, Cao F, Chen A, et al.Corrosion Science,2010,52,627.62 Liu W, Cao F, Jia B, et al.Corrosion Science,2010,52,639.63 Tokuda S, Muto I, Sugawara Y, et al.Corrosion Science,2017,129,126.64 Bakhsheshi-Rad H R, Hamzah E, Low H T, et al. Materials Science and Engineering: C,2017,73,215.65 Xu B S.Materials China,2014,33(7),405(in Chinese).徐滨士. 中国材料进展,2014,33(7),405.
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2021, Vol. 35 
