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材料导报  2020, Vol. 34 Issue (11): 11009-11021    https://doi.org/10.11896/cldb.19030036
  材料与可持续发展（三）——环境友好材料与环境修复材料* |
基于天然贻贝仿生制备聚多巴胺改性石墨烯基功能材料及其水体环境修复应用研究进展
朱武青1,2, 全海燕2, 彭叔森1, 张敏2, 陈东初2, 户华文2,3,4
1 南昌航空大学材料科学与工程学院,南昌 330063
2 佛山科学技术学院材料科学与能源工程学院,佛山 528000
3 中国科学院广州能源所广东省新能源和可再生能源研究开发与应用重点实验室,广州 510640
4 广东省石油与精细化工研究院广东省工业表面活性剂重点实验室,广州 510640
Recent Advances in Mussel-inspired Polydopamine-modified Graphene-based Functional Materials and Their Applications in Waterborne Environmental Remediation
ZHU Wuqing1,2, QUAN Haiyan2, PENG Shusen1, ZHANG Min2, CHEN Dongchu2, HU Huawen2,3,4
1 College of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
2 School of Materials Science and Energy Engineering, Foshan University, Foshan 528000, China
3 Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
4 Guangdong Provincial Key Laboratory of Industrial Surfactant, Guangdong Research Institute of Petrochemical and Fine Chemical Engineering, Guangzhou 510640, China
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摘要 全球水污染问题日益严峻,而石墨烯具有大比表面积且除污性能优异,可作为水体环境修复的优良材料,但它的表面能高,极易发生团聚,这将会大大降低其比表面积和其他优异的物理化学性质。为此,受天然贻贝及其分泌的粘性蛋白结构所启发,将仿生聚多巴胺(Pdop)用于改性石墨烯可有效解决石墨烯聚集的问题,并能赋予石墨烯新的表面性质和功能,如从疏水表面变成亲水表面、增加活性位点密度以及丰富其可设计性,这也使得Pdop改性石墨烯(Pdop-G)成为当前的一大研究热点,尤其在环境修复领域。
   本文回顾了近三年Pdop-G及其相关材料的多种设计、制备方法,并重点关注了Pdop-G在环境修复应用方面的研究进展,包括三种核心环境修复处理手段(即吸附、膜截留和光催化)。通过总结相关文献可知,Pdop-G及其相关材料在处理各类水体环境污染物方面具有良好的应用潜力,但是要达到商业应用的要求,还有待进一步改善制备工艺,完善后处理等问题。本文充分评述和分析了基于石墨烯化学和贻贝仿生学的各种环境修复材料和技术的优缺点,并提出了未来可尝试的研究方向,以明晰这些材料在环境修复中的应用范围和技术发展路线。本文有望给广大学者在Pdop-G及其相关材料研究方面提供指引,并为新型高性能石墨烯基环境修复材料的设计带来新思路和方向。
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朱武青
全海燕
彭叔森
张敏
陈东初
户华文
关键词:  仿生聚多巴胺  石墨烯  吸附  膜截留  光催化  环境修复    
Abstract: The global water pollution problem is becoming increasingly serious. Graphene can be a good choice for designing and fabricating various graphene-based functional materials due to its large specific surface area and excellent decontamination performance. However, graphene sheets readily aggregate and agglomerate themselves, causing a loss of their fabulous properties. It is therefore necessary to modify the surface of graphene to make it dispersible in various water media. Inspired from naturally occurring mussel and its excreted adhesive protein, the chemical modifications of graphene can thus be efficiently achieved based on such a natural way. The resulting polydopamine (Pdop)-modified graphene (Pdop-G) exhibits excellent dispersibility, facilitating its further manufacturing through facile solution-based routes. Such modification also enables the generation of more active sites for diverse applications, and a versatile platform can be provided as well due to the modification. As a consequence, Pdop-G has captured the focus of much attention for various applications, especially environmental remediation.
This paper reviews the design and preparation methods of Pdop-G and related materials over the past three years, and special attention is placed on the research status in environmental remediation applications using a diversity of Pdop-G-based functional materials, mainly including three critical strategies (i.e., adsorption, membrane filtration and photocatalysis). This literature review shows that Pdop-G and related materials have great application potential in dealing with water contaminants, but it is necessary to improve the preparation and manufacturing processes, post-treatment strategies, and other conditions to achieve commercial applications. This review paper sufficiently comments on the merits and demerits of using graphene chemistry, mussel-inspired biomimetic chemistry, and the corresponding technologies for environmental remediation applications, and also suggests the research directions on which future efforts can be put, in order to clarify the scope of applications and the routes to developing technologies. We hope this review paper can provide a guide for researchers when concerning the bio-inspired modification of graphene and the resulting modified graphene-based functional materials for various applications, especially environmental remediation. It is also highly expected that innovative ideas and new research directions will be obtained as a result of this review contribution.
Key words:  polydopamine    graphene    adsorption    membrane filtration    photocatalysis    environmental remediation
                    发布日期:  2020-05-13
ZTFLH:  TQ042  
基金资助: 国家自然科学基金青年科学基金(51702050);广东省教育厅特色创新基金(2017KTSCX188);广东省新能源和可再生能源研究开发与应用重点实验室开放基金(Y807s31001);广东省工业表面活性剂重点实验室开放基金(GDLS-01-2019);佛山科学技术学院特聘教授
通讯作者:  huawenhu@126.com   
作者简介:  朱武青,2017年6月毕业于南昌航空大学,获得理学学士学位。现为南昌航空大学材料科学与工程学院和佛山科学技术学院材料科学与能源工程学院联合培养的硕士研究生,在户华文教授、陈东初教授和彭叔森博士共同指导下进行研究。目前主要研究领域为仿生合成石墨烯基功能材料及其环境修复应用。
户华文,佛山科学技术学院材料科学与能源工程学院副教授、硕士研究生导师。2015年9月在中国香港理工大学材料科学专业取得博士学位,2015—2016年继续在中国香港理工大学进行博士后研究工作,2016年7月入职佛山科学技术学院,并于2018年入选广东省珠江人才计划青年拔尖人才,主要从事低维功能材料及其能源、催化、传感和环境修复应用研究。近年来,在低维纳米材料相关领域发表论文60余篇,包括Advanced Functional Materials、Journal of Materials Chemistry A、Biosensors and Bioelectronics、Nano Research、Chemical Communications、ACS Sustainable Chemistry and Engineering和ACS Applied Nano Materials等,论文共被引1 580余次,h指数为22,i10指数为35。
引用本文:    
朱武青, 全海燕, 彭叔森, 张敏, 陈东初, 户华文. 基于天然贻贝仿生制备聚多巴胺改性石墨烯基功能材料及其水体环境修复应用研究进展[J]. 材料导报, 2020, 34(11): 11009-11021.
ZHU Wuqing, QUAN Haiyan, PENG Shusen, ZHANG Min, CHEN Dongchu, HU Huawen. Recent Advances in Mussel-inspired Polydopamine-modified Graphene-based Functional Materials and Their Applications in Waterborne Environmental Remediation. Materials Reports, 2020, 34(11): 11009-11021.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19030036  或          http://www.mater-rep.com/CN/Y2020/V34/I11/11009
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