高速电弧喷涂FeAlCrTiC涂层组织结构及耐磨、耐腐蚀性能

doi:10.11896/cldb.18060183

材料导报

2019, Vol. 33

Issue (16): 2771-2776 https://doi.org/10.11896/cldb.18060183

金属与金属基复合材料

高速电弧喷涂FeAlCrTiC涂层组织结构及耐磨、耐腐蚀性能

周治文¹, 江旭东¹, 黄朴¹, 陈孝阳¹, 韦德满¹, 许征兵^{1, 2,}

1 广西大学广西有色金属及特色材料加工重点实验室,南宁 530004
2 广西大学广西生态型铝产业协同创新中心,南宁 530004

Microstructure, Wear and Corrosion Resistance of FeAlCrTiC Coatings Prepared by High-velocity Arc Spraying

ZHOU Zhiwen¹, JIANG Xudong¹, HUANG Pu¹, CHEN Xiaoyang¹, WEI Deman¹, XU Zhengbing^1,2 1

Guangxi Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi University, Nanning 530004
2 Center of Ecological Collaborative Innovation for Aluminum Industry in Guangxi, Guangxi University, Nanning 530004

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摘要采用高速电弧喷涂技术,在45钢表面制备FeAlCrTiC耐磨耐腐蚀涂层。采用光学显微镜、扫描电镜、X射线光电子能谱仪、X射线衍射仪、洛氏硬度计、销盘式磨粒磨损试验机、万能试验机及电化学工作站对涂层的微观结构和性能进行研究和分析。结果表明:高速电弧喷涂制备的FeAlCrTiC涂层具有典型的紧密层状堆叠结构,含有晶体相、氧化物和少量非晶体相;涂层内部的孔隙率低,平均值仅为5.36%;涂层与基体的主要结合方式为机械结合,结合强度高,达到了40.56 MPa;涂层表面的洛氏硬度为45.5HRC,涂层的相对耐磨性达到了1.776;涂层的自腐蚀电位相比基体提高了113.8 mV,耐腐蚀性能较好。

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关键词: 高速电弧喷涂 FeAlCrTiC 组织耐磨耐腐蚀

Abstract: FeAlCrTiC wear-resistant and corrosion-resistant coatings were prepared on the substrate of 45 steel by using high-velocity arc spraying (HVAS) technology. The microstructures and properties of the coatings were studied and analyzed by optical microscope, SEM, X-ray photo-electron spectroscopy, X-ray diffractometer, Rockwell hardness tester, pin-disc abrasive wear testing machine, universal testing machine and electrochemical workstation. The results show that the FeAlCrTiC coatings have a typical tight layered structure, and contain crystalline and oxide and little amorphous phases. The average value of internal porosity of coating is 5.36%. The main combination between coating and substrate are mechanical combination. The bonding strength between coating and matrix reaches 40.56 MPa. The Rockwell hardness of the coating surface is 45.5HRC. The relative wear resistance of the coating reaches 1.776. The self-corrosion potential of the coating is 113.8 mV higher than that of the substrate, which lead to better corrosion resistance performance.

Key words: high-velocity arc spraying FeAlCrTiC microstructure wear resistance corrosion resistance

发布日期: 2019-07-12

ZTFLH:

TG178

基金资助: 国家自然科学基金(51401057);“铝合金材料先进加工技术”八桂学者专项经费;广西有色金属及特色材料加工重点实验室青年基金(GXYSYF1808);广西研究生教育创新计划(YCSW2018054)

作者简介: 周治文,广西大学硕士研究生。2012年9月至2016年7月,在黑龙江科技大学获得材料成型及控制工程专业工学学士学位,2016年9月至今,就读广西大学材料加工工程专业,攻读硕士学位。主要从事超音速电弧喷涂表面耐磨损和耐腐蚀研究。
许征兵,广西大学副教授,硕士生导师,2010年在西北工业大学凝固技术国家重点实验室材料加工工程专业获博士学位。长期从事有色金属材料加工理论与工艺研究,目前研究领域主要是铝合金的熔体处理和加工技术以及表面工程的研究。近五年来主持国家自然科学基金项目1项,省部级项目2项,第一或通讯作者发表论文20余篇,以第一发明人申请发明专利4项。

引用本文:

周治文, 江旭东, 黄朴, 陈孝阳, 韦德满, 许征兵. 高速电弧喷涂FeAlCrTiC涂层组织结构及耐磨、耐腐蚀性能[J]. 材料导报, 2019, 33(16): 2771-2776.
ZHOU Zhiwen, JIANG Xudong, HUANG Pu, CHEN Xiaoyang, WEI Deman, XU Zhengbing 1. Microstructure, Wear and Corrosion Resistance of FeAlCrTiC Coatings Prepared by High-velocity Arc Spraying. Materials Reports, 2019, 33(16): 2771-2776.

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http://www.mater-rep.com/CN/10.11896/cldb.18060183 或 http://www.mater-rep.com/CN/Y2019/V33/I16/2771

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