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材料导报  2019, Vol. 33 Issue (11): 1869-1874    https://doi.org/10.11896/cldb.17110051
  无机非金属及其复合材料 |
酸雨环境下混凝土结构性能研究综述
曹琛, 郑山锁, 胡卫兵
西安建筑科技大学土木工程学院,西安 710055
A Survey on Concrete Structure Properties Under Acid Rain Erosion
CAO Chen, ZHENG Shansuo, HU Weibing
School of Civil Engineering, Xi’an University of Architecture and Technology, Xi’an 710055
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摘要 近年来,随着全球人口剧增、城市化进程以及现代工业化进程的加快,两大主要化石燃料能源——煤和石油的消耗量日益增加,同时煤和石油在燃烧过程中产生大量硫和氮的氧化物等,这些氧化物排放到大气中将生成二次污染物硫酸和硝酸,生成的二次污染物和硝酸再遇雨、雪、雾等而形成酸雨。我国是世界上第三大酸雨区,酸雨对水生生态系统、陆生生态系统、人体健康、建筑物等均有很大的危害,给世界各国造成了巨大的经济损失,成为全球性的重大环境问题。混凝土结构因具有取材方便、可模性好、价格低廉、抗压强度高及耐火性好等优点被广泛应用,已成为我国最主要的结构形式之一。但由于混凝土材料中存在大量碱性化合物,可与酸雨发生中性化反应,导致其表面硬化水泥溶解,材料表面变质,进而引起其物理力学性能的劣化。同时,钢筋表面钝化膜由于混凝土碱性下降而发生锈蚀,锈蚀物的产生使混凝土构件膨胀,并产生裂缝,最终使混凝土结构失效。酸雨对混凝土结构耐久性的劣化影响已引起众多学者的关注。目前,国内外学者对酸雨侵蚀混凝土的研究主要集中于:(1)酸雨对水泥混凝土的腐蚀机理及劣化规律的研究;(2)酸雨侵蚀介质、pH值以及矿物掺合料的种类等对混凝土材料及构件侵蚀性能的影响;(3)不同酸雨侵蚀加速试验方法的研究,但此方面研究仍较少,尤其是结构户外暴露试验研究;(4)酸雨侵蚀混凝土结构的静态、动态力学性能的研究,这一方面的研究亦相对较少,目前国内外仍缺乏系统的研究报道。因此,为了明确酸雨对混凝土结构的侵蚀行为,本文对近30年国内外有关酸雨对混凝土耐久性影响的研究报道进行了评述,重点讨论了酸雨对混凝土结构静态及动态力学性能的影响。首先详述了酸雨对混凝土材料的腐蚀机理和劣化过程,其次总结了酸雨加速腐蚀试验方法以及酸雨对混凝土结构力学性能影响的相关研究;最后讨论了当前有关酸雨侵蚀混凝土研究的一些重要问题,并对今后需进一步研究的问题提出了建议。
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曹琛
郑山锁
胡卫兵
关键词:  酸雨  混凝土结构  腐蚀机理  耐久性    
Abstract: With the rapid increase of global population, the acceleration of urbanization and modern industrialization, the consumption of coal and oil, two major fossil fuels, has been continuously increased in recent years. A large amount of sulfur and nitrogen oxides will be generated during combustion of the fossil fuels. When these oxides are emitted into the atmosphere, secondary pollutants like sulfuric acid and nitric acid are formed, and finally the acid rain will come into being as they encounter with rain, snow, fog, etc. China is the third largest acid rain area in the world. Acid rain does great harm to aquatic ecosystems, terrestrial ecosystems, human health, buildings and so forth, causing enormous economic losses over the world. Therefore, it has become a major environmental issue that has aroused global concern. Concrete structures have been widely applied because of theirs convenient material extraction, favorable moldability, low price, high compressive strength and satisfactory fire resistance, which is one of the most important structural forms in China. Nevertheless, there are a large amount of basic compounds in concrete material, the neutralization reaction can take place between these basic compounds and acid rain, which leads to the dissolution of surface hardened cement and deterioration of the material surface, and further the degradation of the physical and mechanical properties. Meanwhile, the passivation film on the surface of the steel bars are destroyed due to the decrease of concrete alkalinity, and the steel bars are rusted. The corrosion products make the concrete members to expand and crack, causing the durability failure of the concrete structures. The influence of acid rain on the durability of concrete structures has attracted wide attention. At present, researches on acid rain corrosive concrete by scholars at home and abroad mainly focus on: Ⅰ. corrosion mechanism and deterioration law of acid rain on cement concrete, Ⅱ. the effects of acid rain erosion medium, pH value and the type of mineral admixture on the erosion properties of concrete materials and components, Ⅲ. different methods of accelerated acid rain erosion test. (There are few studies in this area, especially the outdoor exposure test of concrete structures), Ⅳ. the static and dynamic mechanical properties of concrete structures eroded by acid rain. (It still lack intensive study about this aspect). Accordingly, in order to clarify the erosion behavior of acid rain on concrete structures, this article reviews the worldwide researches about the impact of acid rain on the concrete durability in recent 30 years, and focuses on the effects of acid rain on the static and dynamic mechanical pro-perties of concrete structures. Firstly, the corrosion mechanism and deterioration process of acid rain on concrete materials are described in detail. Secondly, the test methods of accelerated acid rain corrosion and the related research work of influence of acid rain on the mechanical properties of concrete structures are summarized. Finally, some important issues concerning the research of acid rain eroding concrete are discussed, and some suggestions for further research are proposed.
Key words:  acid rain    concrete structure    corrosion mechanism    durability
                    发布日期:  2019-05-21
ZTFLH:  TU528  
基金资助: 国家科技支撑计划(2013BAJ08B03);国家自然科学基金(51678475);陕西省重点研发计划(2017ZDXM-SF-093);陕西省教育厅产业化项目(2017JC15);陕西省自然科学基础研究计划-重点项目(2018JZ5002)
通讯作者:  wbh8008@sohu.com   
作者简介:  曹琛,2011年6月毕业于长安大学,获得硕士学位。现为西安建筑科技大学土木工程学院博士研究生,由郑山锁教授和胡卫兵教授联合培养。目前主要从事混凝土结构耐久性及抗震性能的研究胡卫兵,西安建筑科技大学土木工程学院教授、博士生导师,空间结构研究所所长,陕西省振动工程学会副理事长,教育部高等学校力学基础课程教学指导委员会委员。1988年毕业于哈尔滨船舶工程学院土木工程系,获学士学位;1991毕业于西北工业大学飞行器设计专业,获硕士学位;1994年毕业于西北工业大学结构强度专业,获博士学位。研究方向:结构健康检测,结构振动及控制。主持和参加国家自然科学基金面上项目2项及省部级自然科学基金等项目10余项,获省部级科技进步三等奖2项,厅局级科技进步一等奖2项,在国内外学术会议及刊物发表学术论文五十余篇,其中20多篇被EI、SCI摘录。
引用本文:    
曹琛, 郑山锁, 胡卫兵. 酸雨环境下混凝土结构性能研究综述[J]. 材料导报, 2019, 33(11): 1869-1874.
CAO Chen, ZHENG Shansuo, HU Weibing. A Survey on Concrete Structure Properties Under Acid Rain Erosion. Materials Reports, 2019, 33(11): 1869-1874.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.17110051  或          http://www.mater-rep.com/CN/Y2019/V33/I11/1869
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