放射性含钴废水吸附材料的研究进展

doi:10.11896/cldb.24070147

材料导报

2025, Vol. 39

Issue (12): 24070147-9 https://doi.org/10.11896/cldb.24070147

无机非金属及其复合材料

放射性含钴废水吸附材料的研究进展

刘欣颖, 雷雨菡, 张光辉^*, 顾平

天津大学环境科学与工程学院,天津 300354

Research Progress of Adsorption Materials for Radioactive Cobalt-containing Wastewater

LIU Xinying, LEI Yuhan, ZHANG Guanghui^*, GU Ping

School of Environmental Science and Engineering, Tianjin University, Tianjin 300354, China

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摘要随着核技术的快速发展,放射性废水受到关注,作为主要活化腐蚀产物的⁶⁰Co,一旦进入水环境后易对生物和人体造成潜在威胁。吸附法是放射性废水除钴的重要手段之一,其关键在于吸附材料的开发,而目前吸附材料在性能、成本效益、稳定性和再生性等方面仍有较大提升空间。本文以处理放射性含钴废水的吸附材料为主要研究对象,探讨了钴的吸附等温线和吸附动力学,并对无机、有机和生物吸附材料进行了评估和总结,最后对放射性含钴废水吸附材料的开发和工程应用提出了展望。本文指出未来研究应致力于开发新型高效吸附材料、研发配套工艺、深入明晰吸附除钴的规律和机理,采用多种模型和方法更准确地考察吸附过程,以期为除钴吸附材料的开发及关联技术的工程化应用提供参考。

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关键词: 废水放射性吸附材料钴吸附机理

Abstract: With the rapid development of nuclear technology, radioactive wastewater produced from the nuclear facility is increasingly concerned by the public. ⁶⁰Co, the main activated corrosion product in the radioactive wastewater poses a potential threat to both organisms and human health after entering the water environment. Adsorption is one of the crucial methods for the removal of cobalt from radioactive wastewater, and the key lies in the development of adsorption materials. Currently, there remains substantial room for improvement in the performance, cost-effectiveness, stability and recyclability of adsorption materials. In this review, adsorption materials for the removal of cobalt from radioactive wastewater are taken as the main research object, and the adsorption isotherms and kinetics of cobalt are also explored. Inorganic, organic, and biological adsorption materials are evaluated and summarized. Finally, the development and engineering application of adsorption materials for the removal of cobalt from radioactive wastewater are discussed. Future research is suggested to concentrate on developing novel and efficient adsorption materials, creating supporting processes, and further clarifying the principles and mechanisms of cobalt adsorption. Additionally, this review points out that multiple models and approaches should be used to more accurately investigate the adsorption process, aiming to provide insights for the development and engineering application of cobalt removal adsorption materials and related technologies.

Key words: waste water radioactivity adsorption material cobalt adsorption mechanism

出版日期: 2025-06-25 发布日期: 2025-06-19

ZTFLH:	X591
	TL941+.1
	X703.1

基金资助: 天津大学自主创新基金(2024XZY-008);深圳市科技计划项目(CJGJZD20230724093959001)

通讯作者: ^*张光辉,博士,天津大学环境科学与工程学院副教授、硕士研究生导师。目前主要从事膜法水处理、放射性废水处理等方面的研究工作。z_gh@163.com

作者简介: 刘欣颖,天津大学环境科学与工程学院硕士研究生,在张光辉副教授的指导下进行研究,主要研究领域为放射性废水处理技术。

引用本文:

刘欣颖, 雷雨菡, 张光辉, 顾平. 放射性含钴废水吸附材料的研究进展[J]. 材料导报, 2025, 39(12): 24070147-9.
LIU Xinying, LEI Yuhan, ZHANG Guanghui, GU Ping. Research Progress of Adsorption Materials for Radioactive Cobalt-containing Wastewater. Materials Reports, 2025, 39(12): 24070147-9.

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https://www.mater-rep.com/CN/10.11896/cldb.24070147 或 https://www.mater-rep.com/CN/Y2025/V39/I12/24070147

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