锌电池中钴基正极材料的应用现状与挑战

doi:10.11896/cldb.23040024

材料导报

2024, Vol. 38

Issue (6): 23040024-10 https://doi.org/10.11896/cldb.23040024

电化学能源材料与器件

锌电池中钴基正极材料的应用现状与挑战

尚文旭^1,2, 俞文涛¹, 何义¹, 马彦义¹, 谈鹏^1,*

1 中国科学技术大学热科学和能源工程系,合肥 230026
2 深空探测实验室(天都实验室),合肥 230088

Current Status and Challenges in the Application of Cobalt-based Cathode Materials in Zinc Batteries

SHANG Wenxu^1,2, YU Wentao¹, HE Yi¹, MA Yanyi¹, TAN Peng^1,*

1 Department of Thermal Science and Energy Engineering, University of Science and Technology of China (USTC), Hefei 230026, China
2 Deep Space Exploration Laboratory, Hefei 230088, China

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摘要受益于丰富的矿产资源、超高的理论容量和卓越的安全性,水系锌电池成为下一代储能设备的有力竞争者。作为锌电池理想的正极材料候选者,近年来钴基电极材料因其高输出电压、高理论容量和优异的氧化还原能力(Co²⁺↔Co³⁺↔Co⁴⁺)而受到越来越多的关注。虽然研究者对应用于锌空气电池的钴基催化剂进行了文献综述,但是主要集中在单一催化方向,缺乏关于钴基电极材料多功能特性的系统总结。本文介绍了钴基正极材料在锌电池中的多功能特性,结合其氧化还原和氧催化两方面能力,从锌钴电池拓展到复合锌钴电池体系。然后,从两种电池体系中的充放电机理出发,详细介绍了当前锌钴电池中钴基材料的优化策略,以及复合锌钴电池中电极/电解液三相界面的设计方案。最后,本文介绍了当前研究的不足,并对未来研究方向进行了展望。

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关键词: 钴基材料锌钴电池复合锌钴电池

Abstract: Benefiting from abundant mineral resources, ultra-high theoretical capacity and excellent safety, aqueous zinc batteries have become a strong contender for next-generation energy storage devices. As an ideal cathode material candidate for zinc batteries, cobalt-based electrode materials have received increasing attention in recent years due to their high output voltage, high theoretical capacity and excellent redox ability (Co²⁺↔Co³⁺↔Co⁴⁺). Although cobalt-based catalysts applied to zinc-air batteries have been reviewed by researchers, they mainly focus on a single catalytic direction, and a systematic summary of the multifunctional properties of cobalt-based electrode materials is lacking. This review introduces the application of multifunctional properties of cobalt-based cathode materials in zinc batteries, combining both their redox and oxygen catalysis capabilities, expanding from zinc-cobalt batteries to zinc-cobalt hybrid systems. Then, the charging and discharging mechanisms in the two battery systems are introduced, following by the current optimization strategies of cobalt-based materials in zinc-cobalt batteries and the design of electrode/electrolyte three-phase interface in zinc-cobalt hybrid batteries. Finally, this paper introduces the shortcomings of the current research and provides an outlook on future research.

Key words: cobalt-based materials zinc-cobalt battery hybrid zinc-cobalt battery

出版日期: 2024-03-25 发布日期: 2024-04-07

ZTFLH:

TQ152

基金资助: 安徽省自然科学基金(2008085ME155);国家创新人才计划青年项目(GG2090007001);中国科学院人才项目(KJ2090130001);中国科学技术大学启动基金(KY2090000044)

通讯作者: ^*谈鹏,特任教授、博士研究生导师,系执行主任。入选了中国科学院(2018年)、安徽省(2019年)和国家(2020年)人才计划青年项目。主持科技部重点研发计划项目课题、国家自然科学基金、安徽省自然科学基金和企业技术开发项目多项。主要针对电化学能源系统中多场耦合能质传输前沿问题取得了一系列原创性研究成果,在Proc.Natl.Acad.Sci.、Energy Environ.Sci.等国际知名学术期刊上发表SCI论文130余篇,总引用5 000余次,H指数40;申请中国发明专利21项,10项已授权。

作者简介: 尚文旭,深空探测实验室(天都实验室)科研人员,2018年于东北大学获得学士学位,2023年于中国科学技术大学获得博士学位。目前主要研究领域为碱性锌电池正极材料优化设计。

引用本文:

尚文旭, 俞文涛, 何义, 马彦义, 谈鹏. 锌电池中钴基正极材料的应用现状与挑战[J]. 材料导报, 2024, 38(6): 23040024-10.
SHANG Wenxu, YU Wentao, HE Yi, MA Yanyi, TAN Peng. Current Status and Challenges in the Application of Cobalt-based Cathode Materials in Zinc Batteries. Materials Reports, 2024, 38(6): 23040024-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.23040024 或 https://www.mater-rep.com/CN/Y2024/V38/I6/23040024

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