石墨相氮化碳在聚合物电解质膜中的研究进展

doi:10.11896/cldb.23030250

材料导报

2024, Vol. 38

Issue (6): 23030250-7 https://doi.org/10.11896/cldb.23030250

电化学能源材料与器件

石墨相氮化碳在聚合物电解质膜中的研究进展

刘守一, 望宇皓, 刘莉莉, 欧阳云祥, 李娜, 胡朝霞^*, 陈守文

南京理工大学环境与生物工程学院,南京 210094

Research Progress of Graphitic Carbon Nitride in Polymer Electrolyte Membrane

LIU Shouyi, WANG Yuhao, LIU Lili, OUYANG Yunxiang, LI Na, HU Zhaoxia^*, CHEN Shouwen

School of Environmental & Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

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摘要燃料电池因具有能源转换效率高、近零污染、低噪音等优点受到广泛关注。聚合物电解质膜作为燃料电池的重要组成部件之一,其性能优劣决定了电池的实际表现。为解决聚合物电解质膜在稳定性及离子传导率方面存在的不足,无机纳米材料掺杂作为常规的改性手段应用到聚合物电解质膜材料中。近年来,石墨相氮化碳(g-C₃N₄)因其独特的结构特征和优秀的物化性能,被广泛应用于聚合物电解质膜材料的制备和改性。本文主要综述了g-C₃N₄的结构和性质,总结了g-C₃N₄基复合膜的制备方法,重点对目前g-C₃N₄在聚合物电解质膜中的研究和应用情况进行了综述,展示了其在聚合物电解质膜改性方面的重要成果,并对其在该领域未来的发展做出展望。

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	胡朝霞
	陈守文

关键词: 燃料电池聚合物电解质膜无机纳米材料石墨相氮化碳

Abstract: Fuel cells have attracted wide attention due to the high energy conversion efficiency, near-zero pollution and low noise. Polymer electrolyte membrane (PEM) is an important component of fuel cells, its performance determines the practical output of fuel cells. To address the shortcomings of PEMs in terms of stability and ionic conductivity, inorganic nanomaterial doping is applied to PEMs as a conventional modification method. In recent years, graphitic carbon nitride (g-C₃N₄) has been widely used in the preparation and modification of PEMs due to its unique structural characteristics and excellent physic-chemical properties. This review mainly describes the structural properties of g-C₃N₄, summarizes the typical preparation methods of g-C₃N₄-based composite PEMs, focuses on the current research and application of g-C₃N₄, demonstrates its important achievements in the modification aspect, and gives an outlook on its future development in PEMs.

Key words: fuel cell polymer electrolyte membrane inorganic nanomaterial graphitic carbon nitride

出版日期: 2024-03-25 发布日期: 2024-04-07

ZTFLH:	TQ127.1
	TM911.4

基金资助: 中央高校基本科研业务费专项资金(30920021114)

通讯作者: ^*胡朝霞,南京理工大学环境与生物工程学院副教授、博士研究生导师。2001年、2004年上海交通大学高分子材料专业本科、硕士毕业,2007年日本国立山口大学环境工程专业博士毕业。主要研究方向为聚合物电解质膜及其分离技术。主持及参与聚合物电解质膜相关的项目10余项,作为第一/通信作者已在本学科领域高水平期刊Journal of Membrane Science、International Journal of Hydrogen Energy、Applied Surface Science等发表论文40余篇。

作者简介: 刘守一,2018年6月、2021年6月于青岛科技大学获得工学学士学位和硕士学位。现为南京理工大学环境与生物工程学院博士研究生,在陈守文教授和胡朝霞副教授的指导下进行研究。目前主要研究领域为环境功能聚合物电解质膜材料。

引用本文:

刘守一, 望宇皓, 刘莉莉, 欧阳云祥, 李娜, 胡朝霞, 陈守文. 石墨相氮化碳在聚合物电解质膜中的研究进展[J]. 材料导报, 2024, 38(6): 23030250-7.
LIU Shouyi, WANG Yuhao, LIU Lili, OUYANG Yunxiang, LI Na, HU Zhaoxia, CHEN Shouwen. Research Progress of Graphitic Carbon Nitride in Polymer Electrolyte Membrane. Materials Reports, 2024, 38(6): 23030250-7.

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https://www.mater-rep.com/CN/10.11896/cldb.23030250 或 https://www.mater-rep.com/CN/Y2024/V38/I6/23030250

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