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材料导报  2026, Vol. 40 Issue (8): 25050151-7    https://doi.org/10.11896/cldb.25050151
  无机非金属及其复合材料 |
锰基NASICON正极中反占位缺陷的形成机制及调控策略综述
张继聪1,2, 马汝广2,*, 李长明2,*
1 苏州科技大学化学与生命科学学院,江苏 苏州 215009
2 苏州科技大学材料科学与工程学院,江苏 苏州 215009
A Review on Formation Mechanisms and Regulation Strategies of Anti-site Defects in Mn-based NASICON Cathodes
ZHANG Jicong1,2, MA Ruguang2,*, LI Chang Ming2,*
1 School of Chemistry and Life Science, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
2 School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
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摘要 锰基NASICON型正极材料,如磷酸钛锰钠(Na3MnTi(PO4)3),具有高理论容量、稳定的三维骨架结构、快速钠离子传导能力等特性,在钠离子电池领域具有重要应用前景。然而其实际性能受限于Mn的反占位缺陷(ASD),包括材料合成过程中产生的本征ASD(IASD)和充放电过程中产生的衍生ASD(DASD)。本文系统总结了近年来抑制ASD的策略,如电荷补偿、提高缺陷形成能、化学键强化、磷源优化等。这些策略可显著抑制充放电过程中的电压滞后,提升能量密度和循环稳定性。未来研究可以结合原位表征与多策略协同优化,推动高能量密度锰基NASICON正极材料的实用化。
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张继聪
马汝广
李长明
关键词:  钠离子电池  NASICON正极  反占位缺陷  电压滞后    
Abstract: Manganese-based NASICON-type cathode materials, e.g., sodium manganese titanium phosphate (Na3MnTi(PO4)3), have shown significant application potential in sodium-ion batteries due to high theoretical capacity, stable three-dimensional framework structure, and ra-pid sodium-ion conductivity. However, their practical performance is limited by Mn anti-site defects, including intrinsic anti-site defects (IASD) formed during material synthesis and derived anti-site defects (DASD) generated during charge-discharge processes. This review systematically summarizes recent strategies of defect suppression, including charge compensation, increasing defect formation energy, chemical bond reinforcement, and phosphorus source optimization. These approaches effectively mitigate voltage hysteresis during cycling while enhancing energy density and cycling stability. Future research is suggested to focus on integrating in-situ characterization techniques with multi-strategy synergistic optimization to advance the commercialization of high energy-density manganese-based NASICON cathode materials.
Key words:  sodium-ion battery    NASICON cathode    anti-site defect    voltage hysteresis
出版日期:  2026-04-25      发布日期:  2026-05-06
ZTFLH:  TM911  
基金资助: 国家自然科学基金(52172058)
通讯作者:  * 马汝广,博士,苏州科技大学材料科学与工程学院教授。主要致力于实验与理论模拟相结合揭示电化学储能和电催化关键材料的结构-性能关系,尤其在碳基电催化材料方面取得了一系列成果。ruguangma@usts.edu.cn
李长明,博士,苏州科技大学材料科学与工程学院教授,致力于功能纳米材料、高效能量转换机制与应用以及先进生物传感与生物芯片等研究工作。ecmli@usts.edu.cn   
作者简介:  张继聪,苏州科技大学化学与生命科学学院硕士研究生,在李长明教授和马汝广教授的指导下研究钠离子电池正极材料。
引用本文:    
张继聪, 马汝广, 李长明. 锰基NASICON正极中反占位缺陷的形成机制及调控策略综述[J]. 材料导报, 2026, 40(8): 25050151-7.
ZHANG Jicong, MA Ruguang, LI Chang Ming. A Review on Formation Mechanisms and Regulation Strategies of Anti-site Defects in Mn-based NASICON Cathodes. Materials Reports, 2026, 40(8): 25050151-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25050151  或          https://www.mater-rep.com/CN/Y2026/V40/I8/25050151
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