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材料导报  2025, Vol. 39 Issue (24): 24120039-8    https://doi.org/10.11896/cldb.24120039
  金属与金属基复合材料 |
ZrO2陶瓷与金属异质钎焊的研究现状与应用进展
张文叙1,2, 操齐高1,2,*, 孟晗琪2, 汪小钰2, 张波3
1 东北大学材料科学与工程学院,沈阳 110004
2 西北有色金属研究院电子材料研究所,西安 710016
3 西安理工大学材料科学与工程学院,西安 710048
Research Status and Applications of Brazing Between ZrO2 Ceramics and Metals
ZHANG Wenxu1,2, CAO Qigao1,2,*, MENG Hanqi2, WANG Xiaoyu2, ZHANG Bo3
1 School of Materials Science and Engineering, Northeastern University, Shenyang 1100042, China
2 Electonic Materials Research Institute, Northwest Institute for Nonferrous Metal Research, Xi’an 710016, China
3 School of Materials Science and Engineering of Xi’an University of Technology, Xi’an 710048, China
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摘要 ZrO2陶瓷凭借其优异的物理和力学性能,广泛应用于高温结构材料、医疗器械和电子工业等多个领域。然而,由于加工成型困难,常与本身/金属结合形成复合材料。钎焊作为陶瓷与金属异质连接的一种高效技术,已在制造业、建筑工业和航空航天等多个行业取得广泛应用,被认为是最具前景的连接方法之一。但ZrO2陶瓷与金属异质钎焊面临诸多挑战,包括热膨胀系数差异引发的残余应力、润湿性差及界面反应等问题。研究指出,优化钎料成分(如添加钛、锆等活性元素)、选择合适的钎焊方法以及设计合理的工艺参数有助于改善这些问题,提高接头的性能。文章重点介绍了几种常用钎焊方法及钎料,如活性金属钎焊、非晶钎焊、中间层钎焊和辅助钎焊,同时分析了它们的优势与不足。并展望了未来研究方向,认为通过深入研究界面反应、减少残余应力和优化工艺,ZrO2陶瓷与金属钎焊的应用潜力将进一步提升。
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张文叙
操齐高
孟晗琪
汪小钰
张波
关键词:  氧化锆陶瓷  钎焊  异质金属  润湿性  钎料    
Abstract: Zirconia (ZrO2) ceramics are widely used in high-temperature structural materials, medical devices, and the electronics industry due to their excellent physical and mechanical properties. However, processing and forming ZrO2 ceramics pose significant challenges, often necessitating their combination with metals to create composite materials for various applications. Brazing, an efficient method for joining ceramics to metals, is extensively used in industries such as manufacturing, construction, and aerospace, and is regarded as one of the most promising joining techniques. Despite its advantages, brazing ZrO2 ceramics to metals presents several challenges, including residual stresses from mismatched thermal expansion coefficients, poor wettability, and interfacial reactions. Research suggests that optimizing the brazing filler composition (e.g., by adding active elements such as titanium or zirconium), selecting the appropriate brazing method, and designing reasonable process parameters can improve joint performance. This article reviewed several commonly used brazing methods and fillers, including active metal brazing, amorphous brazing, interlayer brazing, and auxiliary brazing, highlighted their respective advantages and limitations. It also discussed future research directions, suggesting that further studies on interfacial reactions, residual stress reduction, and process optimization could significantly improve the application potential of ZrO2 ceramic-metal brazing across various fields.
Key words:  zirconiaceramics    brazing    dissimilar metals    wettability    brazing materials
出版日期:  2025-12-25      发布日期:  2025-12-17
ZTFLH:  TG47  
基金资助: 西北有色金属研究院自开题(09SK24Z14A)
通讯作者:  *操齐高,博士,东北大学大学材料科学与工程学院教授、博士研究生导师。目前主要从事稀贵金属合金粉体制备、合金材料加工技术开发;微纳米贵金属材料研究;稀贵金属资源综合利用等方面的研究工作。50314712@qq.com   
作者简介:  张文叙,东北大学材料科学与工程学院硕士研究生,在操齐高教授的指导下进行研究。目前主要研究领域为钎焊材料研究。
引用本文:    
张文叙, 操齐高, 孟晗琪, 汪小钰, 张波. ZrO2陶瓷与金属异质钎焊的研究现状与应用进展[J]. 材料导报, 2025, 39(24): 24120039-8.
ZHANG Wenxu, CAO Qigao, MENG Hanqi, WANG Xiaoyu, ZHANG Bo. Research Status and Applications of Brazing Between ZrO2 Ceramics and Metals. Materials Reports, 2025, 39(24): 24120039-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24120039  或          https://www.mater-rep.com/CN/Y2025/V39/I24/24120039
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