放电等离子烧结Bi、Ce掺杂钇铁石榴石陶瓷的微观结构与磁性能

doi:10.11896/cldb.22070054

材料导报

2024, Vol. 38

Issue (4): 22070054-5 https://doi.org/10.11896/cldb.22070054

无机非金属及其复合材料

放电等离子烧结Bi、Ce掺杂钇铁石榴石陶瓷的微观结构与磁性能

叶登建, 代波^*

西南科技大学材料科学与工程学院,环境友好能源材料国家重点实验室,四川绵阳 621010

Microstructure and Magnetic Properties of Bi, Ce-YIG Ceramic Sintered by Spark Plasma Sintering

YE Dengjian, DAI Bo^*

State Key Laboratory of Environment-Friendly Energy Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China

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摘要钇铁石榴石(Y₃Fe₅O₁₂,YIG)是一种立方晶体结构的软磁铁氧体材料。YIG具有法拉第效应、低的铁磁共振线宽,在微波磁光领域具有广阔的应用前景。采用球磨法,通过预烧成功制备Y_2.6-xBi_0.4Ce_xFe₅O₁₂ (x=0.1,0.2)粉末,再利用放电等离子烧结(SPS)将其在较低温度下制备成陶瓷。采用X射线衍射仪对陶瓷表面和内层进行了物相分析,采用扫描电子显微镜对粉体和陶瓷形貌进行观察,采用振动样品磁强计对样品进行了静态磁性能测试。实验结果表明,由于Bi元素的掺入,预烧温度降低到1 050 ℃。利用放电等离子烧结方法,在1 050 ℃、60 MPa、保温4 min条件下制备出孔洞少、表观密度为5.358 5 g/cm³和5.446 9 g/cm³的Bi,Ce-YIG陶瓷,实现了Bi,Ce-YIG陶瓷的低温快速烧结。Ce的掺入提高了Y_2.6-xBi_0.4Ce_xFe₅O₁₂ (x=0.1,0.2)粉末陶瓷的饱和磁化强度(分别为23.01 emu/g、25.96 emu/g),有利于磁光器件的小型化。Bi,Ce-YIG陶瓷的铁磁共振线宽最低为140.5 Oe,有利于器件在微波应用中的低损耗。

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关键词: 钇铁石榴石陶瓷放电等离子烧结低温快速烧结静态磁性能

Abstract: Yttrium iron garnet (Y₃Fe₅O₁₂, YIG) is a soft ferrite material with a cubic crystal structure. YIG has the Faraday effect and low ferromagnetic resonance linewidth, so it has broad application prospects in microwave magneto-optics. In this paper, Y_2.6-xBi_0.4Ce_xFe₅O₁₂ (x=0.1, 0.2) powder was successfully prepared by ball milling and pre-sintering, and then prepared into ceramics at lower temperature by spark plasma sintering (SPS). The phase analysis of the ceramic surface and inner layer was carried out by X-ray diffractometer, the morphology of powder and ceramic was observed by scanning electron microscope, and the static magnetic properties of the samples were tested by vibrating sample magnetometer. The experimental results show that the pre-sintering temperature is reduced to 1 050 ℃ due to the incorporation of Bi element. Using spark plasma sintering method, Bi, Ce-YIG ceramics with less pores and apparent densities of 5.358 5 g/cm³ and 5.446 9 g/cm³ were prepared at 1 050 ℃, 60 MPa, and holding time for 4 min. This paper realizes low temperature rapid sintering of YIG ceramics. The incorporation of Ce increases the saturation magnetization of Y_2.6-xBi_0.4Ce_xFe₅O₁₂ (x=0.1, 0.2) powder ceramics. The saturation magnetization of the powder is 23.01 emu/g and 25.96 emu/g, respectively, which is beneficial to the miniaturization of magneto-optical devices. The minimum ferromagnetic resonance linewidth of Bi,Ce-YIG ceramics is 140.5 Oe, which is beneficial to the low loss of the device in microwave applications.

Key words: yttrium iron garnet ceramic spark plasma sintering low temperature rapid sintering static magnetic property

出版日期: 2024-02-25 发布日期: 2024-03-01

ZTFLH:

O737

基金资助: 中国电子科技集团公司第九研究所揭榜挂帅项目(2022SK-007);西南科技大学环境友好能源材料国家重点实验室(21fksy27)

通讯作者: *代波,西南科技大学材料与化学学院教授、博士研究生导师。2005年7月博士毕业于中国科学院物理研究所,2007—2008年英国巴斯大学博士后,2015年美国东北大学作访问学者。长期从事电磁功能材料与器件研究,在Appl.Phys.Lett.等期刊发表SCI收录论文60余篇,授权国家发明专利6项。Daibo@swust.edu.cn

作者简介: 叶登建,2017年6月在成都理工大学获得工学学士学位,现为西南科技大学材料与化学学院硕士研究生,在代波教授的指导下进行研究,主要研究领域为磁性陶瓷。

引用本文:

叶登建, 代波. 放电等离子烧结Bi、Ce掺杂钇铁石榴石陶瓷的微观结构与磁性能[J]. 材料导报, 2024, 38(4): 22070054-5.
YE Dengjian, DAI Bo. Microstructure and Magnetic Properties of Bi, Ce-YIG Ceramic Sintered by Spark Plasma Sintering. Materials Reports, 2024, 38(4): 22070054-5.

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https://www.mater-rep.com/CN/10.11896/cldb.22070054 或 https://www.mater-rep.com/CN/Y2024/V38/I4/22070054

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