纳米TiB2对CoCrFeNiSi高熵合金涂层耐磨与耐蚀性能的影响

doi:10.11896/cldb.23090210

材料导报

2025, Vol. 39

Issue (3): 23090210-9 https://doi.org/10.11896/cldb.23090210

金属与金属基复合材料

纳米TiB₂对CoCrFeNiSi高熵合金涂层耐磨与耐蚀性能的影响

张泽疆, 李新梅^*, 朱春金, 李航, 杨定力

新疆大学机械工程学院,乌鲁木齐 830000

Effect of Nano-TiB₂ on Wear and Corrosion Resistance of CoCrFeNiSi High-entropy Alloy Coating

ZHANG Zejiang, LI Xinmei^*, ZHU Chunjin, LI Hang, YANG Dingli

School of Mechanical Engineering, Xinjiang University, Urumqi 830000, China

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摘要本工作在40Cr表面激光熔覆CoCrFeNiSi-xTiB₂(x=2.5%,5.0%,7.5%,10.0%,质量分数)高熵合金(High-entropy alloy,HEA)复合涂层,对涂层的物相、显微组织、硬度、摩擦磨损和电化学腐蚀性能进行分析,探讨纳米TiB₂陶瓷颗粒对HEA涂层的影响。结果表明,x=2.5%,5.0%,7.5%时涂层物相由双相FCC和BCC组成;x=10.0%时在两相的基础上生成硼化物CrB,涂层显微组织由等轴晶转变为典型的柱状树枝晶。涂层的显微硬度随纳米TiB₂颗粒的增多而提高,x=10.0%时涂层平均硬度达到最高,为HV547.11,约为基体的2.72倍,其硬度提升的主要原因是固溶强化和弥散强化。随TiB₂含量的增加,复合涂层的磨损量明显减少,x=10.0%时磨损失重量仅为0.13 mg。总体来看,TiB₂含量的增加使复合涂层的主要磨损机制从严重磨粒磨损、氧化磨损转变成轻微磨粒磨损、氧化磨损,耐磨性能明显提高。在3.5%NaCl溶液中,x=7.5%时复合涂层的耐蚀性能最佳。

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关键词: 高熵合金(HEA) 激光熔覆纳米陶瓷耐磨性耐腐蚀性

Abstract: CoCrFeNiSi-xTiB₂(x=2.5%, 5.0%, 7.5%, 10.0%, in weight percentage) high-entropy alloy (HEA) composite coatings were laser clad on 40Cr surface. The phase, microstructure, hardness, friction wear, and electrochemical corrosion properties of the coatings were analyzed, and the influence of nano-TIB₂ ceramic particles on the HEA coating was discussed. The results showed that when x=2.5%, 5.0%, 7.5%, the coating phases were composed of biphase FCC and BCC, and when x=10.0%, boride CrB was formed on the basis of the two phases, and the microstructure changed from equiaxial crystals to typical columnar dendrites. The microhardness of the coating increased with the increase of nano-TiB₂ particles. When x=10.0%, the average hardness of the coating reached its maximum value of HV547.11, about 2.72 times higher than that of the substrate. The hardness increase could be ascribed mainly to solid solution strengthening and dispersion strengthening. With the increase of TiB₂ content, the wear loss of the composite coating decreased significantly, and the wear loss was only 0.13 mg by adopting an x value of 10.0%. In general, the increasing addition of TiB₂ results in the conversion of main wear mechanism of the composite coating from severe abrasive wear and oxidation wear into slight abrasive wear and oxidation wear, and an obviously improved wear resistance. In 3.5%NaCl solution, the composite coating with x=7.5% achieved the best wear resistance.

Key words: high-entropy alloy (HEA) laser cladding nano-ceramics wear resistance corrosion resistance

出版日期: 2025-02-10 发布日期: 2025-02-05

ZTFLH:

TG174.4

基金资助: 国家自然科学基金(52161017);新疆维吾尔自治区自然科学基金(2022D01C386)

通讯作者: *李新梅,教授,博士研究生导师,长期从事于材料表面改性技术、材料磨损腐蚀及防护领域的研究工作。lxmxj2009@126.com

作者简介: 张泽疆,新疆大学机械工程学院硕士研究生,在李新梅教授的指导下进行研究,目前主要研究方向为激光熔覆高熵合金。

引用本文:

张泽疆, 李新梅, 朱春金, 李航, 杨定力. 纳米TiB₂对CoCrFeNiSi高熵合金涂层耐磨与耐蚀性能的影响[J]. 材料导报, 2025, 39(3): 23090210-9.
ZHANG Zejiang, LI Xinmei, ZHU Chunjin, LI Hang, YANG Dingli. Effect of Nano-TiB₂ on Wear and Corrosion Resistance of CoCrFeNiSi High-entropy Alloy Coating. Materials Reports, 2025, 39(3): 23090210-9.

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http://www.mater-rep.com/CN/10.11896/cldb.23090210 或 http://www.mater-rep.com/CN/Y2025/V39/I3/23090210

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