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材料导报  2024, Vol. 38 Issue (3): 22050232-6    https://doi.org/10.11896/cldb.22050232
  无机非金属及其复合材料 |
(Si0.2Ti0.2Nb0.2Ta0.2V0.2)C高熵陶瓷的低温制备及吸波性能
张昊, 黄宗玥, 张妍彬, 魏剑*
西安建筑科技大学材料科学与工程学院,西安 710055
Low-temperature Preparation and Microwave Absorbing Properties of (Si0.2Ti0.2Nb0.2Ta0.2V0.2)C High-entropy Ceramic
ZHANG Hao, HUANG Zongyue, ZHANG Yanbin, WEI Jian*
School of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
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摘要 寻求具有良好耐高温及力学性能的新型陶瓷材料是吸波材料领域的研究热点之一。高熵碳化物陶瓷具有高温热稳定性及抗氧化性好等优点,但合成温度高且吸波性能研究较少,限制了其在高温吸波材料领域的应用。本工作采用熔盐法合成了多晶岩盐晶型(Si0.2Ti0.2Nb0.2Ta0.2V0.2)C高熵碳化物陶瓷,研究了其物相组成、微观形貌及吸波特性。结果表明:随着反应温度的升高,样品的衍射峰逐渐锐化,吸波性能明显提高。当反应温度为1 500 ℃时,3.72 GHz时最低反射损耗达-34.68 dB;与已报道的高熵碳化物陶瓷相比,在相同的有效吸收带宽(2.3 GHz)下,涂层厚度减少了13.3%(1.5 mm降低到1.3 mm),其介电损耗主要来源于极化损耗和导电损耗。本工作制备的高熵碳化物陶瓷可以为研究制备新型环境适应、耐高温、抗冲击的高性能单相吸波材料提供新途径。
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张昊
黄宗玥
张妍彬
魏剑
关键词:  高熵碳化物陶瓷  吸波材料  吸波性能  介电损耗  熔盐法    
Abstract: Seeking electromagnetic shielding materials with good physical properties is one of the hot spots in electromagnetic wave absorption. High entropy ceramics have the advantages of high temperature thermal stability and good oxidation resistance, but the high synthesis temperature and lack of research on wave-absorbing properties limit their development in the field of high-temperature wave absorption. In this work, polycrystalline rock salt type (Si0.2Ti0.2Nb0.2Ta0.2V0.2)C high entropy carbide ceramics were synthesized by molten salt method, and their phase composition, microscopic morphology and wave absorption properties were investigated. The results show that the diffraction peak of the sample shar-pened gradually with the increase of the reaction temperature and the absorption performance improved significantly. When the reaction temperature is 1 500 ℃, the lowest reflection loss reaches -34.68 dB at 3.72 GHz. Compared with the reported high-entropy carbide ceramics, the coa-ting thickness is reduced by 13.3% (1.5 mm to 1.3 mm) for the same effective absorption bandwidth (2.3 GHz), and the dielectric loss mainly comes from polarization loss and conductivity loss. The high-entropy carbide ceramics prepared in this paper can provide a new avenue for research on the preparation of new environmentally adapted, high-temperature resistant and shock-resistant high-performance single-phase absor-bing materials.
Key words:  high-entropy carbide ceramic    microwave absorbing material    microwave absorbing performance    dielectric loss    molten salt method
出版日期:  2024-02-10      发布日期:  2024-02-19
ZTFLH:  TB332  
基金资助: 国家自然科学基金面上项目(51578448;52272089);国家自然科学青年基金项目(51308447;52202113);陕西省优秀青年科学基金(2021JC-43);中国博士后面上基金(2021M702550);陕西省教育厅协同创新项目(20JY042);陕西省教育厅自然科学专项(19JK0463)
通讯作者:  *魏剑,西安建筑科技大学材料科学与工程学院副院长,纳米材料研究所所长。2008年博士毕业于西北工业大学材料学院。主要从事导电/热电水泥基复合材料、锂电池材料、导电/纳米纤维与膜材料、低维纳米材料规模制备技术的研究。出版高等学校规划教材2部,发表学术论文70余篇,以第一/通信作者在国际著名期刊发表论文57篇(其中,SCI论文45篇,一区论文25篇,他引总计1 200余次),申请和授权发明专利25项,技术转化9项。weijian@xauat.edu.cn   
作者简介:  张昊,2007年7月、2010年7月于西北大学和西安交通大学获得理学学士和硕士学位,2014年12月于西安交通大学获工学博士学位。现为西安建筑科技大学材料科学与工程学院讲师。目前主要研究领域为纳米材料,功能陶瓷材料,近年发表学术论文4篇,申请发明专利1项。
引用本文:    
张昊, 黄宗玥, 张妍彬, 魏剑. (Si0.2Ti0.2Nb0.2Ta0.2V0.2)C高熵陶瓷的低温制备及吸波性能[J]. 材料导报, 2024, 38(3): 22050232-6.
ZHANG Hao, HUANG Zongyue, ZHANG Yanbin, WEI Jian. Low-temperature Preparation and Microwave Absorbing Properties of (Si0.2Ti0.2Nb0.2Ta0.2V0.2)C High-entropy Ceramic. Materials Reports, 2024, 38(3): 22050232-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.22050232  或          https://www.mater-rep.com/CN/Y2024/V38/I3/22050232
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