Abstract: Nickel slag from nickel smelting process is an important secondary metal resource, which contains 40%—45% of Fe, 32%—36% of SiO2, 1%—11% of MgO, 1%—3% of CaO (mass fraction) and small amounts of nickel, copper, cobalt and other valuable metals. The composition and phase constitution of typical nickel slag were introduced. The technical points and exis-ting problems of typical comprehensive utilization processes like extraction of valuable metals, manufacture of mine filling material, production of glass ceramics, and preparation of building materials from nickel slag were summarized. A new process to produce direct-reduced iron and cementing material simultaneously was proposed. The preliminary research results which have a broad prospect for comprehensive utilization of nickel slag were briefly introduced.
李小明, 沈苗, 王翀, 崔雅茹, 赵俊学. 镍渣资源化利用现状及发展趋势分析*[J]. 《材料导报》期刊社, 2017, 31(5): 100-105.
LI Xiaoming, SHEN Miao, WANG Chong, CUI Yaru, ZHAO Junxue. Current Situation and Development of Comprehensive Utilization of Nickel Slag. Materials Reports, 2017, 31(5): 100-105.
1 何焕华,蔡乔方.中国镍钻冶金[M].北京:中国冶金出版社,2000. 2 Li Xiaoming,Xie Geng,Zhao Junxue,et al.Study on simultaneous production of reduced iron and bonding component from nickel slag[J].Nonferrous Met(Extractive Metallurgy), 2015(12):51(in Chinese). 李小明,谢庚,赵俊学,等. 镍渣直接还原提铁及同时制备胶凝材料的研究[J]. 有色金属(冶炼部分),2015(12):51. 3 王宁,陆军,施捍东. 有色金属工业冶炼废渣－镍渣的综合利用[J]. 环境工程,1994,12(1):58. 4 Pan J, Zheng G L, Zhu D Q, et al. Utilization of nickel slag using selective reduction followed by magnetic separation[J]. Trans Nonferrous Met Soc China,2013,23(11):3421. 5 Wang Yufang.Industrial study and application on recycling valuable metals in nickel leaching slag[J].Copper Eng,2010(2): 44 (in Chinese). 王玉芳.回收镍浸出渣中有价金属的工艺研究及应用[J]. 铜业工程, 2010(2):44. 6 Bai Yangui,Zhu Guoilng,Zhang Boting.Fundamental study on extracting iron from Jinchuan waste Ni-refining slag[J].J Iron Steel Res,1994(S1):65 (in Chinese). 白彦贵,朱果灵,张柏汀. 金川提镍弃渣提铁基础研究[J]. 钢铁研究学报,1994(S1):65. 7 Guo Yaguang,Zhu Rong,Wang Yun,et al.The fundamental research to extract iron from the nickel slag by smelting reduction process [J].Ind Heating,2015,44(6):40 (in Chinese). 郭亚光,朱荣,王云,等. 镍渣煤基熔融还原提铁工艺基础研究[J]. 工业加热,2015,44(6):40. 8 Ni Wen,Ma Mingsheng,Wang Yali,et al.Thermodynamic and kine-tic in recovery of iron from nickel residue[J]. J University of Science and Technology Beijing, 2009,31(2): 163 (in Chinese). 倪文,马明生,王亚利,等.熔融还原法镍渣炼铁的热力学与动力学[J].北京科技大学学报, 2009, 31(2):163. 9 鲁逢霖. 金川镍渣直接还原磁选提铁实验研究[J]. 酒钢科技,2014(3):1. 10 Liu Hongxiong.Study on high temperature thermal energy utilization in the production of iron from nickel slag[J].Energy Eng,2007(6): 54(in Chinese). 刘宏雄. 关于镍渣提铁生产的高温热能利用的探讨[J]. 能源工程, 2007(6): 54. 11 Dong Haigang,Guo Yufeng,Jiang Tao,et al.Study on recovering magnetite from nickel metallurgical residue with iron[J].Mining Metall Eng, 2008,28(1): 37(in Chinese). 董海刚,郭宇峰,姜涛,等.从含铁镍冶金渣中回收磁铁矿的研究[J]. 矿冶工程, 2008,28(1):37. 12 Lu Xuefeng,Nan Xueli,Guo Xin,et al.Study on smelting Si-Ca alloy from nickel slag[J].Conservation Utilization Mineral Resources,2009(2): 55 (in Chinese). 卢学峰,南雪丽,郭鑫. 利用镍渣冶炼回收硅钙合金的研究[J]. 矿产保护与利用,2009(2): 55. 13 Ge Yanlin,Cui Jinpeng.Application of nickel slag in high silicon silicomanganese production[J].Ferro-Alloys,2009(5):1 (in Chinese). 葛衍琳,崔金鹏. 镍渣在高硅锰硅合金生产中的应用[J]. 铁合金,2009(5):1. 14 Liu Weibo.Tentative study of extracting iron from nickel slag at Jinchuan Corp[D].Xi’an:Xi’an University of Architecture and Technology ,2001(in Chinese). 刘伟波. 金川炼镍渣提铁的试验研究[D].西安:西安建筑科技大学,2001. 15 Yang Zhiqiang,Gao Qian,Wang Yongqian,et al.Experimental study on new filling cementing material using water-hardening nickel slag tailings of Jinchuan Mine[J].Chin J Geotechnical Eng,2014,36(8):1498 (in Chinese). 杨志强,高谦,王永前,等.利用金川水淬镍渣尾砂开发新型充填胶凝剂试验研究[J]. 岩土工程学报,2014,36(8):1498. 16 Gao Shujie,Ni Wen,Li Keqing,et al.Preparation and hydrated mecha-nism of mine filling material of water-granulated secondary nickel slag[J].J Chin Ceram Soc,2013,41(5):612 (in Chinese). 高术杰,倪文,李克庆,等. 用水淬二次镍渣制备矿山充填材料及其水化机理[J]. 硅酸盐学报,2013,41(5):612. 17 Liu Guanglong.Comprehensive utilization of secondary resource of Jinchuan group company[J].China Mine Eng,2004,32(2):39 (in Chinese). 刘广龙.金川集团公司二次资源综合利用[J].中国矿山工程, 2004,32(2):39. 18 Zhou Qi,Nan Xueli,Yi Yuqiang.Preparation of glass-ceramics with nickel slag and recovery of iron form nickel slag[J].J Lanzhou University of Technology,2010,36(5):14 (in Chinese). 周琦,南雪丽,易育强.镍渣微晶玻璃制备及铁的回收利用[J].兰州理工大学学报,2010,36(5):14. 19 Wang Zhongjie, Ni Wen, Jia Yan, et al. Crystallization behavior of glass ceramics prepared from the mixture of nickel slag, blast furnace slag and quartz sand[J]. J Non-Crystalline Solids, 2010,356:1554. 20 Gao Shujie.Preparation and heat-treatment schedules of glass-cera-mics with nickel smelting de-iron slag[D].Beijing:University of Scie-nce & Technology Beijing,2015(in Chinese). 高术杰. 熔态提铁二次镍渣制备微晶玻璃及热处理制度研究[D].北京:北京科技大学,2015. 21 Nan Xueli.Preparation of glass-ceramics[D].Lanzhou:Lanzhou University of Technology,2006(in Chinese). 南雪丽. 微晶玻璃的研制[D].兰州:兰州理工大学,2006. 22 王中杰,倪文,伏程红,等. 镍渣-高炉矿渣微晶玻璃的制备与研究[J]. 矿物学报,2010(S1):54. 23 Wang Yali,Ni Wen,Zhang Jinrui,et al.[J].Effect of CaO/SiO2 on crystallization of glass ceramic made from nickel slag[J].Met Mine, 2008(1): 138 (in Chinese). 王亚利,倪文,张锦瑞,等.镍渣提铁及熔渣制备微晶玻璃的研究[J]. 金属矿山, 2008(1): 138. 24 Li Keqing,Su Shengnan,Ni Wen,et al.Experimental research on extracting iron and making glass-ceramics building materials products by using slag[J].J University of Science and Technology Beijing,2006,28(11):1034 (in Chinese). 李克庆,苏圣南,倪文,等.利用冶炼渣回收铁及生产微晶玻璃建材制品的实验研究[J]. 北京科技大学学报,2006,28(11):1034. 25 徐彬,张天石,邓国柱,等.用镍矿渣生产建筑砌块研究[J]. 环境工程, 1998,16(4): 63. 26 Yu Tao,Cao Deguang,Liu Wenwei,et al.Some factors affecting the compressive strength of nickel slag autoclaved product[J].New Build Mater,2013, 40(7): 56 (in Chinese). 余涛,曹德光,刘文威,等.影响镍渣蒸压制品抗压强度的因素研究[J]. 新型建筑材料, 2013, 40(7): 56. 27 Shan Changfeng,Wang Jian,Zheng Jinfu,et al.Study on application of nickel slag in cement concrete[J].Bull Chin Ceram Soc, 2012, 31(5): 1263 (in Chinese). 单昌锋,王键,郑金福,等.镍渣在混凝土中的应用研究[J]. 硅酸盐通报, 2012, 31(5):1263. 28 Yu Cheng.Application of nickel slag in cement concrete[J].Fujian Build Mater,2015(8):19(in Chinese). 余铖. 镍渣在混凝土中的应用[J]. 福建建材,2015(8):19. 29 Tang Tianjiao.Study on application of nickel slag in cement concrete[J].Ready-Mixed Concr,2014(2):49 (in Chinese). 唐天佼. 镍渣在混凝土中的应用研究[J]. 商品混凝土,2014(2):49. 30 宗浩,吴波玲,谢小元. 镍渣粉在混凝土中作矿物掺和料的应用研究[J]. 混凝土世界,2015(2):76. 31 王习东,赵大伟,张作泰,等.一种利用镍渣提铁和制备纤维的方法:中国,CN201210050302.0[P].2012-07-18. 32 Lin Liang,Yu Yan.A study on the surface physicochemical properties of modified nickel slag adsorbent to remove Pb2 + and Cu2 + from aqueous solution[J].J Fuzhou University:Nat Sci Ed,2016,44(1):119(in Chinese). 林亮,于岩. 镍渣表面理化特性及对Pb2+与Cu2+的吸附研究[J]. 福州大学学报:自然科学版,2016,44(1):119. 33 孟渊,田斌守,邵继新,等. 利用冶炼工业废弃物镍渣研制混凝土储热材料[J]. 混凝土与水泥制品,2015(2):93.
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