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材料导报  2026, Vol. 40 Issue (5): 25070037-9    https://doi.org/10.11896/cldb.25070037
  生物质助力建筑材料可持续发展 |
风干牦牛粪焚烧灰的制备与活性影响因素研究
王科1, 曹锋1,2,*, 张一鸣1, 徐燕行1
1 青海民族大学土木与交通工程学院,西宁 810000;
2 青海省高原能源与环境工程重点实验室,西宁 810000
Study on the Preparation and Activity Influencing Factors of Dried Yak Manure Incineration Ash
WANG Ke1, CAO Feng1,2,*, ZHANG Yiming1, XU Yanhang1
1 College of Civil and Transportation Engineering, Qinghai Minzu University, Xining 810000, China;
2 Qinghai Provincial Key Laboratory Energy and Environmental Engineering of Plateau, Xining 810000, China
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摘要 风干牦牛粪作为高原农牧区家用生活燃料会产生大量的焚烧灰,将其作为生活垃圾处理会造成严重的资源浪费与环境压力。以自然焚烧的牦牛粪灰渣为原料,通过研磨、煅烧工艺制备出一种具有潜在活性的生物质掺合料风干牦牛粪焚烧灰(DYMIA)。首先,对DYMIA的制备条件进行正交试验设计,制备了27种条件下的DYMIA。其次,对不同制备条件下的DYMIA进行了表观形貌与微观形貌分析,对DYMIA的物相组成及结晶度进行了分析计算,对DYMIA的粒径分布进行了测试。最后,采用响应面优化设计和质心正交理论的方法对DYMIA的活性影响参数进行了优化分析,基于灰熵关联分析方法确定了DYMIA活性影响参数的主次顺序。结果表明,在煅烧温度为600 ℃、煅烧时长为5 h、研磨时长为3 h的制备条件下,DYMIA的结晶度最小、粒度最细、活性最高,其SiO2含量达58.6%,平均粒径为2.77 μm,相对活性指数高达66.79%。煅烧温度对DYMIA的活性影响程度最高,在制备过程中应该重点控制。
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王科
曹锋
张一鸣
徐燕行
关键词:  风干牦牛粪焚烧灰  正交试验  活性  响应面优化  灰熵关联分析    
Abstract: The utilization of air-dried yak dung as domestic fuel in high-altitude pastoral regions generates substantial combustion ash. Disposing of this material as general waste represents a significant waste of resources and creates considerable environmental pressure. Dried yak manure incineration ash (DYMIA), a potentially active biomass admixture, was synthesized from naturally combusted yak dung ash through the processes of grinding and calcination. First an orthogonal experimental design was conducted to prepare DYMIA under 27 different conditions. Subsequently the DYMIA samples prepared under varying conditions were subjected to analyses, including assessments of its macro- and micro-structural morphology, phase composition, crystallinity, and particle size distribution. Finally the parameters influencing the activity effect of DYMIA were optimized using response surface optimization combined with centroid orthogonal theory, while the order of its primary and secondary order was determined through grey relational analysis. The results indicate that DYMIA prepared under the conditions of a calcination temperature of 600 ℃, a calcination duration of 5 h, and a grinding time of 3 h exhibited the lowest crystallinity, the finest particle size, and the highest reactivity. Among which, the resulting sample contained 58.6% SiO2, exhibited a median particle size of 2.77 μm, and achieved a relative reactivity index as high as 66.79%. Calcination temperature was identified as the most influential factor affecting the reactivity of DYMIA and should be prioritized as a key control parameter during its preparation.
Key words:  dried yak manure incineration ash (DYMIA)    orthogonal experiment    activity    response surface optimization    grey entropy correlation analysis
出版日期:  2026-03-10      发布日期:  2026-03-10
ZTFLH:  TU502  
基金资助: 青海省重点研发与转化计划(2025-QY-234);西宁市科技计划(2024-Y-6);青海民族大学理工类科学研究面上项目(2024XJMA03)
通讯作者:  *曹锋,博士,青海民族大学土木与交通工程学院副教授、土木水利专业学位管理中心主任、硕士研究生导师。目前主要从事氯氧镁水泥性能调控与设计、严酷环境混凝土结构耐久性、绿色建筑材料与固废资源化利用等方面的研究。caofeng_qhmu@163.com   
作者简介:  王科,青海民族大学土木与交通工程学院硕士研究生,在曹锋副教授的指导下研究绿色建筑材料与固废资源化利用。
引用本文:    
王科, 曹锋, 张一鸣, 徐燕行. 风干牦牛粪焚烧灰的制备与活性影响因素研究[J]. 材料导报, 2026, 40(5): 25070037-9.
WANG Ke, CAO Feng, ZHANG Yiming, XU Yanhang. Study on the Preparation and Activity Influencing Factors of Dried Yak Manure Incineration Ash. Materials Reports, 2026, 40(5): 25070037-9.
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https://www.mater-rep.com/CN/10.11896/cldb.25070037  或          https://www.mater-rep.com/CN/Y2026/V40/I5/25070037
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