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材料导报  2026, Vol. 40 Issue (3): 25020007-7    https://doi.org/10.11896/cldb.25020007
  无机非金属及其复合材料 |
表面活性剂对多孔地聚物孔结构的调控研究
薛斯亭1, 陈曦平1, 罗洪杰1,2,*, 吴林丽1, 姜昊3, 逯奕含1
1 东北大学冶金学院,沈阳 110819
2 教育部材料先进制备技术工程研究中心,沈阳 110819
3 抚顺天成环保科技有限公司,辽宁 抚顺 113001
Study on the Regulation of Porous Geopolymer Pore Structure by Surfactants
XUE Siting1, CHEN Xiping1, LUO Hongjie1,2,*, WU Linli1, JIANG Hao3, LU Yihan1
1 School of Metallurgical Engineering, Northeastern University, Shenyang 110819, China
2 Engineering Research Center of Advanced Materials Preparation Technology, Ministry of Education, Shenyang 110819, China
3 Fushun Tiancheng Environmental Protection Technology Co., Ltd., Fushun 113001, Liaoning, China
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摘要 为优化粉煤灰基多孔地聚物的孔结构,本工作对比了5种表面活性剂对粉煤灰基多孔地聚物孔隙特性及力学性能的影响。结果表明,添加表面活性剂未改变地聚物基体的物相及化学组成,但能够通过降低碱激发剂溶液的表面张力,提升多孔地聚物的泡沫稳定性,进而改善其孔隙结构。基于对孔结构与抗压强度的综合评估,5种表面活性剂的最佳添加量分别为:Meap-k 0.04%、SDS 3%、CTAB 2%、Tween-80 1%以及APG 0.7%。掺加效果优劣降序依次为Meap-k、APG、Tween-80、SDS和CTAB。其中,采用Meap-k最佳添加量制得的试样总孔隙率和通孔率分别达到83.8%和71.4%。本工作通过优化多孔地聚物的孔结构,挖掘其性能潜力,为其在含尘烟气过滤、污水净化等领域的应用提供了可靠的实验依据和理论指导。
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薛斯亭
陈曦平
罗洪杰
吴林丽
姜昊
逯奕含
关键词:  表面活性剂  多孔地聚物  粉煤灰  孔隙率  抗压强度  表面张力    
Abstract: To optimize the pore structure of fly ash-based porous geopolymers, this work compared the effects of five surfactants on the pore characteristics and mechanical properties of fly ash-based porous geopolymers. The results show that the addition of surfactants doesn’t change the phase or chemical composition of the geopolymer matrix but improves the foam stability of the porous geopolymer by reducing the surface tension of the alkaline solution, thereby enhancing its pore structure. Based on a comprehensive evaluation of pore structure and compressive strength, the optimal addition amounts of the five surfactants are as follows:Meap-k 0.04%, SDS 3%, CTAB 2%, Tween-80 1%, and APG 0.7%. The effectiveness of the surfactants, in descending order, is Meap-k, APG, Tween-80, SDS, and CTAB. The sample prepared with the optimal Meap-k amount achieves a total porosity of 83.8% and an open porosity of 71.4%. The findings, by optimizing the pore structure of porous geopolymers, provide reliable experimental evidence for their application in areas such as dust smoke filtration and wastewater treatment.
Key words:  surfactant    porous geopolymer    fly ash    porosity    compressive strength    surface tension
发布日期:  2026-02-13
ZTFLH:  TB321  
基金资助: 2024兴辽英才计划创新团队项目(XLYC2404034);“抚顺英才计划”“带土移植”创新团队项目(FSYC202301002)
通讯作者:  *罗洪杰,博士,东北大学冶金工程学院教授、博士研究生导师。目前主要从事轻金属泡沫、多孔材料等方面的研究。   
作者简介:  薛斯亭,东北大学冶金工程学院硕士研究生,在罗洪杰教授的指导下进行研究。目前主要研究领域为多孔材料。
引用本文:    
薛斯亭, 陈曦平, 罗洪杰, 吴林丽, 姜昊, 逯奕含. 表面活性剂对多孔地聚物孔结构的调控研究[J]. 材料导报, 2026, 40(3): 25020007-7.
XUE Siting, CHEN Xiping, LUO Hongjie, WU Linli, JIANG Hao, LU Yihan. Study on the Regulation of Porous Geopolymer Pore Structure by Surfactants. Materials Reports, 2026, 40(3): 25020007-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25020007  或          https://www.mater-rep.com/CN/Y2026/V40/I3/25020007
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