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材料导报  2026, Vol. 40 Issue (10): 25060055-10    https://doi.org/10.11896/cldb.25060055
  无机非金属及其复合材料 |
固体氧化物燃料电池金属连接体尖晶石涂层研究进展
刘畅1,2,3, 王东梅1,2,3,*, 卞刘振1,2,3, 杨礼林1,2,3, 彭继华1,2,3, 安胜利1,2,3, 朱可晟1,2,3, 贾金朝1,2,3
1 内蒙古科技大学材料科学与工程学院,内蒙古 包头 014010
2 内蒙古自治区先进陶瓷材料与器件重点实验室,内蒙古 包头 014010
3 轻稀土资源绿色提取与高效利用教育部重点实验室(内蒙古科技大学),内蒙古 包头 014010
Research Progress on Spinel Coating of Metal Interconnectors for Solid Oxide Fuel Cells
LIU Chang1,2,3, WANG Dongmei1,2,3,*, BIAN Liuzhen1,2,3, YANG Lilin1,2,3, PENG Jihua1,2,3, AN Shengli1,2,3, ZHU Kesheng1,2,3, JIA Jinzhao1,2,3
1 School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, Inner Mongolia, China
2 Inner Mongolia Key Laboratory of Advanced Ceramic Material and Devices, Baotou 014010, Inner Mongolia, China
3 Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources (Inner Mongolia University of Science and Technology), Ministry of Education, Baotou 014010, Inner Mongolia, China
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摘要 固体氧化物燃料电池(Solid oxide fuel cells,SOFC)具有能量转化效率高、零排放等优点,应用前景广阔。金属连接体作为SOFC的重要组件,其中铁素体不锈钢由于价格低廉、热膨胀系数匹配性较好等优点成为了最受欢迎的金属连接体材料。但其在SOFC运行过程中会面临Cr的挥发与扩散,严重影响了电池的使用性能。尖晶石保护涂层作为连接体表面改性技术之一展现出良好的性能,引起了人们的广泛重视。本文综述了近年来Mn-Co、Cu-Mn、Cu-Fe、Ni-Fe、Ni-Co基尖晶石涂层的成分设计和制备方法对涂层电导率、热膨胀系数匹配性、抗氧化性能、涂层质量与结合情况等的影响,指出存在的问题和解决方法,以期为SOFC连接体涂层的设计、制备及应用提供参考。
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刘畅
王东梅
卞刘振
杨礼林
彭继华
安胜利
朱可晟
贾金朝
关键词:  固体氧化物燃料电池(SOFC)  金属连接体  尖晶石涂层  成分设计  制备方法    
Abstract: Solid oxide fuel cells (SOFC) present considerable promise for widespread applications due to their high energy conversion efficiency and zero emissions. Metallic interconnects constitute critical components of SOFC, among which ferritic stainless steel has emerged as the predominant interconnect material owing to its cost-effectiveness and compatible thermal expansion coefficient. However, during the operation of SOFC, the interconnect experiences chromium volatilization and diffusion, which severely degrades cell performance. As one of the surface modification technologies of interconnects, spinel protective coatings demonstrate exceptional protective capabilities, garnering considerable research attention. This review summarizes the effects of composition design and preparation methods of Mn-Co, Cu-Mn, Cu-Fe, Ni-Fe and Ni-Co-based spinel coatings on the conductivity, thermal expansion coefficient compatibility, oxidation resistance, coating quality and adhesion in recent years. Current challenges and mitigation strategies are discussed, ultimately providing practical guidelines for the design, preparation and application of high-performance SOFC interconnect coatings.
Key words:  solid oxide fuel cells (SOFC)    metallic interconnect    spinel coating    composition design    preparation method
发布日期:  2026-06-03
ZTFLH:  TQ174  
基金资助: 内蒙古自治区自然科学基金面上项目(2025MS05105);内蒙古自治区重点研发和成果转化计划项目(2023YFHH0042);内蒙古自治区直属高校基本科研业务费项目(2023QNJS036;2023QNJS156;2024XKJX010)
通讯作者:  *王东梅,内蒙古科技大学材料科学与工程学院讲师、硕士研究生导师。目前主要从事新能源相关的金属材料组织与性能调控等方面的研究。wangdm6@126.com   
作者简介:  刘畅,内蒙古科技大学材料科学与工程学院硕士研究生,在王东梅讲师的指导下研究新能源相关金属涂层材料。
引用本文:    
刘畅, 王东梅, 卞刘振, 杨礼林, 彭继华, 安胜利, 朱可晟, 贾金朝. 固体氧化物燃料电池金属连接体尖晶石涂层研究进展[J]. 材料导报, 2026, 40(10): 25060055-10.
LIU Chang, WANG Dongmei, BIAN Liuzhen, YANG Lilin, PENG Jihua, AN Shengli, ZHU Kesheng, JIA Jinzhao. Research Progress on Spinel Coating of Metal Interconnectors for Solid Oxide Fuel Cells. Materials Reports, 2026, 40(10): 25060055-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25060055  或          https://www.mater-rep.com/CN/Y2026/V40/I10/25060055
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