无钴共晶高熵合金研究进展

doi:10.11896/cldb.24050218

材料导报

2025, Vol. 39

Issue (11): 24050218-10 https://doi.org/10.11896/cldb.24050218

金属与金属基复合材料

无钴共晶高熵合金研究进展

薛云龙^1,*, 田康康¹, 刘虎林¹, 伍媛婷¹, 袁亮², 高中堂³

1 陕西科技大学陕西省无机材料绿色制备与功能化重点实验室,西安 710021
2 陕西科技大学轻工科学与工程学院,西安 710021
3 西安科技大学机械工程学院,西安 710054

Research Progress of Co-free Eutectic High Entropy Alloys

XUE Yunlong^1,*, TIAN Kangkang¹, LIU Hulin¹, WU Yuanting¹, YUAN Liang², GAO Zhongtang³

1 Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi’an 710021, China
2 College of Light Industry Science and Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
3 College of Mechanical Engineering, Xi’an University of Science and Technology, Xi’an 710054, China

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摘要共晶高熵合金因具有良好的综合力学性能及铸造工艺性而受到国际社会的广泛关注,但现有共晶高熵合金通常含有稀贵金属Co,导致合金的成本居高不下,且由于Co为全球战略稀缺资源,不利于国家的战略安全及稳定发展,因此研发无Co共晶高熵合金具有重要的理论意义及应用价值。本文基于无Co共晶高熵合金的研究现状,介绍了该类合金的成分设计方法,重点阐述了FCC+增强相合金体系、BCC+增强相合金体系及其他合金体系,深入分析了不同合金体系的设计思路、显微组织及力学性能,探讨了该类材料的存在问题及发展趋势,以期为无Co共晶高熵合金的发展及应用提供参考。

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	薛云龙
	田康康
	刘虎林
	伍媛婷
	袁亮
	高中堂

关键词: 共晶高熵合金成分设计合金体系显微组织力学性能

Abstract: Eutectic high entropy alloys have received wide attention because of their good comprehensive mechanical properties and casting processability, but the existing eutectic high entropy alloys usually contain the rare precious metal Co, which leads to high cost of the alloys and is not conducive to the strategic security and stable development of the country due to Co being a globally strategically scarce resource. Therefore, it is of great theoretical significance and application value to develop Co-free eutectic high entropy alloys. Based on the current research status of Co-free eutectic high entropy alloys, this paper introduces the composition design method of such alloys, focuses on FCC+enhanced-phase alloy system, BCC+enhanced-phase alloy system and other alloy systems, and analyzes in depth the design ideas, microstructure and mechanical pro-perties of the different alloy systems, and explores the problems and development trend of such materials, and finally proposes references for the development and application of Co-free eutectic high entropy alloys. This paper may provide reference for the development and application of Co-free eutectic high entropy alloys.

Key words: eutectic high entropy alloy composition design alloy system microstructure mechanical property

发布日期: 2025-05-29

ZTFLH:

TG111.4

基金资助: 陕西省教育厅科研计划项目资助(23JC017);西安市科学技术局高校院所人才服务企业项目(23GXFW0007);陕西高校青年创新团队(2022-70)

通讯作者: *薛云龙,工学博士,陕西科技大学副教授、硕士研究生导师。主要研究方向:高温耐磨合金技术与应用;金属结构材料设计及制备;材料力学性能及强韧化机理。xueyunlong@sust.edu.cn

引用本文:

薛云龙, 田康康, 刘虎林, 伍媛婷, 袁亮, 高中堂. 无钴共晶高熵合金研究进展[J]. 材料导报, 2025, 39(11): 24050218-10.
XUE Yunlong, TIAN Kangkang, LIU Hulin, WU Yuanting, YUAN Liang, GAO Zhongtang. Research Progress of Co-free Eutectic High Entropy Alloys. Materials Reports, 2025, 39(11): 24050218-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24050218 或 https://www.mater-rep.com/CN/Y2025/V39/I11/24050218

1 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6(5), 299.
2 Lu Y, Dong Y, Guo S, et al. Scientific Reports, 2014, 4(1), 6200.
3 Xu T T, Lu Y P, Cao Z Q, et al. Journal of Materials Engineering and Performance, 2019, 28(12), 7642.
4 Qiu Y X, Zhang A J, Xin B B, et al. Tribology, 2023, 43(12), 1381 (in Chinese).
邱玉新, 张爱军, 辛本斌, 等. 摩擦学学报, 2023, 43(12), 1381.
5 Zuo G. Natural Resource Economics of China, 2023, 36(9), 4 (in Chinese).
左更. 中国国土资源经济, 2023, 36(9), 4.
6 Li Y W, Chang K K, Wang P S, et al. Materials Science and Engineering of Powder Metallurgy, 2012, 17(1), 1 (in Chinese).
李一为, 常可可, 王培生, 等. 粉末冶金材料科学与工程, 2012, 17(1), 1.
7 Wu M X, Wang S B, Huang H J, et al. Materials Letters, 2020, 262, 127175.
8 Talluri G, Murty B S, Maurya R S. Scripta Materialia, 2024, 249, 116178.
9 Lu Y P, Jiang H, Guo S, et al. Intermetallics, 2017, 91, 124.
10 Ye X C, Xiong J Y, Wu X, et al. Scripta Materialia, 2021, 199, 113886.
11 Ye X C, Lei H F, Liu X W, et al. Materials Letters, 2023, 343, 134395.
12 Jiang H, Han K M, Gao X X, et al. Materials & Design, 2018, 142, 101.
13 Jiao W N, Miao J, Lu Y, et al. Journal of Alloys and Compounds, 2023, 941, 168975.
14 Chanda B, Das J. Journal of Alloys and Compounds, 2019, 798, 167.
15 Huang W, Martin P, Zhuang H L. Acta Materialia, 2019, 169, 225.
16 Xue J T, Huang J T, Liu G T, et al. Vacuum, 2024, 225, 113290.
17 Jin X, Bi J, Zhang L, et al. Journal of Alloys and Compounds, 2019, 770, 655.
18 Liang D S, Wei C X, Ren F Z. Materials Science and Engineering:A, 2021, 806, 140611.
19 Lu Y, Zhang M D, Zhang L J, et al. Materials Science and Engineering:A, 2021, 801, 140421.
20 Lu Y. Study on microstructure and mechanical properties of Co-free CrFeNiNb_x multi-principal alloy. Master’s Thesis, Yanshan University China, 2021 (in Chinese).
卢烨. CrFeNiNb_x无Co多主元合金组织结构与力学性能研究. 硕士学位论文, 燕山大学, 2021.
21 Song J F, Chai Z S, Zheng J, et al. Acta Metallurgica Sinica (English Letters), 2021, 34(8), 1103.
22 Lee W H, Oh Y J, Jo M G, et al. Journal of Alloys and Compounds, 2021, 860, 158502.
23 Ye F Y, Yang J, Sun P J, et al. Chinese Journal of Lasers, 2023, 50(20), 112 (in Chinese).
叶馥宇, 杨键, 孙潘杰, 等. 中国激光, 2023, 50(20), 112.
24 Yu L E, Ye X C, Fang D, et al. Journal of Materials Research and Technology, 2022, 21, 3207.
25 Li Z, Liu C, Wang L, et al. Materials Characterization, 2023, 203, 113120.
26 Liang X Y, Chen J, Yao Y H, et al. Materials Letters, 2023, 337, 133952.
27 Ye X C, Wu X, Wang T, et al. Transactions of Materials and Heat Treatment, 2022, 43(9), 68 (in Chinese).
叶喜葱, 吴鑫, 王童, 等. 材料热处理学报, 2022, 43(9), 68.
28 Jiang Z F, Chen W P, Xia Z B, et al. Intermetallics, 2019, 108, 45.
29 Wang M Z, Wen Z Q, Liu J X, et al. Journal of Alloys and Compounds, 2022, 918, 165441.
30 Jiao W N, Li T X, Chang X X, et al. Journal of Alloys and Compounds, 2022, 902, 163814.
31 Yao C L. Composition design and microstructure research of NiAl based eutectic high-entropy alloys. Master’s Thesis, Xi’an University of Technology, China, 2021 (in Chinese).
姚成利. NiAl基共晶高熵合金的成分设计与微观组织研究. 硕士学位论文, 西安理工大学, 2021.
32 Wang L, Su Y N, Yao C L, et al. Intermetallics, 2022, 143, 107476.
33 Xue Y L, Wang Y X, Sun H H, et al. Metals and Materials International, 2023, 29(2), 564.
34 Wei Q Q, Xu X D, Shen Q, et al. Science, 2022, 8(27), 2068.
35 Wu M X, Wang S B, Xiao F, et al. Materials Science and Engineering:A, 2022, 842, 143112.
36 Wang M L, Lu Y P, Lan J G, et al. Acta Materialia, 2023, 248, 118806.
37 Hu M C, Du Y, Pei X H, et al. Tribology, 2024, 44 (5), 609 (in Chinese).
胡明川, 杜银, 裴旭辉, 等. 摩擦学学报, 2024, 44 (5), 609.
38 Chen B, Li X, Chen W, et al. Intermetallics, 2023, 155, 107829.
39 Xue Y L, Wang Y X, Sun H H, et al. The Chinese Journal of Nonferrous Metals, 2022, 32(10), 2999 (in Chinese).
薛云龙, 王玉轩, 孙浩华, 等. 中国有色金属学报, 2022, 32(10), 2999.
40 Yuan J P, Yang Y J, Duan S G, et al. Materials, 2023, 16(1), 56.
41 Li S Y. Microstructure evolution and properties of Al-Cr-Fe-Ni-M eutectic high-entropy alloys. Master’s Thesis, Shandong University of Technology, China, 2022 (in Chinese).
李肖逸. Al-Cr-Fe-Ni-M系共晶高熵合金组织演化及性能研究. 硕士学位论文, 山东理工大学, 2022.
42 Guo Y X, Shang X J, Liu Q B. Chinese Journal of Rare Metals, 2018, 42(8), 807 (in Chinese).
郭亚雄, 尚晓娟, 刘其斌. 稀有金属, 2018, 42(8), 807.
43 Yang B T, Ma L L, Zhao P P. Materials Science and Engineering:A, 2023, 863, 144524.
44 Jiao W N. Composition design and mechanical properties of CrFeNiMo(V) eutectic high entropy alloy. Master’s Thesis, Dalian University of Technology, China, 2019 (in Chinese).
焦文娜. CrFeNiMo(V)系共晶高熵合金的成分设计与力学性能研究. 硕士学位论文, 大连理工大学, 2019.
45 Liang W Z, Wu W D, Chen Y S, et al. Journal of Heilongjiang University of Science and Technology, 2021, 31(3), 373(in Chinese).
梁维中, 吴万东, 陈永生, 等. 黑龙江科技大学学报, 2021, 31(3), 373.
46 Ye X C, Cheng Z H, Liu C, et al. Materials Science and Engineering:A, 2022, 841, 143026.
47 Fang D, Wu X, Xu W Q, et al. Materials Science and Engineering:A, 2023, 870, 144919.
48 Wu W D. Study on microstructure and mechanical properties of CrFenNiMoNb-Y/Er eutectic high entropy alloys. Master’s Thesis, Heilongjiang University of Science and Technology, China, 2022 (in Chinese).
吴万东. CrFeNiMoNb-Y/Er共晶高熵合金微观组织与力学性能研究. 硕士学位论文, 黑龙江科技大学, 2022.
49 Luo S C. Composition design and fundamental research on selective laser melting of AlCrCuFeNi_x high entropy alloys. Ph. D. Thesis, Huazhong University of Science and Technology, China, 2021 (in Chinese).
骆顺存. AlCrCuFeNi_x高熵合金的成分设计及激光选区熔化成形基础研究. 博士学位论文, 华中科技大学, 2021.
50 Tri D V, Tieu A K, Wexler D, et al. Journal of Alloys and Compounds, 2022, 928, 167087.
51 Wang Y B, Li S Y, Chen F D, et al. Journal of Alloys and Compounds, 2023, 958, 170373.
52 Miao J W, Wang M L, Zhang A J, et al. Acta Metallurgica Sinica, 2023, 59(2), 267 (in Chinese).
苗军伟, 王明亮, 张爱军, 等. 金属学报, 2023, 59(2), 267.
53 Cheng X. Study on microstructures and properties of Al_xCrFeNi quaternary component alloys. Master’s Thesis, China University of Mining and Technology, China, 2017 (in Chinese).
陈霄. Al_xCrFeNi四组元合金的微观组织与性能研究. 硕士学位论文, 中国矿业大学, 2017.
54 Xiao Y K, Chang X D, Peng X H. Journal of Materials Research and Technology, 2022, 21, 4908.
55 Zhang X B. Study on BCC/B2 phase coherent precipitation of Al_xCrFe_y Ni high entropy alloy. Master’s Thesis, North University of China, China, 2023 (in Chinese).
张小波. Al_xCrFe_yNi系高熵合金BCC/B2相共格析出研究. 硕士学位论文, 中北大学, 2023.
56 Fang D, Zhang A, Luo A J, et al. Special Casting & Nonferrous Alloys, 2024, 44(1), 30 (in Chinese).
方东, 张安, 罗爱娇, 等. 特种铸造及有色合金, 2024, 44(1), 30.
57 Xu Z, Li Q Y, Li W, et al. Wear, 2023, 522, 204701.
58 Wang H M, Du Y, Pei X H, et al. Acta Metallurgica Sinica, 2024, 60 (7), 937 (in Chinese).
王瀚铭, 杜银, 裴旭辉, 等. 金属学报, 2024, 60 (7), 937.
59 Zhu M, Yao L J, Liu Y Q, et al. Materials Letters, 2020, 272, 127869.
60 Xu Q, Wang Q, Li J, et al. Special Casting & Nonferrous Alloys, 2022, 42(3), 292 (in Chinese).
徐琴, 王琪, 李娟, 等. 特种铸造及有色合金, 2022, 42(3), 292.
61 Li H. Microstructure and mechanical properties of directionally solidified Ti₃₀Ni₃₀Fe₁₀Hf₁₀Nb_x high-entropy alloy. Master’s Thesis, University of Science and Technology of China, China, 2021 (in Chinese).
李欢. 定向凝固Ti₃₀Ni₃₀Fe₁₀Hf₁₀Nb_x高熵合金的微观结构及力学性能研究. 硕士学位论文, 2022.
62 Bai K W, Wu Z K, Lin M, et al. Acta Materialia, 2023, 243, 118512.
63 Ou W, Yuan X, Li Z, et al. Surfaces and Interfaces, 2023, 40, 103068.
64 Xu Q, Chen D Z, Wang C R, et al. Transactions of Nonferrous Metals Society of China, 2021, 31(2), 512.
65 Xu Z M. Study on the microstructure and properties of WVTaCr_xTi_y refractory high entropy alloy coating prepared laser cladding. Master’s Thesis, Qilu University of Technology, China, 2023 (in Chinese).
许兆敏. 激光熔覆WVTaCr_xTi_y难熔高熵合金涂层组织与性能研究. 硕士学位论文, 齐鲁工业大学, 2023.
66 Kuang S H. Laser cladding of BCC-based eutectic high-entropy alloy coa-tings. Master’s Thesis, Guizhou University, China, 2021 (in Chinese).
匡世华. 激光熔覆BCC基共晶高熵合金涂层研究. 硕士学位论文, 贵州大学, 2021.
67 Lee C P, Chang C C, Chen Y Y, et al. Corrosion Science, 2008, 50(7), 2053.
68 Zhu J M, Fu H M, Zhang H F, et al. Materials Science & Engineering:A, 2010, 527, 7210.

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