A Critical Review of Biochar Electrode Performance Enhancement Strategies for High-performance Supercapacitors
ZHANG Jincai1,*, LI Meiping2, Subramanian Sunderrajan3,4, Vishnu Vijay Kumar5
1 Institute of Resources and Environmental Engineering, State Environmental Protection Key Laboratory of Efficient Utilization of Waste Resources, Shanxi University, Taiyuan 030006, China 2 School of Life Science, Shanxi University, Taiyuan 030006, China 3 Center for Nanotechnology & Sustainability, Department of Mechanical Engineering, National University of Singapore, Singapore 4 Department of Prosthodontics, Saveetha Dental College and Hospitals, Saveetha Institute of Medical & Technical Science, Saveetha University, Chennai 600077, India 5 Division of Engineering, New York University Abu Dhabi (NYUAD), Abu Dhabi, United Arab Emirates
Abstract: The global demand for sustainable energy solutions has intensified due to resource limitations and environmental challenges. Biochar presents a promising electrode material for energy storage devices, offering a potential cost-effective and environmentally friendly alternative. Howe-ver, traditional biochar production through pyrolysis reveals significant performance constraints. This has prompted researchers to explore innovative approaches for improving biochar’s electrical and chemical properties. This comprehensive review examines biochar’s application in energy storage systems, with particular emphasis on supercapacitor technologies. The study critically analyzes three key methods for enhancing biochar’s performance, providing a detailed investigation of current research strategies. By synthesizing existing literature,this review offers a nuanced overview of biochar’s potential in renewable energy technologies. This review systematically evaluates recent scientific approaches to developing more effective biochar materials, highlighting the critical intersection between sustainable materials and energy storage solutions. Additionally, this work presents targeted recommendations for future scientific investigations, aiming to advance the development of high-performance biochar technologies. Through a critical assessment of current research, this review contributes to our understanding of sustainable energy storage approaches and identifies promising pathways for future technological innovation.
1 Ismail I S, Othma M F H, Rashidi N A, et al. Biomass Conversion Biorefinery, 2023, 1. 2 Liu W J, Jiang H, Yu H Q. Energy & Environmental Science, 2019, 12, 1751. 3 Ehsani A, Parsimehr H. Advances in Colloid and Interface Science, 2020, 284, 102263. 4 Zhang W L, Zhang F, Ming F W, et al. EnergyChem, 2019, 1, 100012. 5 Hao A J, Song C X, Guo A Z, EnergyChem, 2019, 1, 100004. 6 Li J, Song X, Zhang W, et al. Chemistry—a European Journal, 2020, 26, 3326. 7 Zheng S, Li Q, Xue H, et al. National Science Review, 2020, 7, 305. 8 Ramasubramanian B, Sundarrajan S, Rao R P, et al. Energy & Environmental Science, 2022, 15, 4928. 9 Ramasubramanian B, Sundarrajan S, Chellappan V, et al. Batteries, 2022, 8, 133. 10 Kumar P S, Sundaramurthy J, Sundarrajan S, et al. Energy & Environmental Science, 2014, 7, 3192. 11 Darbar D, Reddy M V, Sundarrajan S, et al. Materials Research Bulletin, 2016, 73, 369. 12 Siwal S S, Zhang Q, Devi N, et al. Polymers, 2020, 12, 5. 13 Rolison D R, Long J W, Lytle J C, et al. Chemical Society Reviews, 2009, 38, 226. 14 Cheng B H, Zeng R J, Jiang H. Bioresource Technology, 2017, 246, 224. 15 Many D J J, Gascó G. Biochar as a renewable-based material: with applications in agriculture, the environment and energy, World Scientific Publishing Company, 2020. 16 Magnacca G, Guerretta F, Vizintin A, et al. Applied Surface Science, 2018, 427, 883. 17 Definition P, Guidelines S. Standardized product definition and product testing guidelines for biochar that is used in soil, International Biochar Initiative, 2012. 18 Zhang Z, Zhu Z, Shen B, et al. Energy, 2019, 171, 581. 19 Hyland C, Sarmah A K. Advances and Applications, 2014, 25, 435. 20 Meyer S, Glaser B, Quicker P. Environmental Science Technology, 2011, 45, 9473. 21 Amalina F, Razak A S A, Krishnan S, et al. Journal of Hazardoous Materials Advances, 2022, 7, 100134. 22 Yaman H A. Journal of Thermal Science and Engineering Applications, 2019, 11, 011006. 23 Zhang J J, Zhang X L. Biomass, biopolymer-based materials, and bioe-nergy, Woodhead Publishing, 2019, pp.327. 24 Tripathi M, Sahu J N, Ganesan P. Renewable & Sustaiable Energy Reviews, 2016, 55, 467. 25 Ayhan, Demirbas. Journal of Analytical and Applied Pyrolysis, 2004, 72, 243. 26 Liu W J, Jiang H, Yu H Q. Chemical Reviews, 2015, 115, 12251. 27 Arni S A. Renewable Energy, 2017, 124, 197. 28 Zhang Q, Li Q F, Zhang L X, et al. Energy, 2017, 134, 301. 29 Wang G, Zhang J, Shao J, et al. Energy, 2016, 114, 143. 30 Qian K, Kumar A, Zhang H, et al. Renewable Suatainable Energy Review, 2015, 42, 1055. 31 Mauro G, Mattia B, Carlo R, et al. In:Conference on Bio-char. Cetraro, Italy, 2019. 32 Lee J, Lee K, Sohn D, et al. Energy, 2018, 153, 913. 33 Libra J A, Ro K S, Claudia K, et al. Biofuels, 2011, 2, 71. 34 Jerry A M, Kazuhiro M, Paredes L S. Industrial & Engineering Chemistry Research, 2003, 42, 3690. 35 Bridgwater A V. International Journal of Global Energy Issues, 2010, 27, 160. 36 Yan W, Acharjee T C, Coronella C J, et al. Environmental Progress & Sustainable Energy, 2009, 28, 435. 37 Woolf D, Amonette J E, Street-Perrott F A, et al. Nature Communication, 2010, 1, 1. 38 Antal M J, Gronli M G. Industrial & Engineering Chemistry Research, 2004, 45, 1619. 39 Bard, Edouard. Science, 2001, 292, 2443. 40 Caguiat J N, Arpino G, Krigstin S G, et al. Biomass Bioenergy, 2018, 118, 126. 41 Ma Y, Yao D, Liang H, et al. Electrchimica Acta, 2020, 352, 136452. 42 Tripathi M, Bhatnagar A, Pandey K K, et al. Journal of the Electroche-mical Society, 2021, 168, 050530. 43 Bouchelta C, Medjram M S, Bertrand O, et al. Journal of Analytical and Applied Pyrolysis, 2008, 82, 70. 44 Nabais J M V, Nune S P, Carrott P J M, et al. Fuel Processing Technology, 2008, 89, 262. 45 Chen W, Zhang H, Huang Y, et al. Journal of Materials Chemistry, 2010, 20, 4773. 46 Yu L, Bran N, Sakaushi K. Carbon, 2013, 61, 245. 47 Kubo S, White R J, Tauer K, et al. Chemistry of Materials, 2013, 25, 4781. 48 Aworn A, Thiravetyan P, Nakbanpote W. Journal of Analytical and Applied Pyrolysis, 2008, 82, 279. 49 Dong Z, Chen C, Wen K, et al. Polymers (Basel), 2022, 14(195), 1. 50 Thengane S K, Bandyopadhyay S. Clean Technologies Environmental Po-licy, 2020, 22, 5. 51 Yuan X Z, Dissanayake P D, Gao B, et al. Journal of Environmental Management, 2021, 296, 113128. 52 Cuong D V, Matsagar B M, Lee M, et al. Renewable & Sustainabale Energy Reviews, 2021, 145, 111029. 53 Abioye A M, Ani F N. Renewable & Sustainable Energy Reviews, 2015, 52, 1282. 54 Reza M T, Lynam J G, Vasquez V R, et al. Environmental Progress & Sustainable Energy, 2012, 31, 225. 55 Norouzi O, Maria F D, Dutta A, et al. Journal of Energy Storage, 2020, 29, 101291. 56 Osman A I, Fawzy S, Farghali M, et al. Environmental Chemistry Letters, 2022, 20, 2385. 57 Fu M, Chen W, Ding J X, et al. Journal of Alloys and Compounds, 2018, 782, 352. 58 Gao H Q. Chemical Engineering Journal, 2020, 402, 126171. 59 Peng L, Liang Y, Huang J, et al. ACS Sustainable Chemistry & Engineering, 2019, 7, 10393. 60 Gao Y, Zhang W, Yue Q, et al. Journal of Power Sources, 2014, 270, 403. 61 Qiu Z P, Wang Y S, Xu B, et al. Journal of Power Sources, 2018, 376, 82. 62 Huang W, Zhang H, Huang Y, et al. Carbon, 2011, 49, 838. 63 Genovese M, Lian K. Journal of Materials Chemistry A, 2017, 5, 3939. 64 Tan H, Wang X N, Jia D D, et al. Journal of Materials Chemistry A, 2017, 5, 2580. 65 Giannakopoulos S, Vakros J, Manariotis I D, et al. Materials (Basel), 2022, 16(43), 1. 66 Zhao G, Chen C, Yu D, et al. Nano Energy, 2018, 47, 547. 67 Lima R, Reis G S D, Thyrel M, et al. Nanomaterials (Basel), 2022, 12(866), 1. 68 Rufford T E, Hulicova-Jurcakova D, Zhu Z, et al. Electrochemistry Communications, 2008, 10, 1594. 69 Rufford T E, Hulicova-Jurcakova D, Khosla K, et al. Journal of Power Sources, 2010, 195, 912. 70 Shrestha L K, Shrestha R G, Maji S, et al. Nanomaterials-Basel, 2020, 10(728), 1. 71 Taer E, Susanti A, Taslim R, et al. Journal of Physics Conference Series, 2021, 1811, 012135. 72 Wan L, Hu J, Liu J, et al. Journal of Alloys and Compounds, 2021, 859, 158390. 73 Saliu O D, Adeniyi A, Mamo M, et al. Electrochemical Communications, 2022, 139, 107308. 74 Lei W, Yang B, Sun Y, et al. Journal of Power Sources, 2021, 488, 229455. 75 Li X, Xing W, Zhuo S, et al. Bioresources Technology, 2011, 102, 1118. 76 Lin Y, Li F, Zhang Q, et al. Ionics, 2022, 28, 2525. 77 Ranola S, Mohan D, Masek O, et al. Engineered biochar, fundamentals, preparation, characterization and applications, Sprink, 2022. 78 Benis K Z, Damuchali A M, Soltan J, et al. Science of the Total Environment, 2020, 739, 139750. 79 Chang C, Li M, Wang H, et al. Journal of Materials Chemistry A, 2019, 7, 19939. 80 Huang J, Chen L, Dong H, et al. Electrochimic Acta, 2017, 258, 504. 81 Lin Y, Chen Z, Yu C, et al. ACS Sustainable Chemistry & Engineering, 2019, 7, 3389. 82 Zhang S, Li Y, Du Y, et al. Diamond and Related Materials, 2022, 130, 109507. 83 Zhao N, Deng L, Luo D W, et al. Applied Surface Science, 2020, 526, 1446696. 84 Jiang B, Cao L, Yuan Q, et al. Materials (Basel, Switzerland), 2022, 15(924), 1. 85 Yang S, Wang S L, Liu X, et al. Carbon, 2019. 147, 540. 86 Mehdi R, Naqvi S R, Khoja A H, et al. Fuel, 2023, 348, 128529. 87 Omar N, Abdullah E C, Petrus A A, et al. Biomass Conversion and Biorefinery, 2021, 13, 2279. 88 Yuan X, Zhang Y, Yan Y, et al. Chemical Engineering Journal, 2019, 393, 12124. 89 Yuan C, Lin H, Lu H, et al. Applied Energy, 2016, 178, 260. 90 Zhou B T, Sui Y W, Qi J Q, et al. Journal of Electronic Materials, 2019, 48, 3026. 91 Norouzi O, Pourhosseini S E M, Naderi H R, et al. Science Reports, 2021, 11, 5387. 92 Wesley R J, Durairaj A, Ramanathan S, et al. Diamond and Related Materials, 2021, 115, 108360. 93 Zhang Y, Yang S, Wang S, et al. Energy Storage Materials, 2019, 18, 447. 94 Adhamash E, Pathak R, Qiao Q, et al. RSC Advances, 2020, 10, 29910. 95 Teng Z, Han K, Li J, et al. Ultrasonics Sonochemistry, 2020, 60, 104756. 96 Zhi M J, Xiang C C, Li J T, et al. Nanoscale, 2013, 5, 72. 97 Chen K, Liu J, Bian H, et al. Nanotechnology, 2020, 31, 335713. 98 Li X, Wei B. Nano Energy, 2012, 2, 159. 99 Dai Y F, He S S, Yu L B, et al. Journal of Physics and Chemistry of So-lids, 2019, 129, 122. 100 Pan Z, Zhi H, Qiu Y, et al. Nano Energy, 2018, 46, 266. 101 Xiong C L, Zhong W B, Zou Y B, et al. Electrochim Acta, 2016, 211, 941. 102 Hou J H, Cao C B, Idrees F, et al. ACS Nano, 2015, 9, 2556. 103 Zhang Y L, Sun C, Tang Z S. Diamond and Related Materials, 2019, 97, 107455. 104 Wang S, Dong L, Li Z, et al. International Journal of Biological Macromolecules, 2020, 164, 4095. 105 Shu Y, Maruyama J, Iwasaki S, et al. Journal of Power Sources, 2017, 364, 374. 106 Yuan X, Xiao J, Yilmaz M, et al. Separation and Purification Technology, 2022, 299, 121719. 107 Gandla D, Wu X, Zhang F, et al. ACS Omega, 2021, 6, 7615. 108 Shang Z, An X Y, Zhang H, et al. Carbon, 2020, 161, 62. 109 Meng X, Jia S, Mo L, et al. Journal of Materials Science, 2020, 55, 7417. 110 Song J, Shen W Z, Wang J G, et al. ChemElectroChem, 2018, 5, 1451. 111 Zhang W, Zou Y, Yu C, et al. Journal of Power Sources, 2019, 439, 227067. 112 Sun J, Niu J, Liu M, et al. Applied Surface Science, 2017, 427, 807. 113 Wei T, Zhang Q, Wei X, et al. Science Reports, 2016, 6, 22646. 114 Wan L, Xiao R, Liu J X, et al. Applied Surface Science, 2020, 518, 146265. 115 Li Y, Zheng K, Shah S A A, et al. RSC Advances, 2017, 7, 43356. 116 Hu X R, Li J F, Zhang Y, et al. Chemical Physics, 2019, 525, 110383. 117 Zhao Y Y, Dong C X, Sheng L Z, et al. ACS Sustainable Chemistry and Engineering, 2020, 8, 8664. 118 Song T T, Zhao Y H, Chen C X, et al. Journal of Energy Storage, 2024, 98, 113148. 119 Chen W J, Liu Y F, Zhang X Y, et al. Journal of Power Sources, 2025, 654, 237814.