Please wait a minute...
材料导报  2026, Vol. 40 Issue (8): 25040081-10    https://doi.org/10.11896/cldb.25040081
  无机非金属及其复合材料 |
具有异质结构的多元过渡金属氧化物在超级电容器中的储能应用
陈悦, 徐芬*, 孙立贤*, 余楚钰, 冯俞霖, 李蓉江, 徐如丹, 杜毛湛, 胡星雨
桂林电子科技大学材料科学与工程学院,广西 桂林 541004
Multicomponent Transition Metal Oxides with Heterogeneous Structures in Energy Storage of Supercapacitors
CHEN Yue, XU Fen*, SUN Lixian*, YU Chuyu, FENG Yulin, LI Rongjiang, XU Rudan, DU Maozhan, HU Xingyu
School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China
下载:  全 文 ( PDF ) ( 45260KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 为提高金属氧化物NiMoO4/CoMoO4的能量密度,本工作采用非离子型表面活性剂聚乙烯吡咯烷酮 (PVP) 对其形貌进行修饰,得到由薄且弯曲的纳米片交错形成的纳米花状NiMoO4/CoMoO4-PVP。然后,以NiMoO4/CoMoO4-PVP作为载体,铁氰化钾作为原料,通过溶剂共沉淀方法在NiMoO4/CoMoO4-PVP的表面沉积普鲁士蓝类似物 (PBAs),成功制备具有异质结构的NiMoO4/CoMoO4-PVP@PBAs复合材料。研究结果表明,PBAs既可以提供赝电容及稳定的框架结构,又能与NiMoO4/CoMoO4-PVP形成的异质结构加快电解质离子扩散速率和诱导暴露更多的活性位点用于电化学储能。微观形貌和结构的表征以及电化学研究结果表明,沉积反应的陈化最佳时间为24 h,NiMoO4/CoMoO4-PVP@PBAs-24电极表现出良好的电容性能 (在1 A·g-1下比电容为1 313 F·g-1)。另外,与生物多孔碳CGL组装的NiMoO4/CoMoO4-PVP@PBAs-24//CGL非对称电容器经过10 000次循环后实现了79.8%的电容保持率和100%的高库仑效率,且在393 W·kg-1的功率密度下表现出的最大能量密度为42.17 Wh·kg-1,说明NiMoO4/CoMoO4-PVP@PBAs-24具有良好的电化学性能。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
陈悦
徐芬
孙立贤
余楚钰
冯俞霖
李蓉江
徐如丹
杜毛湛
胡星雨
关键词:  超级电容器  金属氧化物  异质结构  普鲁士蓝类似物  生物质多孔碳    
Abstract: To increase the energy density of metal oxide NiMoO4/CoMoO4, a non-ionic surfactant polyvinylpyrrolidone (PVP) is used to modify the morphology of NiMoO4/CoMoO4-PVP to obtain nano-flower-like NiMoO4/CoMoO4-PVP formed by interlaced thin and curved nanosheets. Then, the NiMoO4/CoMoO4-PVP is used as the supporting material and potassium ferricyanide as the raw material to deposit Prussian blue analogue (PBAs) on the surface of NiMoO4/CoMoO4-PVP by solvent co-precipitation method. The results demonstrate that PBAs can provide pseudocapacitance and stable framework structure, as well as the heterostructure formed by PBAs and NiMoO4/CoMoO4-PVP can accelerate the diffusion rate of electrolyte ions and induce the exposure of more active sites for electrochemical energy storage. The microstructure characterization and the electrochemical performance reveal that the optimal aging time of the deposition reaction is 24 hours, and the NiMoO4/CoMoO4-PVP@PBAs-24 electrode exhibits good capacitance performance (1 313 F·g-1 at 1 A·g-1). Additionally, the NiMoO4/CoMoO4-PVP@PBAs-24//CGL asymmetric capacitor assembled with biological porous carbon CGL achieves 79.8% capacitance retention and 100% high Coulomb efficiency after 10 000 cycles. At the power density of 393 W·kg-1, the maximum energy density is 42.17 Wh·kg-1, indicating that NiMoO4/CoMoO4-PVP@PBAs-24 has good electrochemical performance.
Key words:  supercapacitor    metal oxide    heterogeneous structure    Prussian blue analogs    biomass porous carbon
出版日期:  2026-04-25      发布日期:  2026-05-06
ZTFLH:  TB33  
基金资助: 国家自然科学基金 (52271205;U20A20237;52371218;52101245);广西科技研发基金 (AA19182014);广西重点研发项目 (2021AB17045);广西电子信息材料构效关系重点实验室基金 (231006-Z)
通讯作者:  * 徐芬,博士,教授,桂林电子科技大学材料科学与工程学院博/硕士研究生导师。目前主要从事制/储氢材料、相变储热材料、超级电容器电极材料、传感材料等方面的研究。xufen@guet.edu.cn
孙立贤,博士,教授,桂林电子科技大学材料科学与工程学院博/硕士研究生导师。目前主要从事制/储氢材料、相变储热材料、超级电容器电极材料、传感材料、机器学习等方面的研究。sunlx@guet.edu.cn   
作者简介:  陈悦,桂林电子科技大学材料科学与工程学院硕士研究生,在徐芬教授、孙立贤教授的指导下进行储能材料的研究。目前主要从事超级电容器电极材料的制备及电化学性能研究。
引用本文:    
陈悦, 徐芬, 孙立贤, 余楚钰, 冯俞霖, 李蓉江, 徐如丹, 杜毛湛, 胡星雨. 具有异质结构的多元过渡金属氧化物在超级电容器中的储能应用[J]. 材料导报, 2026, 40(8): 25040081-10.
CHEN Yue, XU Fen, SUN Lixian, YU Chuyu, FENG Yulin, LI Rongjiang, XU Rudan, DU Maozhan, HU Xingyu. Multicomponent Transition Metal Oxides with Heterogeneous Structures in Energy Storage of Supercapacitors. Materials Reports, 2026, 40(8): 25040081-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040081  或          https://www.mater-rep.com/CN/Y2026/V40/I8/25040081
1 Pang Z H, Qiao Z J, Lei Y W, et al. Materials Reports, 2022, 36(S2), 22090254(in Chinese).
庞志恒, 乔志军, 雷贻文, 等. 材料导报, 2022, 36(S2), 22090254.
2 Shaheen I, Hussain I, Zahra T, et al. Journal of Energy Storage, 2023, 72, 108719.
3 Girirajan M, Bojarajan A K, Pulidindi I N, et al. Coordination Chemistry Reviews, 2024, 518, 216080.
4 Kumar Y A, Roy N, Ramachandran T, et al. Journal of Energy Storage, 2024, 98, 113040.
5 Wu X H, Sun L X, Xu F, et al. Materials Reports, 2025, 39(7), 24030138(in Chinese).
吴学虎, 孙立贤, 徐芬, 等. 材料导报, 2025, 39(7), 24030138.
6 Dong Y B, Liu F. Journal of Materials Science: Materials in Electronics, 2020, 31(16), 13987.
7 Zou H B, Wang C M, Feng Z W, et al. Journal of Porous Materials, 2023, 30(3), 965.
8 Pathak M, Bhatt D, Bhatt R C, et al. The Chemical Record, 2024, 24(1), e202300236.
9 Saini S, Chand P, Joshi A. Journal of Energy Storage, 2023, 71, 108209.
10 Li Y T, Zhu J J, Xie J Y, et al. Journal of Colloid and Interface Science, 2023, 650, 1113.
11 Sun J T, Chang Y T, Zhang J, et al. Chemical Engineering, 2023, 473, 145175.
12 Niu X Q, Kang X Y, Ma Y X, et al. Materials Reports, 2022, 36(14), 21050021(in Chinese).
牛晓勤, 康小雅, 马应霞, 等. 材料导报, 2022, 36(14), 21050021.
13 Jiang T T, Wang X L, Zhou H, et al. Journal of Energy Storage, 2023, 72, 108184.
14 Yan D X, Fan X. Materials Reports, 2023, 37(18), 22030311(in Chinese).
颜冬仙, 樊新. 材料导报, 2023, 37(18), 22030311.
15 Du C Y, Han E S, Gao L, et al. Ionics, 2020, 26(8), 4009.
16 Kausar S, Yousaf M, Mir S, et al. Electrochemistry Communications, 2024, 169, 107836.
17 Wang J, Zhang L P, Liu X S, et al. Scientific Reports, 2017, 7(1), 41088.
18 Zhang Z Q, Zhang H D, Zhang X Y, et al. Journal of Materials Chemistry A, 2016, 4(47), 18578.
19 Naresh N, Jayasubramaniyan S, Jena P, et al. Inorganic Chemistry Communications, 2021, 133, 108916.
20 Nguyen V T, Sari F N I, Saputro B W, et al. Journal of Materials Che-mistry A, 2023, 11(36), 19483.
21 Nti F, Anang D A, Han J I. Journal of Alloys and Compounds, 2018, 742, 342.
22 Narale D K, Kumbhar P D, Bhosale R R, et al. Journal of Power Sources, 2024, 601, 234291.
23 Chang L, Chen S Q, Fei Y H, et al. Proceedings of the National Academy of Sciences, 2023, 120(12), e2219950120.
24 Iyer M S, Rajangam I. Journal of Energy Storage, 2023, 67, 107530.
25 Zhang Y Y, Jin F, Liu H, et al. Fuel, 2024, 361, 130655.
26 Morais A, Alves J P C, Lima F A S, et al. Journal of Photonics for Energy, 2015, 5, 057408.
27 Butenko D S, Zhang X, Zatovsky I V, et al. Dalton Transactions, 2020, 49(35), 12197.
28 Zhou P C, Xiao F, Weng R X, et al. Journal of Materials Chemistry A, 2022, 10(19), 10514.
29 Wang J W, Li M Z, Zhai Y, et al. Applied Surface Science, 2021, 556, 149789.
30 Gopi C V V M, Sambasivam S, Raghavendra K V G, et al. Journal of Energy Storage, 2020, 30, 101550.
31 Raza S, Baig F, Fahad H M, et al. Journal of Sol-Gel Science and Technology, 2024, 109(2), 407.
32 Zardkhoshoui A M, Ameri B, Davarani S S H. Chemical Engineering Journal, 2021, 422, 129953.
33 Cai D P, Wang D D, Liu B, et al. ACS Applied Materials & Interfaces, 2014, 6(7), 5050.
34 Huang C X, Li X H, Jiang Z, et al. Acta Materialia, 2024, 281, 120419.
35 Zardkhoshoui A M, Davarani S S H. Chemical Engineering Journal, 2020, 402, 126241.
36 Yaseen S, Wattoo A G, Abbas S M, et al. Chemical Engineering Journal, 2025, 507, 160337.
37 Shi C J, Du Y H, Guo L, et al. Journal of Energy Storage, 2022, 48, 103961.
38 Thakur Y S, Acharya A D, Sharma S, et al. Results in Chemistry, 2024, 7, 101259.
39 Wu B, Qin L R, Zhao J W, et al. Acta Materiae Compositae Sinica, 2022, 39(12), 5727.
40 Liang R B, Du Y Q, Wu J X, et al. Journal of Solid State Chemistry, 2022, 307, 122845.
41 Wang Y, Yu S M, Deng C Y, et al. ACS Applied Materials & Interfaces, 2022, 14(6), 8282.
42 Appiagyei A B, Han J I. Ceramics International, 2020, 46(8), 12422.
43 Zhou E M, Tian L L, Cheng Z F, et al. Nanoscale Research Letters, 2019, 14(1), 221.
44 Song F H, Ma J M, Wang G, et al. Energy, 2025, 326, 136360.
45 Zhang X D, Huang M Y, Wang Y L, et al. Inorganic Chemistry, 2023, 62(45), 18670.
46 Yu B, Jiang G H, Xu W C, et al. Journal of Alloys and Compounds, 2019, 799, 415.
47 Ju H, Tang Q Q, Xu Y, et al. Dalton Transactions, 2023, 52(36), 12948.
[1] 贺格平, 傅泽果, 杨全, 鲍晨皓, 徐锐, 李梦轩, 井格格, 苟文浩. 基于聚乙烯吡咯烷酮表面活性剂的超级电容器电极材料ZnWO4@rGO的制备及性能研究[J]. 材料导报, 2026, 40(6): 25040062-8.
[2] 胡慧, 陈宇, 张亚梅. 生物炭在多功能涂层改性中的研究进展[J]. 材料导报, 2026, 40(5): 25090003-15.
[3] 赵甲正, 张深根, 王健, 李俊, 罗丰华. 金属异质结构材料:分类、强韧化机制与发展趋势[J]. 材料导报, 2026, 40(1): 25020015-16.
[4] 徐桂培, 刘浩, 赖洁文, 卢毅锋, 黄辉, 易宗琳, 邸会芳, 王振兵, 苏方远, 陈成猛. 高电压双电层超级电容器电解质的研究进展[J]. 材料导报, 2025, 39(9): 24030012-8.
[5] 邹振羽, 刘伟, 李朋娟, 李晓丽. 共活化法制备等级多孔炭材料及其储能性能研究[J]. 材料导报, 2025, 39(3): 23080193-7.
[6] 赵甲正, 张深根, 王健, 李俊, 罗丰华. 金属异质结构材料:设计、制备、应用与机遇[J]. 材料导报, 2025, 39(22): 24120123-11.
[7] 张皓天, 刘丽, 刘峻彤, 李扬动. 基于常见金属及金属氧化物纳米材料在手印显现中的应用进展[J]. 材料导报, 2025, 39(22): 24110191-13.
[8] 武志红, 许怡凡, 李鹏, 齐珺, 常吉进, 牛丹, 任安文. 生物质衍生多孔碳基吸波材料的研究进展[J]. 材料导报, 2025, 39(20): 24090134-8.
[9] 高兆辉, 唐茂勇, 迟建卫, 章天歌. 碳包覆氮化钒/碳(VN/C)复合纳米材料的制备以及作为超级电容器电极的应用[J]. 材料导报, 2025, 39(19): 24100197-7.
[10] 周柯, 王晓明, 金庆忍, 常彬彬. 一步法构筑石墨化多级孔碳材料及其超级电容储能性能研究[J]. 材料导报, 2025, 39(18): 24080215-7.
[11] 白京陇, 元丽华, 戴怡乐, 赵继威, 贺艳霞, 魏智强. 金属有机框架衍生的碳包覆二硫化钴多面体材料的电化学性能研究[J]. 材料导报, 2025, 39(16): 24090099-8.
[12] 陈美玲, 孙艳芝, 吴玉锋, 袁浩然, 潘军青. 废轮胎裂解炭黑在能源存储及转换中的应用进展[J]. 材料导报, 2024, 38(8): 23100011-11.
[13] 刘亭亭, 田国兴, 赵欣, 余新勇, 毛超, 于雪寒, 陈玲. 三维网络结构镍钴氢氧化物/石墨烯水凝胶复合材料的合成及电化学性能[J]. 材料导报, 2024, 38(5): 22070064-7.
[14] 李文龙, 支云飞, 陈泽文, 陕绍云, 李梦蕊. 纤维素-金属氧化物在传感器中的应用研究进展[J]. 材料导报, 2024, 38(3): 22060031-8.
[15] 师楷雁, 白杰, 孙炜岩. 碳基电极材料的改性方法与应用进展[J]. 材料导报, 2024, 38(22): 23080167-9.
[1] Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2] Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[3] Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[4] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[5] Yingke WU,Jianzhong MA,Yan BAO. Advances in Interfacial Interaction Within Polymer Matrix Nanocomposites[J]. Materials Reports, 2018, 32(3): 434 -442 .
[6] Zhengrong FU,Xiuchang WANG,Qinglin JIN,Jun TAN. A Review of the Preparation Techniques for Porous Amorphous Alloys and Their Composites[J]. Materials Reports, 2018, 32(3): 473 -482 .
[7] Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅡ: Durability and Life Prediction Model[J]. Materials Reports, 2018, 32(3): 496 -502 .
[8] Lixiong GAO,Ruqian DING,Yan YAO,Hui RONG,Hailiang WANG,Lei ZHANG. Microbial-induced Corrosion of Concrete: Mechanism, Influencing Factors,Evaluation Indices, and Proventive Techniques[J]. Materials Reports, 2018, 32(3): 503 -509 .
[9] Ningning HE,Chenxi HOU,Xiaoyan SHU,Dengsheng MA,Xirui LU. Application of SHS Technique for the High-level Radioactive Waste Disposal[J]. Materials Reports, 2018, 32(3): 510 -514 .
[10] Haoran CHEN, Yingdong XIA, Yonghua CHEN, Wei HUANG. Low-dimensional Perovskites: a Novel Candidate Light-harvesting Material for Solar Cells that Combines High Efficiency and Stability[J]. Materials Reports, 2018, 32(1): 1 -11 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed