导电高分子水凝胶及其应变传感性能研究进展

doi:10.11896/cldb.22120184

材料导报

2024, Vol. 38

Issue (11): 22120184-11 https://doi.org/10.11896/cldb.22120184

高分子与聚合物基复合材料

导电高分子水凝胶及其应变传感性能研究进展

王石¹, 陈昱恺¹, 周新甲¹, 呼博渊¹, 王勇², 李瑜^1,*, 井新利^1,*

1 西安交通大学化学学院,西安 710049
2 江苏宝利金材科技有限公司,江苏镇江 212000

Research Progress in Conducting Polymer Hydrogels and Their Strain Sensing Properties

WANG Shi¹, CHEN Yukai¹, ZHOU Xinjia¹, HU Boyuan¹, WANG Yong², LI Yu^1,*, JING Xinli^1,*

1 School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China
2 Jiangsu Polymet Technology Co., Ltd., Zhenjiang 212000, Jiangsu, China

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摘要导电高分子水凝胶特指以本征型导电高分子聚苯胺、聚吡咯或聚噻吩等作为导电组分的一类水凝胶。水凝胶的介质环境有助于导电高分子保持质子酸掺杂状态,导电高分子的有机骨架又易与水凝胶网络结合,因此含有导电高分子的水凝胶具有丰富的可设计性,在应变传感领域表现出可观的应用前景,是一种极具潜力的柔性电子材料。本文结合导电高分子水凝胶最新研究进展,系统归纳了亲水性高分子网络与刚性的导电高分子复合形成三维交联网络的构建策略,指出了提升该类材料力学性能、导电性能和抗冻性能的关键制备方法,并分析了其应变传感性能的影响因素。

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	王石
	陈昱恺
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	呼博渊
	王勇
	李瑜
	井新利

关键词: 导电高分子水凝胶应变传感力学性能

Abstract: Conducting polymer hydrogels (CPH) here refer to hydrogels contain polyaniline, polypyrrole or polythiophene as conducting components in their matrix. The water rich environment of hydrogels is beneficial for maintaining the protonic acid doped state of conducting polymers, whereas the conducting polymers with organic backbone are more appropriate to be incorporated into hydrogel matrix in compassion with other conducting fillers. Conducting polymer hydrogels thus exhibit highly tunable properties especially interesting strain sensing behaviour, and become a highly concerned material for flexible electronics at present. This review focused on the construction strategies to CPH and summarized the methods to combine the hydrophilic polymer networks with rigid conducting polymers. The key issues to improve the mechanical, conducting, and anti-freezing properties of CPH were analyzed, and the strain sensing behavior of recently reported CPH were also evaluated.

Key words: conducting polymers hydrogel strain sensing mechanical property

发布日期: 2024-06-25

ZTFLH:

TB34

基金资助: 国家自然科学基金(51903200);陕西省高等教育学会高等教育科学研究项目(XGH21030);广东省科技计划项目(2019B090905007)

通讯作者: *李瑜,西安交通大学化学学院副教授、博士研究生导师。2012年西安交通大学化学工程与技术专业博士毕业,2014年起在西安交通大学工作至今。目前主要从事导电高分子水凝胶、动态交联可再生高分子和功能涂层等方面的研究工作。发表论文30余篇,包括Macromolecules、Polymer、Journal Materials Chemistry A、Journal Materials Che-mistry C等。yuli2012@mail.xjtu.edu.cn;xljing@mail.xjtu.edu.cn

作者简介: 王石,2021年6月于西南石油大学获得工学学士学位。现为西安交通大学化学学院硕士研究生,在李瑜副教授的指导下进行课题研究,目前主要研究领域为导电聚吡咯水凝胶及其应变传感性能。
井新利,通信作者,西安交通大学化学学院教授、博士研究生导师。1991年起在西安交通大学工作至今,目前主要从事功能高分子、动态交联可再生高分子、耐烧蚀树脂等方面的研究工作。发表论文100余篇,包括Journal of American Chemical Society、Macromolecules、Chemical Engineering Journal、Journal Materials Chemistry A等。

引用本文:

王石, 陈昱恺, 周新甲, 呼博渊, 王勇, 李瑜, 井新利. 导电高分子水凝胶及其应变传感性能研究进展[J]. 材料导报, 2024, 38(11): 22120184-11.
WANG Shi, CHEN Yukai, ZHOU Xinjia, HU Boyuan, WANG Yong, LI Yu, JING Xinli. Research Progress in Conducting Polymer Hydrogels and Their Strain Sensing Properties. Materials Reports, 2024, 38(11): 22120184-11.

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http://www.mater-rep.com/CN/10.11896/cldb.22120184 或 http://www.mater-rep.com/CN/Y2024/V38/I11/22120184

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