基于静电和金属络合协同作用的MIL-101(Cr)-NH2高效吸附水中单宁酸

doi:10.11896/cldb.22100069

材料导报

2024, Vol. 38

Issue (14): 22100069-8 https://doi.org/10.11896/cldb.22100069

高分子与聚合物基复合材料

基于静电和金属络合协同作用的MIL-101(Cr)-NH₂高效吸附水中单宁酸

李运龙¹, 刘忆贤¹, 刘苗¹, 韩继龙¹, 周理龙¹, 李正杰^1,*, 甄崇礼^1,2, 刘润静¹

1 河北科技大学化学与制药工程学院,石家庄 050018
2 创启时代(青岛)科技有限公司,山东青岛 266041

Efficiently Remove Tannic Acid from Aqueous Solution by MIL-101(Cr)-NH₂ Based on the Synergistic Effect of Electrostatic and Complexation Interaction

LI Yunlong¹, LIU Yixian¹, LIU Miao¹, HAN Jilong¹, ZHOU Lilong¹, LI Zhengjie^1,*, YUN Jimmy^1,2, LIU Runjing¹

1 School of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
2 Chuangqi Times (Qingdao) Technology Co., Ltd., Qingdao 266041, Shandong, China

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摘要通过水热法制备了一种氨基改性的MIL-101(Cr),采用静态吸附法研究了MIL-101(Cr)-NH₂对废水中单宁酸的吸附性能。采用X射线衍射仪(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)和氮气吸附法表征了材料的结构和形貌,研究了pH值、吸附时间、初始浓度及离子强度对其单宁酸吸附性能的影响,探究了其对单宁酸的吸附机理。随着溶液pH增大,MIL-101(Cr)-NH₂对单宁酸的吸附量逐渐升高,最佳pH为7.0。MIL-101(Cr)-NH₂对单宁酸的吸附过程符合拟二级动力学模型、Freundlich模型和Temkin模型,说明吸附过程为多层化学吸附。扩散模型拟合结果表明,膜扩散和粒子内扩散同时控制吸附过程。在T=303 K、pH=7时,MIL-101(Cr)-NH₂饱和吸附量高达2 031 mg/g。通过Zeta电位和FTIR等表征分析发现,单宁酸主要靠静电作用和金属络合作用被吸附在MIL-101(Cr)-NH₂上。

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	李运龙
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	韩继龙
	周理龙
	李正杰
	甄崇礼
	刘润静

关键词: MIL-101(Cr)-NH₂ 吸附单宁酸静电作用络合作用

Abstract: An amino-functionalized MIL-101(Cr) (namely MIL-101(Cr)-NH₂) was prepared by hydrothermal method and its adsorption performance of tannic acid in aqueous solution was investigated by batch experiments. The structure and morphology of MIL-101(Cr)-NH₂ were characterized through powder X-ray diffraction instrument (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption-desorption isotherms. The effects of initial pH, adsorption time, initial concentration and ion strength on the adsorption performance of tannic acid were explored and the adsorption mechanism was studied. The adsorption capacity of tannic acid onto MIL-101(Cr)-NH₂ gradually increased with the increasing pH value and the optimal pH value was 7.0. The pseudo-second-order kinetic model, Freundlich model, and Temkin model fitted the adsorption data well, which indicated that tannic acid was adsorbed onto MIL-101(Cr)-NH₂ by multilayer adsorption and the adsorption process was dominated by chemisorption. The fitting results of diffusion models suggested that film diffusion and intra-particle diffusion affected the adsorption process together. At T=303 K and pH=7, the equilibrium adsorption capacity of MIL-101(Cr)-NH₂ was up to 2 031 mg/g. The main mechanism controlling the adsorption of tannic acid onto MIL-101(Cr)-NH₂ are the electrostatic interaction and Cr-O complexation interaction.

Key words: MIL-101(Cr)-NH₂ adsorption tannic acid electrostatic interaction complexation interaction

出版日期: 2024-07-25 发布日期: 2024-08-12

ZTFLH:	X52
	TQ46

基金资助: 河北省自然科学基金(B2020208095);河北省高等学校科学技术研究项目(QN2022142);青海省海西州科技局企业创新项目(2019-104)

通讯作者: * 李正杰,河北科技大学化学与制药工程学院讲师、硕士研究生导师。2011年北京化工大学化学工程与工艺专业本科毕业,2016年北京化工大学化学工程与技术专业博士毕业。目前主要从事多孔材料的设计、制备及在气液相中吸附分离性能研究。lizj@hebust.edu.cn

作者简介: 李运龙,2020年6月毕业于平顶山学院化学与环境工程学院,获得工学学士学位。目前为河北科技大学化学与制药工程学院硕士研究生,在李正杰老师的指导下进行研究。目前主要研究领域为双金属-有机骨架材料的制备及性能。

引用本文:

李运龙, 刘忆贤, 刘苗, 韩继龙, 周理龙, 李正杰, 甄崇礼, 刘润静. 基于静电和金属络合协同作用的MIL-101(Cr)-NH₂高效吸附水中单宁酸[J]. 材料导报, 2024, 38(14): 22100069-8.
LI Yunlong, LIU Yixian, LIU Miao, HAN Jilong, ZHOU Lilong, LI Zhengjie, YUN Jimmy, LIU Runjing. Efficiently Remove Tannic Acid from Aqueous Solution by MIL-101(Cr)-NH₂ Based on the Synergistic Effect of Electrostatic and Complexation Interaction. Materials Reports, 2024, 38(14): 22100069-8.

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http://www.mater-rep.com/CN/10.11896/cldb.22100069 或 http://www.mater-rep.com/CN/Y2024/V38/I14/22100069

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