磁性Ce-La-MOFs@Fe3O4的除氟性能

doi:10.11896/cldb.22080185

材料导报

2024, Vol. 38

Issue (4): 22080185-7 https://doi.org/10.11896/cldb.22080185

无机非金属及其复合材料

磁性Ce-La-MOFs@Fe₃O₄的除氟性能

宋江燕^1,2, 翟涛², 温倩³, 周融融², 杨为森², 简绍菊², 潘文斌¹, 胡家朋^2,*

1 福州大学环境与安全工程学院,福州 350001
2 武夷学院生态与资源工程学院,福建省生态产业绿色技术重点实验室,福建武夷山 354300
3 武夷学院数学与计算机学院,福建武夷山 354300

Defluoridation Performance of Magnetic Ce-La-MOFs@Fe₃O₄

SONG Jiangyan^1,2, ZHAI Tao², WEN Qian³, ZHOU Rongrong², YANG Weisen², JIAN Shaoju², PAN Wenbin¹, HU Jiapeng^2,*

1 College of Environment and Safety Engineering, Fuzhou University, Fuzhou 350001, China
2 Fujian Provincial Key Laboratory of Eco-Industrial Green Technology, College of Ecological and Resources Engineering, Wuyi University, Wuyishan 354300, Fujian, China
3 College of Mathematics and Computer Science, Wuyi University, Wuyishan 354300, Fujian, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 10453KB )
输出: BibTeX | EndNote (RIS)

摘要通过水热法制备了Ce-La-MOFs@Fe₃O₄复合材料,研究了Ce-La-MOFs@Fe₃O₄对水溶液中F^-的吸附性能,并通过响应曲面法优化了吸附条件。实验结果表明:在pH=3.6、实验温度为40 ℃、初始氟离子浓度为17.4 mg/L的条件下,Ce-La-MOFs@Fe₃O₄的吸附效果最佳,F^-去除率可达94.5%。除氟特性实验数据更适合用Langmuir模型进行描述,拟合得到最大吸附容量(q_max)为147.23 mg/g,热力学参数ΔG^o、ΔH^o和ΔS^o表明该吸附反应是一个自发吸热的熵增过程。动力学研究表明Ce-La-MOFs@Fe₃O₄对F^-的吸附符合准二级反应动力学过程。对复合材料的形貌和结构进行了表征分析,并结合吸附热力学和动力学研究探讨了吸附机理,该吸附过程主要是离子交换和静电吸附共同作用。共存离子实验、循环再生实验结果显示,Ce-La-MOFs@Fe₃O₄对F^-具有较好的选择性,该复合材料的再生性能较好,回收率可达96%,两次循环后对F^-的去除率仍达81.74%。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	宋江燕
	翟涛
	温倩
	周融融
	杨为森
	简绍菊
	潘文斌
	胡家朋

关键词: 磁性Ce-La-MOFs@Fe₃O₄ 除氟吸附响应曲面优化

Abstract: In the present work, Ce-La-MOFs@F₃O₄ composites were prepared via hydrothermal method, and the adsorption performance of Ce-La-MOFs@Fe₃O₄ on F^- in aqueous solution was investigated, and the adsorption conditions were optimized by response surface method. The experimental results show that the best adsorption effect of Ce-La-MOFs@Fe₃O₄ is achieved at pH=3.6, experimental temperature of 40 ℃, and initial fluoride ion concentration of 17.4 mg/L, and the F^- removal efficiency could reach 94.5%. The experimental datas of fluoride removal were more suitable to be described by Langmuir isotherm model, and the maximum adsorption capacity (q_max) is 147.23 mg/g. The thermodynamic parameters ΔG^o, ΔH^o and ΔS^o indicated that the adsorption reaction is anentropy-increasing process with spontaneous heat absorption, and kinetic study show that the adsorption of F^- by Ce-La-MOFs@Fe₃O₄is well fitted with the pseudo second order model. The morphology and structure of the composites were characterized and analyzed, and the adsorption mechanisms were explored in conjunction with the adsorption thermodynamic and kinetic studies, which were mainly a combination of ion-exchange action and electrostatic adsorption. The results of co-existing ion experiments and regeneration experiments show that Ce-La-MOFs@Fe₃O₄ has ahigh selectivity for F^-. And the regeneration perfor-mance of Ce-La-MOFs@Fe₃O₄ is so excellent that the recovery rate can reach 96%. After two cycles, the removal efficiency still reached 81.74% of F^-.

Key words: magnetic Ce-La-MOFs@Fe₃O₄ defluoridation adsorption response surface optimization

出版日期: 2024-02-25 发布日期: 2024-03-01

ZTFLH:

X52

基金资助: 国家自然科学基金(61903288);福建省自然科学基金(2019J01829;2019J01830);福建省教育厅项目(FBJG20210043);南平市科技项目(2022-ZXHZ-002;N2020Z015);武夷学院师生共创科研团队项目(2020-SSTD-05)

通讯作者: *胡家朋,博士,武夷学院生态与资源工程学院教授、硕士研究生导师。目前主要从事MOF材料制备及其吸附应用研究,近年来,在环境功能材料设计制备及应用领域发表论文80多篇,授权国家发明专利35项。wyuwqhjp@163.com

作者简介: 宋江燕,2021年毕业于天津城建大学,获得工学学士学位。现为福州大学环境与安全工程学院硕士研究生,在胡家朋教授和潘文斌教授的指导下进行研究。目前主要从事MOF材料的制备及除氟性能的研究。

引用本文:

宋江燕, 翟涛, 温倩, 周融融, 杨为森, 简绍菊, 潘文斌, 胡家朋. 磁性Ce-La-MOFs@Fe₃O₄的除氟性能[J]. 材料导报, 2024, 38(4): 22080185-7.
SONG Jiangyan, ZHAI Tao, WEN Qian, ZHOU Rongrong, YANG Weisen, JIAN Shaoju, PAN Wenbin, HU Jiapeng. Defluoridation Performance of Magnetic Ce-La-MOFs@Fe₃O₄. Materials Reports, 2024, 38(4): 22080185-7.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22080185 或 http://www.mater-rep.com/CN/Y2024/V38/I4/22080185

1 Kim W, Singh R, Smith J A. Scientific Report, 2020, 10(1), 5759.
2 Zhang Y Y, Qian Y, Li W, et al. Science of the Total Environment, 2019, 683, 609.
3 Hu Y S. Guangdong Chemical Industry, 2021, 48(18), 112 (in Chinese).
胡永胜. 广东化工, 2021, 48(18), 112.
4 He J Y, Yang Y, Wu Z J, et al. Journal of Environmental Chemical Engineering, 2020, 8(6), 104516.
5 Zhang Q X, Zhang C, Xu Y, et al. Journal of Green Science and Technology, 2021, 23(12), 46 (in Chinese).
张启贤, 张成, 徐瑶, 等. 绿色科技, 2021, 23(12) 46.
6 Das D, Nandi B K. Journal of Dispersion Science and Technology, 2018, 40(8), 1136.
7 Luo S, Zhu M, Tian B H, et al. Industrial Water Treatment, 2022, 42(12), 1(in Chinese).
罗胜, 朱铭, 田秉晖, 等. 工业水处理, 2022, 42(12), 1.
8 Bejaoui I, Mnif A, Hamrouni B. Separation Science and Technology, 2014, 49(8), 1135.
9 Tang X F, Zhou C Y, Xia W, et al. Chemical Engineering Journal, 2022, 446, 137299.
10 Zhao X D, Liu D H, Huang H L, et al. Microporous and Mesoporous Materials, 2014, 185, 72.
11 Haldar D, Duarah P, Purkait M K. Chemosphere, 2020, 251, 126388.
12 Zhang Q, Zhou Y M, Yao Q Z, et al. Environmental Science and Pollution Research, DOI: 10. 1007/s11356-022-21177-y.
13 Duan P Z, Jia X B, Hou X K, et al. Research of Environmental Science, 2021, 34(5), 1139 (in Chinese).
段平洲, 贾晓波, 后希康, 等. 环境科学研究, 2021, 34(5), 1139.
14 Zhao X L, Wang J M, Wu F C, et al. Journal of Hazardous Materials, 2010, 173(1-3), 102.
15 Zhang Y H, Lin X Y, Zhou Q S, et al. Applied Surface Science, 2016, 389, 34.
16 Yan B W, Ye C W, Gong R, et al. Research of Environmental Science, 2019, 32(4), 709 (in Chinese).
严博文, 叶长文, 龚锐, 等. 环境科学研究, 2019, 32(4), 709.
17 Wang N N, Zhao Q, Xu H, et al. Chemosphere, 2018, 210, 624.
18 Zhao J Y, Hu J P, Liu R L, et al. Chemistry, 2021, 84(1), 75.
19 Kuerbanjiang·Nuermaiti, Renaguli·Abudureheman. Chemical industry times, 2022, 36(2), 22 (in Chinese).
库尔班江·努尔麦提, 热娜古丽·阿不都热合曼. 化工时刊, 2022, 36(2), 22.
20 Du Y, Wang X, Nie G Z, et al. Journal of Colloid and Interface Science, 2020, 580, 234.
21 Wang J G, Chen N, Feng C P, et al. Environmental Science and Pollution Research, 2018, 25(16), 15326.
22 Lim D T, Tuyen T N, Nhiem D N, et al. Journal of Nanomaterials, 2021, 2021, 1.
23 Yin C, Huang Q L, Zhu G P, et al. Journal of Colloid and Interface Science, 2022, 607, 1762.
24 Zhang Q R, Bolisetty S, Cao Y P, et al. Angewandte Chemie-Interantional Edition, 2019, 58(18), 6012.
25 Jian S J, Shi F S, Hu R B, et al. Composites Communications, 2022, 33, 101194.
26 Yang Y Q, Li X Y, Gu Y X, et al. Surfaces and Interfaces, 2022, 28, 101649.
27 Thathsara S K T, Cooray P L A T, Journal of Environmental Management, 2018, 207, 387.
28 He Y X, Zhang L M, An X, et al. Science of the Total Environment, 2019, 688, 184.
29 Rego R M, Sriram G, Ajeya K V, et al. Journal of Hazardous Materials, 2021, 416, 125941.
30 Jeyaseelan A, Viswanathan N. Journal of Chemical and Engineering Data, 2020, 65(11), 5328.
31 Zhao J Y, Su L M, Xu J, et al. Journal of Synthetic Crystals, 2020, 49(9), 1705 (in Chinese).
赵瑨云, 苏丽鳗, 徐婕, 等. 人工晶体学报, 2020, 49(9), 1705.
32 Han M Y, Zhang J H, Hu Y Y, et al. Journal of Chemical and Enginee-ring Data, 2019, 64(8), 3641.
33 Alhassan S I, Wang H Y, He Y J, et al. Journal of Hazardous Materials, 2022, 430, 128401.
34 Tao W, Zhong H, Pan X B, et al. Journal of Hazardous Materials, 2020, 384, 121373.
35 Kiran M S, Bhandari R, Nehra A, et al. Journal of Dispersion Science and Technology, 2021, 42(10), 1550.
36 Gasparotto J M, Roth D, Perilli A L D, et al. Journal of Environmental Chemical Engineering, 2021, 9(6), 106350.
37 Jian S J, Cheng Y T, Hong H F, et al. Journal of Synthetic Crystals, 2022, 51(2), 316 (in Chinese).
简绍菊, 程意婷, 洪慧芳, 等. 人工晶体学报, 2022, 51(2), 316.
38 Yang W S, Liu Y F, Shi F S, et al. Acta Materiae Compositae Sinica, 2023, 40(6), 3385(in Chinese).
杨为森, 刘毅飞, 史丰硕, 等. 复合材料学报, 2023, 40(6), 3385.
39 Jeyaseelan A, Viswanathan N. Journal of Molecular Liquids, 2021, 326, 115163.

[1]	程婷, 陈晨, 张晓, 温明月, 王磊. Mn掺杂Zigzag(8,0)型单壁碳纳米管吸附甲醛分子的密度泛函理论研究[J]. 材料导报, 2024, 38(4): 22040187-6.
[2]	李佳敏, 常麟晖, 陈步明, 黄惠, 郭忠诚. 氯化物体系单槽双室电积锰工艺研究[J]. 材料导报, 2024, 38(3): 22010135-6.
[3]	周爱玲, 贾爱忠, 赵新强, 王延吉. 污水重金属离子选择性吸附的研究进展[J]. 材料导报, 2023, 37(9): 21110052-10.
[4]	杨旭, 历新宇, 周娟苹, 姜男哲. 含重金属离子废水处理技术研究进展[J]. 材料导报, 2023, 37(9): 21090197-10.
[5]	李娅, 马飞跃, 张明, 涂行浩, 杜丽清. 不同尺寸改性果胶基磁性微球的制备及对Pb²⁺吸附性能的研究[J]. 材料导报, 2023, 37(9): 21050165-8.
[6]	李贞, 刘加平, 乔敏, 于诚, 谢惟肖, 陈俊松. 基于减水剂吸附行为的再生微粉-水泥浆体黏度调控机理研究[J]. 材料导报, 2023, 37(8): 21090090-7.
[7]	王歆銘, 马晓宇, 崔素萍, 王剑锋, 王亚丽, 马骥堃. 钢渣内部金属氧化物调控提高干法脱硫性能研究[J]. 材料导报, 2023, 37(8): 21090022-4.
[8]	吴肖, 魏新莉, 赵栋, 翟文翔, 李旺. 栓皮栎软木分级多孔活性炭的制备及对亚甲基蓝的吸附[J]. 材料导报, 2023, 37(8): 21090088-7.
[9]	施宏玉, 邢冀琦, 薛培宏, 刘娟. 分子尺度下研究海洋污损生物的吸附机理[J]. 材料导报, 2023, 37(7): 21120126-7.
[10]	陶正凯, 荆肇乾, 王郑. 纳米纤维素材料在重金属废水治理中的应用[J]. 材料导报, 2023, 37(6): 21030120-8.
[11]	宋学锋, 陆伟宁. 转化方式对粉煤灰地聚物原位转化沸石及其Pb²⁺吸附性能的影响[J]. 材料导报, 2023, 37(6): 21070249-7.
[12]	栗启, 胡魁, 俞才华, 张桃利, 王丹丹. 聚乙烯与沥青相互作用的分子动力学机理研究[J]. 材料导报, 2023, 37(5): 21080176-6.
[13]	石现兵, 王涛, 吕明泽, 赵晋, 韩振邦. 树枝状PVDF纳米纤维膜负载TiO₂吸附-光催化降解染料废水[J]. 材料导报, 2023, 37(4): 21060080-6.
[14]	鲁浩, 杨强, 孔赟. 金属有机框架材料对水体中有机污染物的吸附去除及氧化降解研究进展[J]. 材料导报, 2023, 37(4): 22060239-13.
[15]	刘斌, 王文庆, 于知非, 汤晶, 李正心, 刘天中, 苏革. 氧化石墨烯/氧化铟/两性离子丙烯酸氟化聚合物复合膜的制备及抗牛血清白蛋白性能[J]. 材料导报, 2023, 37(4): 21010165-8.

[1]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4]	Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5]	Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6]	Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7]	Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8]	Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9]	Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10]	Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .

Viewed

Full text

Abstract

Cited

Shared

Discussed