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材料导报  2024, Vol. 38 Issue (22): 24030103-7    https://doi.org/10.11896/cldb.24030103
  路域废弃物资源化及高值化利用 |
化学活化方法对磨细火山岩弃渣-水泥复合胶凝体系的影响
谭盐宾1,2, 李林香1,2, 杨珍珍3, 邢梓达4, 林炘恺4, 葛昕1,2, 杨鲁1,2, 元强3,*
1 中国铁道科学研究院集团有限公司,北京 100081
2 高速铁路轨道系统全国重点实验室,北京 100081
3 中南大学土木工程学院,长沙 410083
4 中南大学邓迪国际学院,长沙 410083
Effect of Chemical Activation Methods on Volcanic Slag-Cement Composite Binder
TAN Yanbin1,2, LI Linxiang1,2, YANG Zhenzhen3, XING Zida4, LIN Xinkai4, GE Xin1,2, YANG Lu1,2, YUAN Qiang3,*
1 China Academy of Railway Sciences Corporation Limited, Beijing 100081, China
2 National Key Laboratory of High-speed Railway Track System, Beijing 100081, China
3 School of Civil Engineering, Central South University, Changsha 410083, China
4 Dundee International Institute, Central South University, Changsha 410083, China
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摘要 化学活化方法能够改善天然磨细火山岩弃渣作为矿物掺合料的工程适用性。采用强度活性指数法,对比了多种化学激发剂的活化效果,分析了化学激发剂类别及掺量对磨细火山岩弃渣-水泥复合胶凝体系的浆体凝结时间、流变性能以及孔结构的影响,并基于热重分析探索其影响机理。结果表明:化学激发剂对强度的提升效果更多地反映在中后期强度,Li2SO4、Na2SO4和三乙醇胺(TEA)对磨细火山岩弃渣活性的提升效果最佳,最高可达18%。化学激发剂会加速浆体凝结,还会增大新拌浆体的塑性黏度。化学激发剂可以降低复合胶凝体系的孔隙率,并可优化孔径分布,且对水泥的水化产物种类没有影响。
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谭盐宾
李林香
杨珍珍
邢梓达
林炘恺
葛昕
杨鲁
元强
关键词:  天然磨细火山岩弃渣  化学活化  激发剂  复合胶凝体系    
Abstract: The utilization of chemical activation method can enhance the applicability of natural volcanicash produced by waste slags as mineral admixtures in engineering applications. By employing the strength activity index method, a comparative analysis was conducted on the effects of various chemical activators on activation, and the impacts of activator type and dosage on setting time, rheological properties, and pore structure of pulverized pozzolan-cement composite binder were investigated. Results indicate that chemical activators have a more pronounced influence on strength enhancement during intermediate to late ages, with Li2SO4, Na2SO4, and TEA exhibiting superior performance in activating natural volcanic slags up to 18%. Chemical activators accelerate slurry setting while increasing plastic viscosity for newly mixed slurries. They also reduce porosity within composite binder while refining pores size distribution without affecting hydration product types.
Key words:  natural volcanic slags    chemical activation    activator    composite binder
出版日期:  2024-11-25      发布日期:  2024-11-22
ZTFLH:  TU528  
基金资助: 中国铁道科学研究院集团有限公司国家创新平台开放基金(2022YJ133);科技部国家重点研发计划(2022YFB2602604)
通讯作者:  *元强,中南大学土木工程学院教授、博士研究生导师。国家自然科学基金委优秀青年基金、中国硅酸盐学会青年科技奖获得者。主持国家级、省部级、企业课题60余项,长期围绕高速铁路建造与养维关键水泥基材料、3D 打印水泥基材料、新型结构材料、绿色低碳材料等领域开展研究,主持和参与项目获铁道学会特等奖1项、湖南省科技进步一等奖1项、湖南省自然科学三等奖1项,授权发明专利20余件,发表SCI论文100余篇,主持参与编写国家技术标准或规范 4 部。yuanqiang@csu.edu.cn   
作者简介:  谭盐宾,中国铁道科学研究院集团有限公司铁建所工程材料事业部副主任、研究员、硕士研究生导师。2004年重庆大学材料科学与工程学院无机非金属材料专业本科毕业,2007年重庆大学材料科学与工程学院材料科学与工程专业硕士毕业后到中国铁道科学研究院集团有限公司工作至今。目前主要从事铁路高性能混凝土制备与耐久性提升技术、无砟轨道自密实混凝土技术、功能外加剂技术的研究。发表论文20余篇,授权国家发明专利26项、实用新型专利15项,先后获国家发明专利优秀奖2项、省部级奖励12项。
引用本文:    
谭盐宾, 李林香, 杨珍珍, 邢梓达, 林炘恺, 葛昕, 杨鲁, 元强. 化学活化方法对磨细火山岩弃渣-水泥复合胶凝体系的影响[J]. 材料导报, 2024, 38(22): 24030103-7.
TAN Yanbin, LI Linxiang, YANG Zhenzhen, XING Zida, LIN Xinkai, GE Xin, YANG Lu, YUAN Qiang. Effect of Chemical Activation Methods on Volcanic Slag-Cement Composite Binder. Materials Reports, 2024, 38(22): 24030103-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.24030103  或          http://www.mater-rep.com/CN/Y2024/V38/I22/24030103
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