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《材料导报》期刊社  2017, Vol. 31 Issue (16): 107-111    https://doi.org/10.11896/j.issn.1005-023X.2017.016.022
  材料研究 |
Ni-25Cr-20Co合金时效组织结构及性能研究
魏力民1,2, 杨权1,2, 程义1,2, 谭舒平1,2
1 哈尔滨锅炉厂有限责任公司材料研究所, 哈尔滨 150046;
2 高效清洁燃煤电站锅炉国家重点实验室, 哈尔滨 150046
Microstructure and Properties of Ni-25Cr-20Co Alloy After Long-term Aging
WEI Limin1,2, YANG Quan1,2, CHENG Yi 1,2, TAN Shuping1,2
1 Material Research Institute of Harbin Boiler Co., Ltd, Harbin 150046;
2 State Key Laboratory of Efficient and Clean Coal-fired Utility Boilers, Harbin 150046
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摘要 在Thermo-Calc热力学软件模拟计算基础上,采用光学显微镜、扫描电子显微镜、能谱检测和透射电子显微镜研究了Ni-25Cr-20Co合金在长期时效过程中析出相的变化情况及对性能的影响,理论分析了γ′相颗粒粗化对合金拉伸变形过程中第二相与位错交互作用机制的影响。结果表明:经750 ℃时效后合金中析出MC、M23C6和γ′相,γ′相的体积分数约为16%。长期时效后,γ′相颗粒的平均尺寸与时间t符合LSW理论,受溶质原子扩散及γ/γ′界面能的影响。时效后合金的拉伸强度明显增加,随时效时间的延长,拉伸强度逐渐降低。随γ′相的粗化,拉伸变形过程中第二相与位错交互作用的机制由位错热攀移机制→位错切割机制→Orowan绕越机制转变为位错热攀移机制→Orowan绕越机制→位错切割机制。
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魏力民
杨权
程义
谭舒平
关键词:  Ni-25Cr-20Co合金  长期时效  组织结构  γ′相  变形机制    
Abstract: Based on Thermo-Calc software, the microstructure and mechanical properties of Ni-25Cr-20Co alloy after long-term aging at 750 ℃ was investigated using OM, SEM, TEM and tensile testing. The relationship between dislocation resistance mechanism and γ′ phase size was calculated. The results show that MC, M23C6 and γ′ phase are the main precipitates, the volume fraction of γ′ phase is 16%. The growth kinetic of γ′ phase follows LSW theory, affecting by the diffusion of solute atoms and interface energy of γ/γ′. The tensile strength increases obviously after aging treatment. The tensile strength decreases with the extending aging time. Deformation mechanism in stretching process is changed with the growth of γ′ phase. When γ′ phase is small, deformation mechanism is climb mechanism→cut mechanism→Orowan mechanism. Deformation mechanism switch to climb mechanism→Orowan mechanism→cut mechanism when γ′ phase exceed critical value.
Key words:  Ni-25Cr-20Co alloy    long-term aging    microstructure    γ′ phase    deformation mechanism
               出版日期:  2017-08-25      发布日期:  2018-05-07
ZTFLH:  TG113.12  
通讯作者:  谭舒平:通讯作者,男,1963年生,博士,研究员级高级工程师,研究方向为耐热材料研究及寿命分析 E-mail:beyond4650@163.com   
作者简介:  魏力民:男,1986年生,硕士研究生,工程师,研究方向为材料微观组织及性能演变
引用本文:    
魏力民, 杨权, 程义, 谭舒平. Ni-25Cr-20Co合金时效组织结构及性能研究[J]. 《材料导报》期刊社, 2017, 31(16): 107-111.
WEI Limin, YANG Quan, CHENG Yi, TAN Shuping. Microstructure and Properties of Ni-25Cr-20Co Alloy After Long-term Aging. Materials Reports, 2017, 31(16): 107-111.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.016.022  或          http://www.mater-rep.com/CN/Y2017/V31/I16/107
1 Maile K. Use of advanced alloy 617 mod for critical components of the future 700 ℃ coal fired power plant[C]//2009 Symposium on Advanced Power Plant Heat Resistant Steels and Alloys. Shanghai: The Materials Institution, Chinese Society of Power Engineering,2009:1.
2 周兰章. 700 ℃超超临界机组耐热材料的研制现状及选材思考[C]//国家700 ℃计划耐热材料第一次专题研讨会.北京: 国家700℃超超临界燃煤发电技术创新联盟秘书处,2011:13.
3 Zhu B T,Zhou R C.Problems paid attention to raise the ultrasupercritical units steam parameters [J]. Proceedings of the CSEE,2009,29(S):95(in Chinese).
朱宝田,周荣灿.进一步提高超超临界机组蒸汽参数应注意的问题[J].中国电机工程学报,2009,29(S):95.
4 Zhang H J, Zhou R C, Hou S F, et al. Microstructure stability of candidate material alloy263 for advanced USC unit [J]. J Chinese Soc Power Eng,2011(12):969(in Chinese).
张红军,周荣灿,侯淑芳,等. 先进超超临界机组用候选材料Alloy263的组织稳定性[J]. 动力工程学报,2011(12):969.
5 Xiao X, Zhao H Q, Wang C S, et al. Effects of B and P on microstructure and mechanical properties of GH984 alloy [J]. Acta Metall Sin,2013,29(4):421(in Chinese).
肖旋,赵海强,王常帅,等. B和P对GH984合金组织和力学性能的影响[J]. 金属学报,2013,29(4):421.
6 Shi Y Y, Jiao S Y, Dong J X, et al. Classical precipitation dynamic model of γ′ phase of nickel-based super alloys and applications [J]. Acta Metall Sin,2012(6):661(in Chinese).
石宇野,焦少阳,董建新,等. 镍基高温合金γ′相析出的经典动态模型及应用[J]. 金属学报,2012(6):661.
7 Tan M L, et al. Influence of Ti/Al ratios on γ′ coarsening behavior and tensile properties of GH984G alloy during long-term thermal exposure [J]. Acta Metall Sin,2014(10):1260(in Chinese).
谭梅林,等. Ti/Al比对GH984G合金长期时效过程中γ′沉淀相粗化行为及拉伸性能的影响[J]. 金属学报,2014(10):1260.
8 Grosdidier T, Hazotte A, Simon A. Precipitation and dissolution processes in γ/γ′ single crystal nickel-based superalloys[J]. Mater Sci Eng A,1998,256(1):183.
9 MacKay R A, Nathal M V. γ′ coarsening in high volume fraction nickel-base alloys [J]. Acta Metall Mater,1990,38(6):S93.
10 Kim H T, Chun S S, Yao X X, et al. Gamma prime (γ′) precipita-ting and ageing behaviours in two newly developed nickel-base super alloys [J]. J Mater Sci,1997,32(18):4917.
11 Zhang H J, Zhou R C, Hou S F, et al. Study on microstructure stability of Inconel 740 for advanced ultra supercritical unit [J]. Proceedings of the CSEE,2011,31(8):108(in Chinese).
张红军,周荣灿,侯淑芳,等. 先进超超临界机组用 Inconel 740 合金的组织稳定性研究[J]. 中国电机工程学报,2011,31(8):108.
12 Lifshitz I M, Slyozov V V. The kinetics of precipitation from supersaturated solid solutions [J]. J Phys Chem Solids,1961,19(1-2):35.
13 Wagner C. See, for instance, the following references: Z [J]. Elektrochem,1961,65:581.
14 Sparke B, James D W, Leak G M. Lattice diffusion in gamma-iron [J]. J Iron Steel Institute,1965,203:152.
15 Barford J. Physical properties of martensite and bainite[J]. Iron Steel Inst J,1966,204(4):392.
16 Minamino Y, Jung S B, et al. Diffusion of cobalt, chromium, and titanium in Ni3Al [J]. Metall Trans A,1992,23(10):2783.
17 Gomez-Acebo T, Navarcorena B, Castro F. Inter diffusion in multiphase, Al-Co-Cr-Ni-Ti diffusion couples [J]. J Phase Equilibria Diffusion,2004,25(3):237.
18 Brown L M, Ham R K. Strengthening methods in crystals[M].London: Applied Science,1971:9
19 Pollock T M, Argon A S. Creep resistance of CMSX-3 nickel base superalloy single crystals [J]. Acta Metall Mater,1992,40(1):1.
20 Schwarz R B, Labusch R. Dynamic simulation of solution hardening [J]. J Appl Phys,1978,49(10):5174.
21 赵双群, 谢锡善, 董建新. 700 ℃超超临界燃煤电站用镍基高温合金Inconel740/740H的组织与性能[C]//第九届电站金属材料学术年会. 成都,2011:278.
22 Shewfelt R S W, Brown L M. High-temperature strength of dispersion-hardened single crystals Ⅱ. Theory [J]. Philosophical Magazine,1977,35(4):945.
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