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《材料导报》期刊社  2018, Vol. 32 Issue (1): 51-57    https://doi.org/10.11896/j.issn.1005-023X.2018.01.006
  物理   材料综述 ｜材料 |
铁酸锌作为光催化剂的研究进展
侯桂芹1,2(),李云凯1,王晓燕2
1 北京理工大学材料学院,北京100081
2 华北理工大学轻工学院,唐山 063000
Research Progress of Zinc Ferrite as Photocatalyst
Guiqin HOU1,2(),Yunkai LI1,Xiaoyan WANG2
1 School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081
2 Qing Gong College, North China University of Science and Technology, Tangshan 063000
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摘要 

铁酸锌是具有较高光催化活性及对可见光敏感的n型半导体,其独特的磁性能和化学稳定性使其在光催化领域有着广泛的应用。针对不同形貌的铁酸锌,采用不同的改性方法,可将其与其他材料结合制备出更为高效、实用的光催化剂。近年来,利用铁酸锌的特性,制备磁性可回收且性能稳定的复合光催化剂引起了科研人员的广泛关注。概述了铁酸锌作为光催化剂的基本性质,对不同形貌铁酸锌的制备方法进行了总结,并重点讨论了铁酸锌在光催化方面的改性技术及改性机理,最后对目前存在的问题和未来的研究方向做了简要的总结和预测。
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侯桂芹
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关键词:  铁酸锌  形貌  改性  光催化    
Abstract: 

Zinc ferrite is a n-type semiconductor with high photocatalytic activity and visible light sensitive, the unique magnetic properties and chemical stability make it widely used in the field of photocatalysis. For various morphology of zinc ferrite, different modification methods can be taken to make it more efficient and practical. In recent years, taking advantage of the zinc ferrite characteristics, the preparation of magnetic recovery and stable performance of the composite photocatalyst has attracted the attention of researchers. In this paper, the basic properties of zinc ferrite as photocatalyst and the preparation methods of various morphology are introduced. The modification technology and modification mechanism of zinc ferrite in photocatalysis are discussed. At the same time, the existing problems and prospects are pointed out.
Key words:  ZnFe2O4    morphology    modification    photocatalysis
               出版日期:  2018-01-10      发布日期:  2018-01-10
ZTFLH:  TB34  
作者简介:  侯桂芹:女,1980年生,博士研究生,讲师,主要从事光催化材料的研究 E-mail: 283636899@qq.com
引用本文:    
侯桂芹,李云凯,王晓燕. 铁酸锌作为光催化剂的研究进展[J]. 《材料导报》期刊社, 2018, 32(1): 51-57.
Guiqin HOU,Yunkai LI,Xiaoyan WANG. Research Progress of Zinc Ferrite as Photocatalyst. Materials Reports, 2018, 32(1): 51-57.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.01.006  或          http://www.mater-rep.com/CN/Y2018/V32/I1/51
图1  (a) ZnFe2O4的晶体结构,氧离子构成的(b)四面体单元和(c)八面体单元
图2  ZnFe2O4光催化机理示意图
图3  溶液燃烧法制备的ZnFe2O4的TEM 及HRTEM 图
图4  (a)ZnFe2O4纳米棒的磁滞回线和(b)多孔纳米棒铁酸锌的形貌图
图5  (a)花状和(b)片状铁酸锌的SEM图
图6  (a)铁酸锌纳米线扫描电镜图;(b)铁酸锌纳米管扫描电镜图
图7  中空 ZnFe2O4微球的制备过程和形成机理
Morphologies Preparation
method		 Catalyst
dosage		 Degradation
dyes		 Degradation
time		 Photocatalytic
activity
Bulk Solution combustion synthesis 0.1 g, 21.9 nm 100 mL, 10 mg/L
RhB		 300 W, Xe
lamp,2 h		 61.3%
Porous
nanorods		 Template-surfactant-free
solvothermal method		 100 mg, diameters of 100—
200 nm and lengths of
several micrometers		 100 mL, 5 mg/L
MB		 Sunlight,April,
10∶00—16∶00		 85%
Floriated Mild hydrothermal and calcination
processes by using CTABr as a
template-directing reagent		 100 mg, average length of
122 nm and diameter of
29 nm		 80 mL water and
20 mL methanol		 250 W,
Xe lamp, 5 h		 237.87(mmol·g)/L
Flaky Mild hydrothermal and
calcination processes		 100 mg 80 mL water and
20 mL methanol		 250 W,
Xe lamp, 5 h		 87.40(mmol·g)/L
Nanotube Anodic aluminum oxide templates
from sol-gel solution		 Average diameter of
approximately 200 nm		 100 mL, 10 mg/L,
4-CP		 500 W,
Xe lamp, 6 h		 100%
表1  不同形貌铁酸锌的制备方法及其光催化活性
图8  光照作用下不同半导体光催化剂之间的复合示意图
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