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材料导报  2022, Vol. 36 Issue (17): 21060143-7    https://doi.org/10.11896/cldb.21060143
  金属与金属基复合材料 |
不同温度低压真空渗氮对新型TiZr基合金微观组织及摩擦学性能的影响
吕源远1,2, 岳赟1,*, 杜志浩1,2, 杜三明1, 倪锋1, 张永振1
1 河南科技大学高端轴承摩擦学技术与应用国家地方联合工程实验室, 河南 洛阳 471023
2 河南科技大学材料科学与工程学院, 河南 洛阳 471023
Effect of Low-pressure Vacuum Nitriding Temperatures on Microstructure and Tribological Properties of Novel TiZr-based Alloy
LYU Yuanyuan1,2, YUE Yun1,*, DU Zhihao1,2, DU Sanming1, NI Feng1, ZHANG Yongzhen1
1 National United Engineering Laboratory for Advanced Bearing Tribology, Henan University of Science and Technology, Luoyang 471023, Henan, China
2 School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, Henan, China
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摘要 以新型钛锆基合金Ti-47Zr-5Al-3V(以下称47Zr)为研究对象,研究了不同温度(650 ℃、700 ℃、750 ℃、800 ℃、850 ℃)低压真空渗氮对合金的摩擦学性能的影响。使用扫描电子显微镜(SEM)和X射线衍射仪(XRD)、显微维氏硬度计及UMT-2摩擦磨损试验机对低压真空渗氮后合金的组织、物相、硬度及摩擦磨损性能进行分析和测试。结果表明,低压真空渗氮后,47Zr合金表面物相以Ti2N、ZrN化合物为主,硬度最高可达710HV0.05,表面平均硬度与基体相比提升近285HV0.05,渗氮影响层的深度随着温度的升高而增加。不同温度低压真空渗氮47Zr合金中,耐磨性较好的为经750 ℃和800 ℃渗氮的样品。相较于原始样品,750 ℃低压真空渗氮后,样品的平均摩擦系数减小57.14%,磨损率在固定载荷(30 N)下降低29.74%;800 ℃低压真空渗氮后,样品的平均摩擦系数减小了45.71%,磨损率下降了33.74%。合金的磨损特征表明不同温度低压真空渗氮的47Zr合金在室温干摩擦条件下的磨损机制均为磨粒磨损和粘着磨损。
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吕源远
岳赟
杜志浩
杜三明
倪锋
张永振
关键词:  钛锆基合金  渗氮  组织  摩擦磨损    
Abstract: Novel TiZr-based alloy Ti-47Zr-5Al-3V (referred to as 47Zr) was studied to reveal the effect of low-pressure vacuum nitriding at different temperatures (650 ℃, 700 ℃, 750 ℃, 800 ℃ and 850 ℃) on its tribological properties. Microstructure, phase composition, hardness and tribological properties of 47Zr alloy with low-pressure vacuum nitriding were analyzed and tested by scanning electron microscopy (SEM), X-ray diffraction (XRD), micro-Vickers and UMT-2 multifunctional tribometer. The results indicate that the surface phase composition of nitriding 47Zr alloy is dominated by Ti2N and ZrN compounds, and its hardness is high up to 710HV0.05. Compared with the substrate, the average hardness of the surface increases by nearly 285HV0.05. The depth of nitrided layer increases with nitriding temperature rising. Compared with the untreated samples, the average coefficient of friction (COF) decreases by 57.14% through low-pressure vacuum nitriding at 750 ℃, and the wear rate decreases by 29.74% under a normal load of 30 N. Through nitriding at 800 ℃, the average COF and wear rate decrease by 45.71% and 33.74%, respectively. The wear characteristics show that the wear mechanism of the low-pressure vacuum nitrided 47Zr alloy at different temperature is abrasive wear and adhesive wear under dry sliding condition.
Key words:  TiZr-based alloy    nitriding    microstructure    friction and wear
出版日期:  2022-09-10      发布日期:  2022-09-10
ZTFLH:  TB333  
基金资助: 国家自然科学基金(51801054)
通讯作者:  *yueyunbw@haust.edu.cn   
作者简介:  吕源远,河南科技大学材料工程在读硕士。2019年获得河南科技大学金属材料工程学士学位。目前从事新型钛锆基合金表面改性及摩擦学性能研究。
岳赟,河南科技大学讲师。2017年7月毕业于燕山大学,获材料学博士学位。同年加入河南科技大学高端轴承摩擦学技术与应用国家地方联合工程实验室工作至今,主要从事钛合金表面改性及摩擦学性能表征。在国内外重要期刊发表文章30余篇,申报发明专利10余项。
引用本文:    
吕源远, 岳赟, 杜志浩, 杜三明, 倪锋, 张永振. 不同温度低压真空渗氮对新型TiZr基合金微观组织及摩擦学性能的影响[J]. 材料导报, 2022, 36(17): 21060143-7.
LYU Yuanyuan, YUE Yun, DU Zhihao, DU Sanming, NI Feng, ZHANG Yongzhen. Effect of Low-pressure Vacuum Nitriding Temperatures on Microstructure and Tribological Properties of Novel TiZr-based Alloy. Materials Reports, 2022, 36(17): 21060143-7.
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http://www.mater-rep.com/CN/10.11896/cldb.21060143  或          http://www.mater-rep.com/CN/Y2022/V36/I17/21060143
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