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材料导报  2021, Vol. 35 Issue (20): 20143-20148    https://doi.org/10.11896/cldb.20090061
  金属与金属基复合材料 |
可控电磁能(CEME)时效处理下Al-Zn-Mg-Cu合金的析出及强化机理研究
白庆伟1,2, 麻永林2, 邢淑清2, 于文霞2, 陈重毅2
1 内蒙古科技大学材料与冶金学院(稀土学院), 包头 014010
2 内蒙古自治区白云鄂博矿多金属资源综合利用重点实验室, 包头 014010
Precipitation and Strengthening Mechanism of Al-Zn-Mg-Cu Alloy Under Controllable Electromagnetic Energy (CEME) Aging Treatment
BAI Qingwei1,2, MA Yonglin2, XING Shuqing2, YU Wenxia2, CHEN Zhongyi2
1 School of Material and Metallurgy(School of Rare Earth), Inner Mongolia University of Science & Technology, Baotou 014010, China
2 Key Laboratory of Comprehensive Utilization of Polymetallic Resources of Bayan Obo Mine, Inner Mongolia Autonomous Region, Baotou 014010, China
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摘要 文中提出了可控电磁能(CEME)铝合金辅助时效处理技术,研究了脉冲电磁场产生的可控电磁能对Al-Zn-Mg-Cu合金析出相密度、尺寸分布及力学性能的影响并分析了组织强化机制。引入磁-热扩散模型和量子力学探讨外加脉冲磁能作用下Al-Zn-Mg-Cu合金的扩散析出机理。结果表明,施加脉冲电磁场有利于增加析出质点数量,而延长时效可促进析出相长大,经脉冲电磁场时效1 h后的析出相分布密度为1.124 μm-2,约为传统时效12 h的3倍,其抗拉强度分别为506 MPa和542 MPa;随着析出相尺寸的增大,强化机理由共格应变场强化机制(OS)过渡至Orowan绕过强化模型(CS),理论临界析出颗粒尺寸为20 nm。动力学分析认为,外加磁能对扩散激活能的Gtot 作用较小,提高原子振动频率v0是增加析出质点数量的主要原因。
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白庆伟
麻永林
邢淑清
于文霞
陈重毅
关键词:  析出强化  外加磁能  磁-热扩散模型  Larmor频率    
Abstract: Pulsed electromagnetic fields could induce controlled electromagnetic energy (CEME). Auxiliary aging treatment of Al-Zn-Mg-Cu alloy was performed by pulsed electromagnetic field. The effects of pulsed electromagnetic field on the precipitation density, size distribution and mechanical properties were investigated, and the mechanism of microstructure strengthening was analyzed. The magnetic-thermal diffusion model and quantum mechanics were introduced to explore the evolution of precipitation phase under pulsed magnetic energy. The results showed that the number of precipitated particles increases under the pulsed electromagnetic field, while prolonged aging time promotes the growth of the precipitated phase. The density of the precipitated phase is 1.124 μm-2 after pulsed electromagnetic field aging for 1 h, which is about three times the traditional aging 12 h. The strengths of aged Al-Zn-Mg-Cu alloy are 506 MPa and 542 MPa, respectively. The strengthening mechanism of precipitation changes from coherent strain field strengthening mechanism (CS) transitions to the Orowan by pass strengthening model (OS) with the increase of the precipitate size, and the theoretical critical precipitate size is 20 nm. The kinetic analysis indicates that the electromagnetic energy almost has no effect on the diffusion activation energy, and increasing the atomic vibration frequency is the main reason for increasing the number of precipitated particles.
Key words:  precipitation strengthening    electromagnetic energy    magnetic-thermal diffusion model    Larmor frequency
               出版日期:  2021-10-25      发布日期:  2021-11-12
ZTFLH:  TF821  
基金资助: 内蒙古自治区自然科学基金(2020BS05021;2018MS05008);内蒙古科技大学创新基金(2019QDL-B16);内蒙古自治区重大基础研究开放课题(0406091701);内蒙古自治区科技计划项目(2021GG0095);国家留学基金委员会的留学资助(201708150077)
通讯作者:  abcqingwei@163.com; malin@imust.cn   
作者简介:  白庆伟,2015年9月至2018年12月于法国国家科学院SIMAP/EPM实验室/内蒙古科技大学公派联合培养攻读冶金工程博士学位,2019年1月任职内蒙古科技大学。以第一作者在国内外学术期刊上发表论文20余篇,申请国家专利6项,主持省部级科研项目3项,担任多个学术期刊的审稿人。研究工作主要围绕电磁冶金、材料电磁过程领域的交叉学科,主要开展微波辐射/脉冲电磁场下材料的相变行为及其冶金过程数值模拟研究。
麻永林,内蒙古科技大学教授,博士研究生导师,享受国务院政府特殊津贴。获东北大学材料加工博士学位。其中2007—2008年到瑞典皇家工学院访问、合作研究。在国内外学术期刊上发表论文200余篇,申请专利20余项。其团队主要研究方向包括:低熔点合金电磁能形核机理研究及其应用;低熔点合金电磁泵送系统研发。先后开展了数十项科学研究和技术合作项目,多个项目通过专家鉴定,并在工业中得到应用,取得了良好的经济效益。获得省部级一等奖3项,三等奖4项,地市级科技进步奖多项。完成和正在承担的项目包括:科技部国际合作专项、国家科技重大专项、工信部民口配套项目、国家自然科学基金、教育部、内蒙古自治区科技厅、教育厅以及包头市项目等多项;同时与部分企业、国家重点实验室和国外教授合作项目多项。培养博士7名、在读硕士20余名。
引用本文:    
白庆伟, 麻永林, 邢淑清, 于文霞, 陈重毅. 可控电磁能(CEME)时效处理下Al-Zn-Mg-Cu合金的析出及强化机理研究[J]. 材料导报, 2021, 35(20): 20143-20148.
BAI Qingwei, MA Yonglin, XING Shuqing, YU Wenxia, CHEN Zhongyi. Precipitation and Strengthening Mechanism of Al-Zn-Mg-Cu Alloy Under Controllable Electromagnetic Energy (CEME) Aging Treatment. Materials Reports, 2021, 35(20): 20143-20148.
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http://www.mater-rep.com/CN/10.11896/cldb.20090061  或          http://www.mater-rep.com/CN/Y2021/V35/I20/20143
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