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材料导报  2019, Vol. 33 Issue (11): 1805-1812    https://doi.org/10.11896/cldb.18060005
  核材料 |
不同合金成分的T91/316L焊缝在550 ℃高流速液态铅铋共晶合金中的腐蚀行为
肖龙仁, 雷玉成, 朱强, 李天庆, 陈钢, 罗梦, 赵军, 陈文彬
江苏大学材料科学与工程学院,镇江 212013
Corrosion Behavior of T91/316L Weld Seams with Different Chemical Compositions in 550 ℃ High-speed Flowing Liquid Lead-bismuth Eutectic Alloy
XIAO Longren, LEI Yucheng, ZHU Qiang, LI Tianqing, CHEN Gang, LUO Meng, ZHAO Jun, CHEN Wenbin
School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013
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摘要 T91/316L异种钢焊缝在高流速液态铅铋共晶合金(LBE)中的腐蚀是T91和316L钢在未来核电领域应用中所面临的重要挑战。利用ER309L、ER316L和ERNiCr-3三种不同焊丝获得了T91/316L异种钢焊缝,采用自主设计的旋转腐蚀试验装置研究其在550 ℃高流速(相对流速2.98 m/s)液态LBE中的腐蚀。三种焊缝经过300 h、600 h和900 h的腐蚀试验后,腐蚀表面均表现出明显的方向性。焊缝在高流速液态LBE中的腐蚀机理主要为焊缝基体中Fe、Cr、Ni元素和LBE中Pb、Bi、O元素的溶解与迁移。由于不同元素的溶解度以及所形成氧化物相的稳定程度不同,最终在焊缝表面形成了由疏松外氧化层和致密内氧化物层构成的双层结构。三种焊丝中,利用309L焊丝所得的焊缝的耐高流速LBE腐蚀性最好,利用316L焊丝所得的焊缝次之,利用NiCr-3焊丝所得的焊缝最差。经焊后再热处理所得的焊缝具有更好的耐高流速LBE腐蚀性。
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肖龙仁
雷玉成
朱强
李天庆
陈钢
罗梦
赵军
陈文彬
关键词:  T91钢  316L钢  铅铋共晶合金(LBE)  焊缝  腐蚀    
Abstract: The corrosion of T91/316L dissimilar weld seam in high-speed flowing liquid lead-bismuth eutectic alloy (LBE) is an important challenge for the future application of T91 and 316L steels in nuclear industry. In this paper, the corrosion test of T91/316L dissimilar weld seams obtained by using three different welding wires (ER309L, ER316L and ERNiCr-3) in 550 ℃ high-speed flowing liquid LBE (relative flow rate of 2.98 m/s) was carried out in a self-designed rotary corrosion device. After being corroded for 300 h, 600 h and 900 h, the surface of all weld seams showed obvious directionality. The corrosion mechanism of weld seam in the high-speed flowing liquid LBE is mainly the dissolution and migration of Fe, Cr and Ni elements in the weld matrix and Pb, Bi, and O elements in the LBE. Due to the different solubility of different elements and the different stability of oxide phases, a double-layer structure consisting of a loose outer oxide layer and a dense inner oxide layer was finally formed on the surface of weld seam. The corrosion resistance of weld seam by using 309L welding wire in the high-speed flowing LBE was the best, followed by 316L welding wire, and that using NiCr-3 welding wire was the worst. The weld seam after heat treatment showed better corrosion resistance to high-speed flowing LBE.
Key words:  T91 steel    316L steel    lead-bismuth eutectic alloy (LBE)    weld seam    corrosion
                    发布日期:  2019-05-21
ZTFLH:  TL341  
基金资助: 国家自然科学基金(51375216);国家自然科学基金青年基金(51505197)
通讯作者:  yclei@ujs.edu.cn   
作者简介:  肖龙仁,2015年9月至2018年6月在江苏大学攻读硕士研究生学位,主要从事T91/316L异种钢焊接接头耐腐蚀性的研究,在国内外重要期刊上发表文章6篇。雷玉成,1962年生,博士,教授,博士研究生导师,主要从事先进材料的连接技术和焊接过程控制及模拟,负责过多项国家自然科学基金项目,在国内外重要期刊发表文章100余篇。
引用本文:    
肖龙仁, 雷玉成, 朱强, 李天庆, 陈钢, 罗梦, 赵军, 陈文彬. 不同合金成分的T91/316L焊缝在550 ℃高流速液态铅铋共晶合金中的腐蚀行为[J]. 材料导报, 2019, 33(11): 1805-1812.
XIAO Longren, LEI Yucheng, ZHU Qiang, LI Tianqing, CHEN Gang, LUO Meng, ZHAO Jun, CHEN Wenbin. Corrosion Behavior of T91/316L Weld Seams with Different Chemical Compositions in 550 ℃ High-speed Flowing Liquid Lead-bismuth Eutectic Alloy. Materials Reports, 2019, 33(11): 1805-1812.
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http://www.mater-rep.com/CN/10.11896/cldb.18060005  或          http://www.mater-rep.com/CN/Y2019/V33/I11/1805
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