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材料导报  2021, Vol. 35 Issue (z2): 46-49    
  无机非金属及其复合材料 |
镍源对催化酚醛树脂原位生成碳纳米管的影响
谢丹丹, 张宝荣, 赵晖, 刘君, 宋安康, 朱国本, 马爱珍, 宋文文, 赵海峰
青岛正望钢水控制股份有限公司,青岛 266200
Influence of Nickel Sources on the In-situ Formation of Carbon Nanotubes via Catalytic Pyrolysis of Phenolic Resin
XIE Dandan, ZHANG Baorong, ZHAO Hui, LIU Jun, SONG Ankang, ZHU Guoben, MA Aizhen, SONG Wenwen, ZHAO Haifeng
Qingdao Hiworld Motlen Steel Control. Co. Ltd., Qingdao 266200, China
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摘要 分别将硝酸镍和乙酸镍两种镍源作为催化剂前驱体加入酚醛树脂中,在N2保护气氛中催化碳纳米管原位生成。采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射仪(XRD)分别研究两种镍源对生成碳纳米管的形貌、结构和热解产物石墨化程度的影响。实验结果表明,含硝酸镍酚醛树脂生成的碳纳米管长径比和热解产物的石墨化程度均高于含乙酸镍酚醛树脂。两种镍源在酚醛树脂中的分散状态是影响碳纳米管生成差异的主要原因。
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谢丹丹
张宝荣
赵晖
刘君
宋安康
朱国本
马爱珍
宋文文
赵海峰
关键词:  酚醛树脂  镍源  催化  原位生成  碳纳米管    
Abstract: Carbonnanotubes (CNTs) were in-situ formed via catalytic pyrolysis of phenol resin using nickel nitrate and nickel acetate as the catalyst precursor in the N2 atmosphere, respectively. The effect of the nickel sources on the morphology and structure of CNTs and the crystallization degree of pyrolytic products were investigated. The graphitization degree of pyrolytic products and the structure of CNTs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscope (TEM). Results showed that the length to diameter ratio of CNTs and the graphitization degree of pyrolytic products of phenolic resin containing nickel nitrate were higher than that containing nitrate acetate. The dispersion of the two nickel sources in phenolic resin is the main effect reason for the different formation of CNTs.
Key words:  phenolic resin    nickel sources    catalytic    in-situ formation    carbon nanotubes (CNTs)
                    发布日期:  2021-12-09
ZTFLH:  TB324  
通讯作者:  zhaohiworld@163.com   
作者简介:  谢丹丹,2016年6月毕业于青岛科技大学,获得工程硕士学位。于2016年7月在青岛正望钢水控制股份有限公司工作至今,主要从事功能无机非金属材料领域的研究。
赵海峰,2021年6月毕业于青岛科技大学,获得材料学博士学位。2021年入选青岛市“高层次人才”拔尖人才。于2003年6月在青岛正望钢水控制股份有限公司工作至今,主要从事功能无机非金属材料领域的研究。主持和参与完成“青岛市创新型中小企业培育计划项目”、企业技术创新项目40余项;以第一作者发表学术论文3篇,以第一完成人授权发明专利1项,实用新型专利9项,参与制修定国家标准1项,黑色冶金行业标准2项。
引用本文:    
谢丹丹, 张宝荣, 赵晖, 刘君, 宋安康, 朱国本, 马爱珍, 宋文文, 赵海峰. 镍源对催化酚醛树脂原位生成碳纳米管的影响[J]. 材料导报, 2021, 35(z2): 46-49.
XIE Dandan, ZHANG Baorong, ZHAO Hui, LIU Jun, SONG Ankang, ZHU Guoben, MA Aizhen, SONG Wenwen, ZHAO Haifeng. Influence of Nickel Sources on the In-situ Formation of Carbon Nanotubes via Catalytic Pyrolysis of Phenolic Resin. Materials Reports, 2021, 35(z2): 46-49.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2021/V35/Iz2/46
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