高镁硅红土镍矿开发利用研究现状

材料导报

2020, Vol. 34

Issue (Z1): 261-267

无机非金属及其复合材料

高镁硅红土镍矿开发利用研究现状

曲涛^1,2,3,4, 谷旭鹏^1,2,3, 施磊^2,3,4, 罗铭洋^2,3,4, 王强^2,3,4, 吕飞^1,2,3, 田源^2,3,4, 戴永年^1,2,3,4

1 昆明理工大学省部共建复杂有色金属资源清洁利用国家重点实验室,昆明 650093;
2 昆明理工大学真空冶金国家工程实验室,昆明 650093;
3 云南省有色金属真空冶金重点实验室,昆明 650093;
4 昆明理工大学冶金与能源工程学院,昆明 650093

Research Status of Development and Utilization of Garnierite

QU Tao^1,2,3,4, GU Xupeng^1,2,3, SHI Lei^2,3,4, LUO Mingyang^2,3,4, WANG Qiang^2,3,4, LYU Fei^1,2,3, TIAN Yuan^2,3,4, DAI Yongnian^1,2,3,4

1 State Key Laboratory of Complex Non-ferrous Metal Resources Clear Utilization, Kunming University of Science and Technology, Kunming 650093, China;
2 National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China;
3 Key Laboratory of Vacuum Metallurgy for Nonferrous Metal of Yunnan Province, Kunming 650093, China;
4 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 2407KB )
输出: BibTeX | EndNote (RIS)

摘要近年来,随着硫化镍矿被不断消耗,红土镍矿的开发利用引起了广泛关注。红土镍矿中的高镁硅红土镍矿镍含量较高,更具开发价值。为提高高镁硅红土镍矿的开发利用水平,对高镁硅红土镍矿资源的火法及湿法处理工艺和机理进行了综述。指出传统火法工艺虽然流程短、操作简单,但仅回收矿物中的Ni、Fe,无法回收其中的Mg;而真空碳热还原工艺能够综合回收矿物中的Ni、Fe、Mg,创造更高的经济效益。湿法工艺中的酸法虽然能够有效回收矿物中的Ni、Co,但存在成本高、对环境不友好等问题;而碱法则能使Ni、Fe富集,还能够制备出白炭黑(SiO₂)产品,该工艺所用试剂可以循环利用,具有良好的发展前景。昆明理工大学课题组针对火法、湿法工艺存在的问题,提出了一种火法-湿法联合处理工艺,能够综合回收高镁硅红土镍矿中的Mg、Si、Ni、Fe等元素,期望为高镁硅红土镍矿的综合利用提供思路。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	曲涛
	谷旭鹏
	施磊
	罗铭洋
	王强
	吕飞
	田源
	戴永年

关键词: 高镁硅红土镍矿火法工艺湿法工艺综合利用

Abstract: With the continuous consumption of nickel sulphide ore in recent years, the development and utilization of laterite nickel ore has attracted extensive attention. Garnierite which belongs to laterite nickel ore has high nickel content, so it can create more value. In order to improve the development and utilization level of garnierite, the pyrometallurgy and hydrometallurgical treatment process and mechanism of garnierite resources are reviewed. It is pointed out that although the traditional pyrometallurgy process is short in process and simple in operation, only Ni and Fe in minerals can be recovered, and Mg can not. Ni, Fe and Mg in minerals can be comprehensively recovered by the vacuum carbothermal reduction process, which can create high economic efficiency. Although the acid method in the hydrometallurgical process can effectively recover Ni and Co in minerals, there are problems such as high cost and environment-unfriendly; while the alkali method can enrich Ni and Fe, and can also produce silica white products (SiO₂), the reagents used in this process can be recycled, those advantages make good development prospects. The related research group of Kunming University of Science and Technology proposed a pyrometallurgy-hydrometallurgical combined treatment process for the problems of pyrometallurgy and hydrometallurgical processes, which can comprehensively recover Mg, Si, Ni, Fe and other elements in garnierite and expect to provide ideas for the comprehensive utilization of garnierite.

Key words: garnierite pyrometallurgy process hydrometallurgical process comprehensive utilization

发布日期: 2020-07-01

ZTFLH:

TF815

基金资助: 国家自然科学基金(51604133);云南省院士自由探索基金(2019HA006)

作者简介: 谷旭鹏,2017年6月毕业于燕山大学,获工学学士学位。现为昆明理工大学有色资源利用国家重点实验室硕士研究生,在曲涛副教授的指导下进行研究。目前主要研究领域为高镁硅红土镍矿的真空冶金;曲涛,昆明理工大学,副教授,硕士研究生导师。2015年毕业于昆明理工大学,获工学博士学位。目前在昆明理工大学冶金与能源工程学院工作,主要研究方向为真空冶金和冶金环保。

引用本文:

曲涛, 谷旭鹏, 施磊, 罗铭洋, 王强, 吕飞, 田源, 戴永年. 高镁硅红土镍矿开发利用研究现状[J]. 材料导报, 2020, 34(Z1): 261-267.
QU Tao, GU Xupeng, SHI Lei, LUO Mingyang, WANG Qiang, LYU Fei, TIAN Yuan, DAI Yongnian. Research Status of Development and Utilization of Garnierite. Materials Reports, 2020, 34(Z1): 261-267.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/261

1 刘岩,翟玉春,王虹.材料导报,2006,20(3),79.
2 赵昌明,翟玉春.材料导报,2009,23(11),73.
3 Ashok D D, Gordon Bacon W, Robert C. In: PDAC 2004 International Convention, Trade Show & Investors Exchange.2004,pp.1.
4 北京有色冶金设计研究总院.重有色金属冶炼设计手册·铜镍卷,冶金工业出版社,1996.
5 刘大星.有色金属(冶炼部分),2002(3),6.
6 李洋洋,李金辉,张云芳,等.材料导报,2015,29(9),79.
7 卢超.促进剂及含铁量对贫镍红土矿煤基还原富集镍的研究.硕士学位论文,昆明理工大学,2017.
8 王成彦,尹飞,陈永强,等.中国有色金属学报,2008,18(Z1),1.
9 郭学益,吴展,李栋.金属材料与冶金工程,2009,37(2),3.
10 陈庆根.湿法冶金,2008,27(1),7.
11 刘志宏,杨慧兰,李启厚,等.有色金属(冶炼部分),2010(2),2.
12 陈士朝,边妙莲,孙辉,等.中国专利,CN108034811A,2017.
13 He A P, Zeng J M. Materials & Design,2017,115,433.
14 何奥平,曾建民.钢铁研究学报,2017,29(1),26.
15 Wang X P, Sun T C, Kou J, et al. International Journal of Minerals Metallurgy and Materials,2018,25(6),591.
16 李小明,白涛涛,赵俊学,等.材料导报,2014,28(5),112.
17 彭犇,岳清瑞,李建军,等.有色金属工程,2011,1(4),15.
18 吴龙忠.江苏冶金,2008,36(6),64.
19 季爱兵,尹鑫平,李欣.现代冶金,2016,44(1),14.
20 何超.褐铁矿直接还原熔分制备珠铁.硕士学位论文,内蒙古科技大学,2014.
21 范兴祥,董海刚,汪云华,等.中南大学学报(自然科学版),2012,43(9),3344.
22 胡长松.中国有色冶金,2014,43(2),74.
23 Shi L, Qu T, Liu D C, et al. In: 8th International Symposium on High-Temperature Metallurgical Processing. San Diego,2017,pp.517.
24 徐冬,刘岩,李杰,等.东北大学学报(自然科学版),2010,31(4),559.
25 Dwipuji Rahayu, Ahmad Maksum, Johny Wahyuadi Soedarsono. In: 2nd international Tropical Renewable Energy Conference.2017,pp.1.
26 高金涛,张颜庭,陈培钰,等.北京科技大学学报,2013,35(10),1289.
27 丁志广,李博,魏永刚.中国有色金属学报,2018,28(8),1669.
28 Li B, Wang H, Wei Y G. Mineral Processing & Extractive Metallurgy,2011,122(4),1556.
29 Liu W R, Li X H, Hu Q Y, et al. Transactions of Nonferrous Metals Society of China,2010,20(s1),s82.
30 Zhou S W, Wei Y G, Li B, et al. Metallurgical & Materials Transactions B,2016,47(1),145.
31 Zhou S W, Wei Y G, Li B, et al. Scientific Reports,2016,6,1.
32 董竞成,卢超,魏永刚.矿冶工程,2017,37(5),68.
33 Li B, Wei Y G, Wang H. Mineral Processing & Extractive Metallurgy,2011,122(4),249.
34 刘志国,孙体昌,蒋曼,等.中南大学学报(自然科学版),2015(10),3566.
35 林重春,张建良,黄冬华,等.北京科技大学学报,2011,33(3),270.
36 梁威,王晖,符剑刚,等.中南大学学报(自然科学版),2011,42(8),2173.
37 Luo J, Li G H, Peng Z W, et al. JOM,2016,68(12),3015.
38 Wang Z H, Chu M S, Liu Z G, et al. Metals,2017,7(8),1.
39 Chen Y Q, Zhao H L, Wang C Y. International Journal of Minerals Metallurgy and Materials,2017,24(5),512.
40 Ma B Z, Xing P, Yang W J, et al. Metallurgical & Materials Transactions B,2017,48(4),2037.
41 薛正良,肖承鹏,杭桂华,等.重庆大学学报,2017,40(12),43.
42 戴永年,杨斌.有色金属真空冶金.冶金工业出版社,2009.
43 徐宝强,裴红彬,杨斌,等.真空科学与技术学报,2011,31(3),341.
44 Qu T, Tian Y, Yang B, et al. Magnesium Technology,2012,505.
45 田阳,曲涛,杨斌,等.真空科学与技术学报,2012,32(9),814.
46 罗启,曲涛,刘大春,等.真空科学与技术学报,2012,32(11),1026.
47 罗启,曲涛,刘大春,等.中南大学学报(自然科学版),2012,43(11),4190.
48 罗启.低品位红土镍矿真空碳热还原机理及实验研究.硕士学位论文,昆明理工大学,2012.
49 罗启,曲涛,刘大春,等.真空科学与技术学报,2012,32(5),430.
50 曲涛.高镁硅红土镍矿真空碳热还原—磁选工艺研究.博士学位论文,昆明理工大学,2015.
51 杨永强,王成彦,汤集刚,等.有色金属工程,2008,60(3),84.
52 Whittington B I, Muir D. Mineral Processing and Extractive Metallurgy Review,2000,21(6),527.
53 杨玮娇,马保中.矿冶,2011,20(3),61.
54 伍博克.云南元江红土镍矿加压酸浸研究.硕士学位论文,中南大学,2010.
55 伍博克,刘葵,陈启元,等.云南冶金,2010,39(4),29.
56 Mcdonald R G, Whittington B I. Hydrometallurgy,2008,91(1),35.
57 Rice M N. Minerals Engineering,2016,88,28.
58 Mcdonald R G, Whittington B I. Hydrometallurgy,2008,91(1),56.
59 Behera S K, Mulaba-Bafubiandi A F. Korean Journal of Chemical Engineering,2015,32(8),1447.
60 Agatzini-Leonardou S, Zafiratos I G. Hydrometallurgy,2004,74(3-4),267.
61 Agacayak T, Zedef V. In: MinePlanning and Equipment Selection, Proceedings of the 22nd MPES Conference. Dresden,2013,pp.1039.
62 张培育.红土镍矿酸浸-水解耦合新工艺选择性浸出镍钴应用基础研究.博士学位论文,中国科学院过程工程研究所,2016.
63 Li J H, Li D S, Xu Z F, et al. Journal of Cleaner Production,2018,179,24.
64 Valix M, Tang J Y, Cheung W H. Minerals Engineering,2001,14(12),1629.
65 刘学,温建康,阮仁满.稀有金属,2006,30(4),490.
66 刘岩,张霞,李在元,等.金属矿山,2008(9),54.
67 翟玉春,牟文宁,刘岩,等.中国工程院化工、冶金与材料工学部学术会议.2009,pp.906.
68 牟文宁,翟玉春,刘岩.中国有色金属学报,2009,19(3),570.
69 张霞.以红土镍矿为原料制备纳米二氧化硅.硕士学位论文,东北大学,2009.
70 刘岩,张霞,申晓毅,等.化工学报,2008,59(10),2687.
71 Mu W N, Lu X Y, Cui F H, et al. Transactions of Nonferrous Metals Society of China,2018,28(1),169.
72 曲涛,谷旭鹏,王强,等.中国专利,CN109652646A,2019.

[1]	刘文博, 姚华彦, 王静峰, 陈传明, 刘玉亭. 铁尾矿资源化综合利用现状[J]. 材料导报, 2020, 34(Z1): 268-270.
[2]	贾敏, 杨磊. 粉煤灰盐酸法提铝后残渣的综合利用研究[J]. 材料导报, 2020, 34(Z1): 277-279.
[3]	胡贵生, 章超, 钱晨阳, 文建新. 钼尾矿资源综合利用最新研究进展概述[J]. 材料导报, 2019, 33(Z2): 233-238.
[4]	贺东风, 潘江涛, 曾凡博. 中钛型含钛高炉渣制微晶玻璃及其性能研究^*[J]. 《材料导报》期刊社, 2017, 31(2): 126-129.

[1]	Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[3]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[4]	Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[5]	Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[6]	Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[7]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[8]	Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[9]	Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[10]	Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .

Viewed

Full text

Abstract

Cited

Shared

Discussed