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材料导报  2020, Vol. 34 Issue (17): 17139-17148    https://doi.org/10.11896/cldb.19090232
  无机非金属及其复合材料 |
二次可充放电电池用硒化锡负极材料的研究现状
程娅伊1,2, 黄剑锋2, 李嘉胤2, 谢辉1, 周影影1
1 西安航空学院材料工程学院, 西安 710077
2 陕西科技大学无机材料绿色制备与功能化重点实验室, 西安 710021
Recent Progress of Secondary Rechargeable/discharged Battery Tin Selenide Anode Materials
CHENG Yayi1,2, HUANG Jianfeng2, LI Jiayin2, XIE Hui1, ZHOU Yingying1
1 School of Materials Science & Engineering, Xi'an Aeronautical University, Xi'an 710077, China
2 Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China
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摘要 硒化锡(SnSe、SnSe2)因其特殊的层状晶体结构以及较高的导电性,有望成为锂/钠离子电池的负极材料。但是硒化锡负极在充放电过程中体积会反复变化,导致电极结构及表面SEI膜(电极与电解液界面)遭到破坏,使活性材料失去电接触,从而导致循环容量迅速衰减;此外,硒化锡转化反应中间产物Li2Se/Na2Se的导电性较差,阻碍了电荷的传输,从而影响了硒化锡电极的电化学反应活性。
   本文针对硒化锡电极在储锂/钠过程中存在的问题,总结了提升其电化学性能的手段,并概述了国内外学者从构建特殊纳米结构和复合结构等层面上采取的解决办法,揭示了其电化学存储机制以及能够获得的电化学性能。
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程娅伊
黄剑锋
李嘉胤
谢辉
周影影
关键词:  硒化锡  负极材料  电化学性能  电池    
Abstract: Tin selenide (SnSe, SnSe2) is considered to be a kind of potential lithium/sodium ion battery anode materials due to its special layered crystal structure and high electrical conductivity. However, tin selenide materials still exist several issues during lithium/sodium ions storage process. On the one hand, the huge volumetric change of tin selenide anode can result in the destruction of electrode structure and SEI film (solid-electrolyte interface film). This cracked structure without good electric contact will lead to rapid decay of the cycling performance. On the other hand, the electrical conductivity of intermediate products Li2Se/Na2Se is poor, hindering the charge transfer and lowering the electrochemical reaction kinetics of tin selenide electrode.
Based on the issues in lithium/sodium ions storage process, we summarize several strategies that have been used to enhance the electrochemical property of tin selenide, and review the domestic and foreign scholars from build special nano structure and composite structure level to reveal the electrochemical storage mechanism as well as the improved electrochemical performance.
Key words:  tin selenide    anode materials    electrochemical performance    battery
               出版日期:  2020-09-10      发布日期:  2020-09-02
ZTFLH:  TQ152  
基金资助: 陕西省自然科学基础研究计划(2019JQ-911);陕西省教育厅科研计划项目资助(19JK0428);国家自然科学基金(51672165; 51702198)
通讯作者:  chengyayisust@126.com   
作者简介:  程娅伊,2018年6月毕业于陕西科技大学,获得工学博士学位。现为西安航空学院专任教师。目前主要研究领域为锡基纳米储能材料。近年来,以第一作者在二次电池储能领域发表SCI收录论文10余篇,包括Small、Nanoscale、ACS Sustainable Chemistry & Engineering、Journal of Power Sources等国际权威期刊,授权国家发明专利11项。
引用本文:    
程娅伊, 黄剑锋, 李嘉胤, 谢辉, 周影影. 二次可充放电电池用硒化锡负极材料的研究现状[J]. 材料导报, 2020, 34(17): 17139-17148.
CHENG Yayi, HUANG Jianfeng, LI Jiayin, XIE Hui, ZHOU Yingying. Recent Progress of Secondary Rechargeable/discharged Battery Tin Selenide Anode Materials. Materials Reports, 2020, 34(17): 17139-17148.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19090232  或          http://www.mater-rep.com/CN/Y2020/V34/I17/17139
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