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材料导报  2019, Vol. 33 Issue (Z2): 92-96    
  无机非金属及其复合材料 |
富锌载银可溶玻璃抗菌材料的性能
王晓燕, 王继梅, 侯国艳
中国建筑材料科学研究总院有限公司,北京 100024
Properties of Ag-doped Zinc-rich Soluble Glass Antimicrobial Material
WANG Xiaoyan, WANG Jimei, HOU Guoyan
China Building Materials Academy, Beijing 100024
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摘要 本工作以银为抗菌有效成分,在玻璃原料中添加高比例氧化锌,以高温熔融的方法制备得到一种新型富锌载银可溶玻璃抗菌材料。运用扫描电镜(SEM)、能谱(EDS)和X射线衍射(XRD)测试,结果发现,材料为非晶态物质,由B、O、Na、Si、Ca、Zn和Ag元素组成。利用原子吸收光谱(AAS)法研究了材料释放Ag+的性质,并以大肠杆菌和金黄色葡萄球菌作为代表菌株研究其抗菌效果。实验发现:材料Ag+溶出量随时间延长而增加,但随着溶液中溶解的Ag+浓度增加,溶解速率减慢;Ag+溶出量也受材料用量的影响,材料用量越少,Ag+溶出越充分,该抗菌材料体现出良好的稳定缓释Ag+的性能。抗菌实验结果显示,抗菌材料周围的细菌生长受到明显抑制而形成透明抑菌圈。以红外光谱(IR)方法研究了材料的基团结构,氧化锌形成了Zn-O-B及Zn-O-Si键,以[ZnO4]四面体形式参与了玻璃网络架构。
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王晓燕
王继梅
侯国艳
关键词:  玻璃载银抗菌材料  琼脂扩散  Ag+溶出  红外光谱  结构基团    
Abstract: In the present study, Ag-doped glass antimicrobial material containing a high proportion of zinc oxide was developed by high temperature melting method, in which the silver as antimicrobial active ingredient. By means of scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD), the material is amorphous, consisting of B, O, Na, Si, Ca, Zn and Ag elements. The dissolubility of Ag+ was investigated by atomic absorption spectrometry (AAS).It was found that the amount of Ag+ released was increased with time, but the release rate decreased while Ag+ concentration in solution increased. Moreover, it is also affected by the amount of material, the less the material used, the higher the proportion of Ag+ dissolution. The antimicrobial material shows a good performance of stable and slow release of Ag+. Escherichia coli and Staphylococcus aureus were used to value the antimicrobial activities. The results showed that the growth of bacteria around the antimicrobial material was obviously inhibited and transparent bacteriostasis circles were formed. The results of IR absorption spectra showed that ZnO participated in the glass network structure in the form of [ZnO4] tetrahedron and formed Zn-O-B and Zn-O-Si bonds.
Key words:  Ag-doped glass antimicrobial material    agar diffusion    silver ions release    IR absorption spectra    structure group
               出版日期:  2019-11-25      发布日期:  2019-11-25
ZTFLH:  TB332  
基金资助: 国家重点研发计划(2016YFC0700906-2)
通讯作者:  wangxiaoyan@cbmamail.com.cn   
作者简介:  王晓燕,中国建筑材料科学研究总院,高级工程师。2006年6月毕业于中国建筑材料科学研究总院,材料学专业硕士学位,同年留院工作至今,主要从事环境健康建材方面的研究,包括空气净化、抗菌防霉等方向。
引用本文:    
王晓燕, 王继梅, 侯国艳. 富锌载银可溶玻璃抗菌材料的性能[J]. 材料导报, 2019, 33(Z2): 92-96.
WANG Xiaoyan, WANG Jimei, HOU Guoyan. Properties of Ag-doped Zinc-rich Soluble Glass Antimicrobial Material. Materials Reports, 2019, 33(Z2): 92-96.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2019/V33/IZ2/92
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