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材料导报  2018, Vol. 32 Issue (6): 947-950    https://doi.org/10.11896/j.issn.1005-023X.2018.06.017
  材料研究 |
锌含量对铝基可降解合金降解速率的影响
郭思文, 邵媛, 古正富, 任国富, 张华光
长庆油田分公司油气工艺研究院,西安 710018
Influence of Zn Content on the Degradation Rates of Degradable Aluminum Alloys
GUO Siwen, SHAO Yuan, GU Zhengfu, REN Guofu, ZHANG Huaguang
Oil and Gas Technology Institute of Changqing Oilfield Company, Xi’an 710018
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摘要 以Al-Mg-Ga-In-Sn合金为基体,采用熔融工艺制备了不同Zn含量的可降解铝合金材料。通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)和电化学工作站分析了Zn含量对可降解铝合金相组成、显微结构和电化学参数的影响规律。降解速率的测定在90 ℃恒温的蒸馏水中进行。结果表明:合金析出相的组成、数量和形貌是影响合金降解速率改变的重要因素。随着Zn元素的加入,主要析出相由短棒状的Mg2Sn转变为树枝状或网络状的Mg32(AlZn)49,而合金的降解总是沿着细小的球状富Mg、In析出相开始并围绕其向周围扩展。然而大量的Mg被Mg32(AlZn)49相结合,使得腐蚀区域明显减少,降解速率降低,因此,Mg32(AlZn)49起到延缓合金降解的作用。此外,随着Zn含量的增加,合金的腐蚀电位均不同程度地正移,腐蚀电流逐渐减小,使得合金的腐蚀倾向减弱,降解速率降低。
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郭思文
邵媛
古正富
任国富
张华光
关键词:  锌含量  相组成  微观结构  极化曲线  降解速率    
Abstract: The degradable aluminum alloys of different Zn content were prepared by melting technique based on the Al-Mg-Ga-In-Sn alloy. The effect of different Zn content on phase compositions, microstructure and electrochemical parameters of the degradable aluminum alloys were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM) and electrochemical workstation. In addition, the degradation rates were conducted in distilled water at 90 ℃. Experimental results showed that the composition, amount and morphology of the precipitates in alloys played an important role in changing the degradation rates. As the increa-sing Zn content, the main precipitation was changed to the dendritic or the network Mg32(AlZn)49 from the clavate Mg2Sn. The degradation of alloys always started along the globular phase which was rich in Mg-In, and spread around it. Obviously, a large amount of Mg was combined into the Mg32(AlZn)49 precipitation, which made both the corrosion proportion and the degradation rate decrease. Therefore, the Mg32(AlZn)49 can delay the degradation of alloys. Moreover, the Ecorr of alloys was shifted to positive values in varying degrees and the icorr decreased gradually. For this reason, the corrosion trend of alloys weakened and the degradation rate decreased in the end.
Key words:  Zn content    phase compositions    microstructure    polarization curves    degradation rates
               出版日期:  2018-03-25      发布日期:  2018-03-25
ZTFLH:  TU512.4  
基金资助: 低渗透油气田勘探开发国家工程实验室开放课题(16GJ-KF-002)
作者简介:  郭思文:男,1980年生,工程师,从事油气增产技术研究 E-mail:gswen_cq@petrochina.com.cn
引用本文:    
郭思文, 邵媛, 古正富, 任国富, 张华光. 锌含量对铝基可降解合金降解速率的影响[J]. 材料导报, 2018, 32(6): 947-950.
GUO Siwen, SHAO Yuan, GU Zhengfu, REN Guofu, ZHANG Huaguang. Influence of Zn Content on the Degradation Rates of Degradable Aluminum Alloys. Materials Reports, 2018, 32(6): 947-950.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.06.017  或          http://www.mater-rep.com/CN/Y2018/V32/I6/947
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