Preparation of Sn Doped In2O3 Materials Derived from MOFs and Their Gas-sensing Properties for Chlorine
MA Jiangwei1,2,*, ZHAI Haichao1,2, ZHANG Ziwei1,2, HU Jifan1,2,*
1 School of Materials Science & Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China 2 Shanxi Province Key Laboratory of Magnetic and Electric Functional Materials and Their Applications, Taiyuan University of Science and Technology, Taiyuan 030024, China
Abstract: Sn-doped indium oxide hollow micron-rods (Sn-In2O3 HMs) were prepared by calcination of Sn-doped organic framework compounds (MOFs) which prepared by a simple hydrothermal method. From the results of characterization, the morphology of Sn-In2O3 was hollow micron-rod and the specific surface area was large. In addition, Sn element was successfully doped and Sn-In2O3 HMs had abundant oxygen vacancy. The investigation on the gas-sensing performance revealed that the Sn-In2O3 HMs sensors could detect low concentration of chlorine (Cl2) and displayed a low detection limit (0.37×10-9). According to the analysis of gas-sensing mechanism, the excellent Cl2 sensing properties were ascribed to the hollow structure, large specific surface area and abundant oxygen vacancy. Those mainly derived from the preparation of MOFs template method and the doping of Sn element.
通讯作者: *马江微,太原科技大学材料科学与工程学院讲师、硕士研究生导师。2012年唐山师范学院化学本科毕业,2015年空军军医大学药物化学专业硕士毕业,2020年西北工业大学材料学专业博士毕业。目前主要从事气敏材料及器件等方面的研究工作。以第一作者发表论文7篇,包括Sensors and Actuators B:Chemical、ACS Sustainable Chemistry & Engineering、Journal of Hazardous Materials、Ceramics International等。jiangweima@tyust.edu.cn 胡季帆,太原科技大学材料科学与工程学院特聘教授、长江学者、博士研究生导师。1985 年山东大学物理学专业本科毕业,1988 年中科院物理研究所凝聚态物理专业硕士毕业,1993 年中科院物理研究所凝聚态物理专业博士毕业。目前主要从事气敏、储氢、永磁等稀土功能材料的研究工作。发表论文200余篇,包括Sensors and Actuators B:Chemical、Applied Surface Science、Renewable Energy、Journal of Rare Earths等。曾获教育部科技进步一等奖。2019064@tyust.edu.cn
引用本文:
马江微, 翟海潮, 张紫薇, 胡季帆. MOFs衍生的Sn掺杂In2O3材料的制备及氯气气敏性能[J]. 材料导报, 2023, 37(16): 23040030-6.
MA Jiangwei, ZHAI Haichao, ZHANG Ziwei, HU Jifan. Preparation of Sn Doped In2O3 Materials Derived from MOFs and Their Gas-sensing Properties for Chlorine. Materials Reports, 2023, 37(16): 23040030-6.
1 Li P, Fan H. Materials Science in Semiconductor Processing, 2015, 29, 83. 2 Wang D, Hu P, Xu J, et al. Sensors and Actuators B: Chemical, 2009,140(2), 383. 3 Patil D R, Patil L A. Sensors & Actuators B Chemical, 2007,123(1), 546. 4 Bender F, Kim C, Mlsna T, et al. Sensors and Actuators B: Chemical, 2001,77(1), 281. 5 Zhang Y, Song W, Zhang S, et al. Materials Reports, 2022, 36(23), 21010015 (in Chinese). 张亦文, 宋晚晴, 张士雨, 等. 材料导报, 2022, 36(23), 21010015. 6 Ma J, Fan H, Tian H, et al. Sensors and Actuators B: Chemical, 2018,262, 17. 7 Li P, Cai Y, Fan H. RSC Advances, 2013, 3(44), 22239. 8 Wang L, Lou Z, Fei T, et al. Journal of Materials Chemistry, 2011, 21(48), 19331. 9 Zhao J, Shao Q, Ge S, et al. The Chemical Record, 2020, 20(7), 710. 10 Sun J K, Xu Q. Energy & Environmental Science, 2014, 7(7), 2071. 11 Liu W, Chen X, Zhi W, et al. Materials Reports, 2023, 37(5), 21030231 (in Chinese). 刘维赛, 陈晓怡, 智文科,等. 材料导报, 2023, 37(5), 21030231. 12 Wang M, Shen Z, Zhao X, et al. Journal of Hazardous Materials, 2019, 371, 352. 13 Jin Z, Wang C, Wu L, et al. Sensors and Actuators B: Chemical, 2023, 377, 133058. 14 Li P, Fan H, Cai Y, et al. CrystEngComm, 2014, 16(13), 2715. 15 Liang R, Huang R, Wang X, et al. Applied Surface Science, 2019, 464, 396. 16 Seo W S, Jo H H, Lee K, et al. Advanced Materials, 2003, 15(10), 795. 17 Pan D, Ge S, Zhang X, et al. Dalton Transactions, 2018, 47(3), 708. 18 Liu Y, Liu J, Pan Q, et al. Sensors and Actuators B: Chemical, 2022, 352(1), 131001. 19 Liu F, Huang G, Wang X, et al. Sensors and Actuators B: Chemical, 2018, 277, 144. 20 Xun H, Zhang Z, Yu A, et al. Sensors and Actuators B: Chemical, 2018, 273, 983. 21 Ma J, Fan H, Zheng X, et al. Journal of Hazardous Materials, 2020, 387, 122017. 22 Tu N, Van Bui H, Trung D Q, et al. Journal of Alloys and Compounds, 2019, 791, 722. 23 Ri J, Li X, Shao C, et al. Sensors and Actuators B: Chemical, 2020, 317, 128194. 24 Kundu S, Kumar A. Journal of Alloys and Compounds, 2019, 780, 245. 25 Zhou J Y, Bai J L, Zhao H, et al. Sensors and Actuators B: Chemical, 2018, 265, 273. 26 Sing K S W. Pure and Applied Chemistry, 1985, 57(4), 603. 27 Scott R W J, Yang S M, Chabanis G, et al. Advanced Materials, 2001, 13(19), 1468. 28 Spjotvoll E, Martens H, Naes T. Applied Statistics, 1991, 40, 341. 29 Peng L, Zhao Q, Wang D, et al. Sensors and Actuators B: Chemical, 2009, 136(1), 80. 30 Kumar R, Al-Dossary O, Kumar G, et al. Nano-Micro Letters, 2015, 7(2), 97. 31 Miyata T, Hikosaka T, Minami T. Sensors and Actuators B: Chemical, 2000, 69(1), 16. 32 Tamaki J, Naruo C, Yamamoto Y, et al. Sensors and Actuators B: Chemical, 2002, 83(1), 190. 33 Chaparadza A, Rananavare S B. Nanotechnology, 2008, 19(24), 245501. 34 Van Dang T, Duc Hoa N, Van Duy N, et al. ACS Applied Materials & Interfaces, 2016, 8(7), 4828. 35 Wang D, Hu P, Xu J, et al. Sensors and Actuators B: Chemical, 2009, 140(2), 383.
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2023, Vol. 37 
