铁电材料表面电畴结构的压电力显微镜表征研究进展

doi:10.11896/cldb.21120259

材料导报

2022, Vol. 36

Issue (7): 21120259-21 https://doi.org/10.11896/cldb.21120259

表面工程材料与技术

铁电材料表面电畴结构的压电力显微镜表征研究进展

何东昱¹, 马国政¹, 邢志国¹, 王海斗^1,2

1 陆军装甲兵学院装备再制造技术国防科技重点实验室,北京 100072
2 陆军装甲兵学院机械产品再制造国家工程研究中心,北京 100072

Research Progress of Piezoelectric Force Microscope on Surface Domain Structure of Ferroelectrics

HE Dongyu¹, MA Guozheng¹, XING Zhiguo¹, WANG Haidou^1,2

1 National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072, China
2 National Engineering Research Center for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072, China

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摘要铁电材料是一类应用广泛的功能材料,常用于电子、光学和精密机电等领域,未来有望用于高密度非易失性存储器和多功能纳米器件中。铁电材料的应用源于其具有自发极化电畴且可通过施加电场实现内部电畴的转向,因此对铁电畴及其极化翻转的理解和认知对于实际器件的设计与应用至关重要。压电力显微镜(PFM)方法是一种表面检测技术,基于极化和机电行为之间的强耦合作用,可直接反映铁电材料电畴结构的微观特征,用于探测纳米级压电和铁电特性。本文总结了使用压电力显微镜研究铁电材料表面电畴的最新成果与进展。首先,简要介绍了PFM技术的成像机制和分析方法;随后,展示了PFM技术在铁电畴结构以及电畴局部动力学中的相关研究,包括铁电体表面电畴结构的表征与识别、电畴的热稳定性、铁电表面屏蔽、电畴的形核、畴壁运动、电畴弛豫、电畴中缺陷的作用等;最后,指出了PFM研究铁电材料的发展趋势,包括铁电存储的应用与规律研究、新型铁电材料的优化设计、将PFM与其他技术结合对铁电体的深入探究和PFM技术的精细化发展对探索纳米压电和铁电的影响等方面。

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	何东昱
	马国政
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	王海斗

关键词: 铁电材料电畴铁电表面电畴翻转压电力显微镜

Abstract: Ferroelectrics are widely used in electronics, optics, precision electromechanical and other fields,which are also expected to be used in high-density nonvolatile memory and multifunctional nano devices in the future. The application of ferroelectrics origins from the domain and domain switching with applying of an electric field. Therefore, the understanding of ferroelectric domain polarization is very important for the design and application of ferroelectric devices.Piezoelectric force microscopy (PFM) method is a surface detection technique based on the strong coupling between polarization and electromechanical behavior, which can reflect the micro characteristics of the domain structure directly, and is used to probe nanoscale piezoelectric and ferroelectric characteristic.In this review, the latest achievements and progress in the study on ferroelectric domains by using PFM are summarized. Firstly, the mechanism and analysis methods of PFM technology are briefly introduced, and then the description of PFM technology in a wide range of ferroelectric domains and their dynamic process are shown,including ferroelectric surface domain structure characterization and identification, domain thermal stability, ferroelectric surface screening, domain nucleation, domain wall motion, domain relaxation, the role of domain defects.Finally, the development trend of PFM research on ferroelectric materials is pointed out, including the application and the regular study of PFM in ferroelectric storage, the optimal design of new ferroelectric materials, the in-depth characterization of ferroelectrics combined with other technologies, and the impact of the fine development of PFM technology on the exploration of nano piezoelectric and ferroelectric.

Key words: ferroelectrics domain ferroelectric surface domain switching piezoresponse force microscopy

发布日期: 2022-04-07

ZTFLH:

O487

基金资助: 国家自然科学基金(51805539;52130509;52075543);清华大学摩擦学国家重点实验室开放基金(SKLTKF19B07);国防基础科研计划(JCKY2019Z03)

通讯作者: xingzg2011@163.com; whaidou2021@163.com

作者简介: 何东昱,陆军装甲兵学院装备保障与再制造系副研究员。2007年6月本科毕业于北京科技大学材料科学与工程专业,2012年6月获北京科技大学工学博士学位。研究方向是再制造与纳米铁电表面工程,发表SCI学术论文10余篇,包括Physics review B、Applied physics letters、Journal of the American Ceramic Society、Journal of Alloys and Compounds、Acta Metallurgica Sinica等。
邢志国,博士,陆军装甲兵学院装备保障与再制造系助理研究员,研究方向为表面摩擦学。
王海斗,研究员,博士研究生导师,陆军装甲兵学院机械产品再制造国家工程研究中心主任。2003年毕业于清华大学并获得博士学位。国家杰出青年科学基金获得者,国家“万人计划”科技领军人才,国家中青年科技领军人才、国家百千万工程人才、国家有突出贡献中青年专家、北京市科技领军人才、国防973计划首席科学家。目前的研究领域包括表面工程、再制造工程、先进制造等。

引用本文:

何东昱, 马国政, 邢志国, 王海斗. 铁电材料表面电畴结构的压电力显微镜表征研究进展[J]. 材料导报, 2022, 36(7): 21120259-21.
HE Dongyu, MA Guozheng, XING Zhiguo, WANG Haidou. Research Progress of Piezoelectric Force Microscope on Surface Domain Structure of Ferroelectrics. Materials Reports, 2022, 36(7): 21120259-21.

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http://www.mater-rep.com/CN/10.11896/cldb.21120259 或 http://www.mater-rep.com/CN/Y2022/V36/I7/21120259

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