The State of the Art of Hydrogen Storage Materials for High-pressure Hybrid Hydrogen Vessel
ZHOU Chao1, WANG Hui1,2, OUYANG Liuzhang1,2, ZHU Min1,2
1 Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 2 China-Australia Joint Laboratory for Energy & Environmental Materials, South China University of Technology, Guangzhou 510641
Abstract: Hydrogen energy is one of the most important choices for realizing clean energy because of its wide sources, no pollution, and high energy density. The technological innovation of fuel cells contributes to the attractive prospect of hydrogen energy in vehicles, but the problem of hydrogen filling and hydrogen storage has become one of the obstacles to the development of hydrogen energy cars. The safe and efficient hydrogen storage is crucial for the large-scale application of hydrogen energy. Till now there have been developed three main hydrogen storage methods, which include high-pressure gaseous hydrogen storage, low-temperature liquid hydrogen storage and solid-state hydrogen storage. The gravimetric density of gaseous hydrogen storage system can be promoted by increasing the pressure of hydrogen and the specific strength of container material. However, H2 molecular interaction causes a relatively low volumetric density of gaseous hydrogen storage system, and excessively high hydrogen pressure challenges the safety and heightens design difficulty and cost of hydrogen tanks. The liquid hydrogen storage owns ideal gravimetric and volumetric density, which can be realized by compres-sing and liquefying hydrogen gas. However, liquid hydrogen is particularly prone to volatilize and liquid hydrogen container requires strict storing conditions. In addition, the liquefying process of gaseous hydrogen is uneconomical, as it consumes an energy quantity that constitutes about 40% of the combustion heat release of the stored hydrogen. For the solid-state hydrogen storage, hydrogen is stored in the hydrides in the form of atom or ion. Hence, the solid-state hydrogen storage obtains an impressively high volumetric density and enjoys greater security because the hydrogen storage materials absorb/desorb hydrogen at mild conditions. But the gravimetric density of hydrogen storage materials is comparatively low. The high-pressure hybrid hydrogen storage vessel, which combines the advantages of gaseous and solid-state hydrogen storage methods, offers a feasible path to safe and high-density hydrogen storage. The volumetric density of high-pressure hydrogen tank can be effectively enhanced by the hydrogen storage materials, resulting in lower operating pressure, smaller volume, and higher safety. The performance promotion of the high-pressure hybrid hydrogen storage vessels depends upon the development of materials with excellent hydrogen sorption performances under high hydrogen pressure. The AB2 type ZrFe2-based and TiCr2 based alloys are the currently prevailing high-pressure hydrogen storage materials. Though researchers mainly concentrate on and have achieved the regulation of storage capacity, absorption/desorption pressure plateau and kinetics through the alloying trials which partially substitute elements with various atomic radius and electronic structures for either A-site or B-site, the gravimetric densities of ZrFe2-based and TiCr2-based alloys are still unsatisfactory. NaAlH4 and AlH3 display considerable potential as candidate storage materials owing to their intrinsically high storage density. For NaAlH4, sufficient works have preliminarily confirmed the effectiveness of nanosizing and catalyst-doping toward dehydrogenation temperature reduction and cyclic stability enhancement. And the yield of AlH3 along with its crystallinity can likely be enhanced by adopting ball milling or improving the solvent. This review starts with a brief introduction of how the high-pressure hybrid hydrogen storage vessel works and a summary of the performance requirements of the hydrogen storage materials. It then provides detailed discussion and description upon the structure, characteristics and research status quo with respect to the above-mentioned two species of high-pressure hydrogen storage materials, i.e.hydrogen storage alloys (ZrFe2, TiCr2) and aluminum based complex hydrides (NaAlH4, AlH3).
周超, 王辉, 欧阳柳章, 朱敏. 高压复合储氢罐用储氢材料的研究进展[J]. 材料导报, 2019, 33(1): 117-126.
ZHOU Chao, WANG Hui, OUYANG Liuzhang, ZHU Min. The State of the Art of Hydrogen Storage Materials for High-pressure Hybrid Hydrogen Vessel. Materials Reports, 2019, 33(1): 117-126.
Zhu M. Introduction to Advanced Hydrogen Storage Materials, Science Press, China,2015(in Chinese).朱敏.先进储氢材料导论,科学出版社,2015.2 http:∥www.toyota-global.com/innovation/environmental_technology/fuelcell_vehicle/3 Wolf J. MRS Bulletin,2002,27(9),684.4 Arnold G, Wolf J. Teion Kogaku,2005,40(6),221.5 Jiang Z, Pan Q, Xu J, et al. International Journal of Hydrogen Energy,2012,39(30),17442.6 Li X G. Hydrogen and Hydrogen Energy, China Machine Press, China,2012(in Chinese).李星国.氢与氢能,机械工业出版社,2012.7 Rusman N A, Dahari M. International Journal of Hydrogen Energy,2016,41(28),12108.8 https:∥www.energy.gov/node/13151869 Luxenburger B, Müller W. International Journal of Hydrogen Energy,1985,10(5),305.10 Takeichi N, Senoh H, Yokota T, et al. International Journal of Hydrogen Energy,2003,28(10),1121.11 Mori D, Haraikawa N, et al. MRS Proceedings,2005,884,72.12 Lee H H, Kim H K, Hwang K H. U.S. patent, US20090155648,2009.13 Kojima Y, Kawai Y, Towata S I, et al. Journal of Alloys and Compounds,2006,419(1-2),256.14 Wang L. Micromechanics-based failure theory for strength and life investigation of carbon fiber-reinforced composite hydrogen storage vessel. Ph.D. Thesis, Zhejiang University, China,2016(in Chinese).王亮.基于微观力学分析的复合材料储氢容器强度与寿命研究.博士学位论文,浙江大学,2016.15 Mori D, Kobayashi N, Shinozawa T, et al. Journal of the Japan Institute of Metals,2005,69(3),308.16 Cao Z, Ouyang L, Hui W, et al. International Journal of Hydrogen Energy,2015,40(6),2717.17 Cao Z, Ouyang L, Wang H, et al. International Journal of Hydrogen Energy,2016,41(26),11242.18 Cao Z, et al. Journal of Alloys and Compounds,2015,639,452.19 Li S Q, Chen C P, Wang X H, et al. In: Conference Record of the International Hydrogen Energy Conference. Beijng,2006,pp.29.20 Yasuai O. Properties and Applications of Mental Hydrides, Chemical Industry Press, China,1990(in Chinese).大角泰章.金属氢化物的性质与应用,化学工业出版社,1990.21 Guo X M, Wang S M, Liu X P, et al. Metal Functional Materials,2011,18(4),10(in Chinese).郭秀梅,王树茂,刘晓鹏,等.金属功能材料,2011,18(4),10.22 Zotov T, Movlaev E, Mitrokhin S, et al. Journal of Alloys and Compounds,2008,459(1-2),220.23 Ropka J, erny＇ R, Paul-Boncour V. Journal of Solid State Chemistry,2011,184(9),2516.24 Shaltiel D, Jacob I, Davidov D. Journal of The Less-Common Metals,1977,53(1),117.25 Filipek S M, et al. Polish Journal of Chemistry,2001,33(9),1921.26 Zotov T A, et al. Journal of Alloys and Compounds,2011,509(5),S839.27 Mitrokhin S, Zotov T, Movlaev E, et al. Journal of Alloys and Compounds,2013,580(24),S90.28 Jain A, Jain R K, Agarwal S, et al. Journal of Alloys and Compounds,2008,454(1-2),31.29 Koultoukis E D, Makridis S S, Pavlidou E, et al. International Journal of Hydrogen Energy,2014,39(36),21380.30 Sivov R B, et al. Journal of Alloys and Compounds,2011,509(5),S763.31 Sivov R B, Zotov TA, Verbetsky V N. Interaction of Hydrogen Isotopes with Structural Materials (IHISM-08 Junior), Sarov,2009,201.32 Banerjee S, Kumar A, Pillai C G S. Intermetallics,2014,51(51),30.33 Li H. Study on hydrogen storage alloys applied in high-pressure hydrogen storage vessel and metal hydride compressor. Master’s Thesis, Zhejiang University, China,2010(in Chinese).李慧.用于氢化物复合储氢器和高压氢化物压缩器的储氢合金研究.硕士学位论文,浙江大学,2010.34 Jacob I, Bereznitsky M. Journal of Alloys and Compounds,2002,336(1-2),L1.35 Davidson D J, Srivastava O N. International Journal of Hydrogen Energy,2001,26(3),219.36 Li Z, Wang H, et al. Journal of Alloys and Compounds,2017,704,491.37 Sivov R B, Zotov T A, Verbetsky V N. International Journal of Hydrogen Energy,2011,36(1),1355.38 Li S L, Cheng H H, Deng X X, et al. Journal of Alloys and Compounds,2008,460(1-2),186.39 Hu Z L. Hydrogen Storage Materials, Chemical Industry Press, China,2002(in Chinese).胡子龙.贮氢材料,化学工业出版社,2002.40 Zhang Q A, Lei Y Q, Yang X G, et al. Journal of Alloys and Compounds,1999,292(1-2),236.41 Tu Y L. Research on modification of Zr-Fe based high pressure hydrogen storage alloys. Master’s Thesis, General Research Institute for Nonferrous Metals,2014(in Chinese).涂有龙.高坪台压Zr-Fe系储氢合金改性研究.硕士学位论文,北京有色金属研究总院,2014.42 Tang R Z, Tian R Z. Binary Alloy Phase Diagrams and Crystal Structure of Intermediate Phase, Central South University Press, China,2009(in Chinese).唐仁政,田荣璋.二元合金相图及中间相晶体结构,中南大学出版社,2009.43 Huang T Z. Research on hydrogen storage characteristics and phase composition of TiCr base alloys. Ph.D. Thesis, Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences,2005(in Chinese).黄太仲.TiCr基合金的储氢性能及相结构研究.博士学位论文,中国科学院上海微系统与信息技术研究所,2005.44 Klyamkin S N, Kovriga A Y, Verbetsky V N. International Journal of Hydrogen Energy,1999,24(2),149.45 Bodega J, Fernández J F, Leardini F, et al. Journal of Physics & Chemistry of Solids,2011,72(11),1334.46 Huang T Z, Wu Z, Xia B, et al. Materials Science and Engineering A,2005,397(1-2),284.47 Beeri O, Cohen D, Gavra Z, et al. Journal of Alloys and Compounds,2003,352(1),111.48 Santos D S D, Bououdina M, Fruchart D. Journal of Alloys and Compounds,2002,340(1-2),101.49 Hagström M T, Klyamkin S N, Lund P D. Journal of Alloys and Compounds,1999,s293-295,67.50 Liu L, Chen L, et al. Journal of Alloys and Compounds,2015,636,117.51 Akiba E, Iba H. Intermetallics,1998,6(6),461.52 Graetz J. Chemical Society Reviews,2009,38(1),73.53 Li L, et al. Journal of Materials Chemistry,2012,22(27),13782.54 Bogdanović B, Schwickardi M. Journal of Alloys and Compounds,1997,253-254,1.55 Bogdanović B, Brand R A, Marjanović A, et al. Journal of Alloys and Compounds,2000,302(1-2),36.56 Ley M B, Meggouh M, Moury R, et al. Materials,2015,8(9),5891.57 Schüth F, Bogdanović B, Felderhoff M. Chemical Communications,2004,(20),2249.58 Anton D L. Journal of Alloys and Compounds,2003,s356-357(16),400.59 Sun T. Improving the hydrogen storage properties of metal complex hydrides by nano-composite and catalysis. Ph.D. Thesis, South China University of Technology,2010(in Chinese).孙泰.用复合和催化方法改善金属配位氢化物的储氢性能.博士学位论文,华南理工大学,2010.60 Sun T, Zhou B, Wang H, et al. International Journal of Hydrogen Energy,2008,33(9),2260.61 Sun J, Xiao X Z, Zheng Z J, et al. Rare Metals,2017,36(2),1.62 Zidan R A, Takara S, Hee A G, et al. Journal of Alloys and Compounds,1999,285(1-2),119.63 Jensen C M, Zidan R, Mariels N, et al. International Journal of Hydrogen Energy,1999,24(5),461.64 Wang P, Kang X D, Cheng H M. Journal of Alloys and Compounds,2006,421(1-2),217.65 Chen P, Zhu M. Materials Today,2008,11(12),36.66 Baldé C P, Hereijgers B P, Bitter J H, et al. Angewandte Chemie International Edition,2006,118(21),3581.67 Li Y, Zhou G, Fang F, et al. Acta Material,2011,59(4),1829.68 Nielsen T K, Manickam K, et al. ACS Nano,2009,3(11),3521.69 Gao J, Adelhelm P, Verkuijlen M H W, et al. The Journal of Physical Chemistry C,2010,114(10),4675.70 Bhakta R K, Herberg J L, Jacobs B, et al. Journal of the American Chemical Society,2009,131(37),13198.71 Nielsen T K, Polanski M, Zasada D, et al. ACS Nano,2011,5(5),4056.72 Kang X D, Wang P, Song X. P, et al. Journal of Alloys and Compounds,2006,424(1-2),365.73 Bogdanovic B, Felderhoff M, Pommerin A, et al. Journal of Alloys and Compounds,2010,471(1),383.74 Graetz J, Reilly J J, Yartys V A, et al. Journal of Alloys and Compounds,2011,509(Suppl.2),S517.75 Ikeda K, Muto S, et al. Nanotechnology,2009,20(20),204004.76 Graetz J, Reilly J, et al. Brookhaven National Laboratory,2006.77 Zhang Y. Synthesis and characterization of AlH3. Master’s Thesis, Southwest University of Science and Technology,China,2013(in Chinese).张永岗.氢化铝的制备与表征.硕士学位论文,西南科技大学,2013.78 Sabrina S, Susanne M O, Ole Martin L, et al. Journal of Materials Che-mistry,2008,18(20),2361.79 Sandrock G, Reilly J, Graetz J, et al. Journal of Alloys and Compounds,2006,421(1),185.80 Sandrock G, Reilly J, et al. Applied Physics A,2005,80(4),687.81 Chen T, Liu H Z, Xu L, et al. Journal of Materials Science &Engineering,2017,35(1),9(in Chinese).陈田,刘海镇,徐丽,等.材料科学与工程学报,2017,35(1),9.82 Andreasen A. Journal of Alloys and Compounds,2006,419(1),40.83 Graetz J. Isrn Materials Science,2012,2012(2012),1.84 Baranowski B, Tkacz M. Zeitschrift für Physikalische Chemie,1983,135(135),27.85 Saitoh H., Okajima Y, Yoneda Y, et al. Journal of Alloys and Compounds,2010,496(1-2),L25.86 Brinks H. W, Istad-Lem A, Hauback B C. Journal of Physical Chemistry B,2006,110(51),25833.87 Sartori S, Istad-Lem A, Brinks H W, et al. International Journal of Hydrogen Energy,2009,34(15),6350.88 Duan C, Hu L, Dan X. Green Chemistry,2015,17(6),3466.89 Brower F M, Matzek N E, Reigler P F, et al. Journal of the American Chemical Society,1976,98(9),2450.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2019, Vol. 33 
