Research Progress in Pyrolysis Method of Polymer Derived Ceramic Coatings
LI Enzhong1, GUO Weiling1, LIU Jun2, YU Helong1, XU Binshi1
1 National Key Laboratory for Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China 2 National Engineering Research Center for Mechanical Product Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China
Abstract: As the service environment of metal parts become more and more demanding, according to the different environment and failure characteristics of metal parts, different ceramic material systems and appropriate technologies are selected to prepare high-performance ceramic protective coating on the surface of metal parts and giving it special functions. The preparation of ceramic protective coatings on metal parts has become an effective way to solve the problem of reliable service of metal parts under harsh working conditions. As a new method of in-situ preparation of ceramic coating, polymer derived ceramic method takes advantage of the good fluidity, formability and designability of molecular structure of the precursor polymer, the polymer coating transformed into ceramic coating by pyrolysis, and dense protective coating is formed on the surface of the substrate material. Pyrolysis is an important way for precursors to transform from organic to ceramic coating. Traditional furnace pyrolysis uses setting heating program to achieve continuous and batch preparation of ceramic coatings on the surface of metals, porous materials, fibers or fiber-reinforced composite materials. The furnace pyrolysis simple and easy to control, but it has a great thermal effect on the substrate, then it is impossible to prepare ceramic coating on substrate with low melting point or complex structure. Laser pyrolysis can selectively control the heat input, with uniform heating rate and fast pyrolysis, and laser pyrolysis has little thermal effect on the substrate. Ceramic coatings with special compositions can be prepared by laser pyrolysis, while the precursor must be able to absorb laser, and the efficiency of laser pyrolysis is low. Ion beam irradiation is a non-thermal cracking method, which the pyrolysis speed is high, but has low efficiency and high cost. In this paper, the research progress in pyrolysis method of polymer derived ceramic coatings is summarized. The advantages and disadvantages of pyrolysis methods including furnace pyrolysis, laser pyrolysis and ion irradiation for polymer derived ceramic coatings are compared. In the future, it is necessary to explore new methods and technologies for controllable preparation of polymer derived ceramic coatings, reveal the evolution law microstructure from polymers to ceramic coatings, realize the accurate control of the preparation of the densification ceramic coatings which the crack defects can be precisely controlled.
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2021, Vol. 35 
