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材料导报  2020, Vol. 34 Issue (6): 6166-6171    https://doi.org/10.11896/cldb.19040174
  高分子与聚合物基复合材料 |
等离子体聚合聚环氧乙烷类涂层用于提高镁合金心血管支架抗腐蚀性能
余东海, 熊开琴, 黄楠
西南交通大学材料科学与工程学院,成都 610031
Plasma Polymerized Poly (Ethylene Oxide)-like Coating for Enhancing Corrosion Resistance of Magnesium Alloy Cardiovascular Stents
YU Donghai, XIONG Kaiqin, HUANG Nan
School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
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摘要 本研究以二乙二醇二甲醚(Diglyme)为单体,通过等离子体聚合技术得到均匀、无孔的聚环氧乙烷类(PEO-Like)涂层,并用来提高MgZnMn合金的抗腐蚀性能。在两种放电功率下制得了不同结构的涂层。X射线光电子能谱(XPS)和傅里叶变换衰减全反射红外光谱(ATR-FTIR)显示,高功率下制备的涂层(HPEO)比低功率下制备的涂层(LPEO)分子结构交联度更高。电化学与体外浸泡测试证明两种涂层均具有良好的防腐蚀效果,但HPEO保护效果更佳。经过球囊扩张试验后,HPEO在MgZnMn支架上仍粘附良好,并且在后续的PBS浸泡实验中,涂层依旧能显著降低支架的降解速率。
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余东海
熊开琴
黄楠
关键词:  等离子体聚合  镁合金  降解  心血管支架  聚环氧乙烷类    
Abstract: In this paper, in order to enhance the corrosion-resistance of MgZnMn alloy, plasma polymerization coatings were synthesized by using diethylene glycol dimethyl ether (diglyme) as organic monomer. Two kinds of an ultra-thin, pinhole-free with poly (ethylene oxide)-like (PEO-like) characteristics prepared with two different discharge power. X-ray photoelectron spectroscopy (XPS) and attenuated total internal reflection Fourier transform infrared spectroscopy (ATR-FTIR) results showed that, higher cross-linked structure formed when using high power (HPEO) than low power (LPEO). Electrochemical and in vitro immersion tests showed that two coatings had good anti-corrosion effect, especially the HPEO coating. The HPEO coating adhered well on the MgZnMn stent after the balloon expansion test, and significantly slowed down the degradation rate of the stent in the subsequent in vitro immersion test.
Key words:  plasma-polymerization    magnesium alloy    degradation    cardiovascular stent    PEO-like
               出版日期:  2020-03-25      发布日期:  2020-03-12
ZTFLH:  TB34  
基金资助: 国家自然科学基金(31570957;81330031)
作者简介:  余东海,出生于1994年,就读于西南交通大学生物医学工程专业,研究方向是生物医用镁合金的表面改性;黄楠,西南交通大学材料科学与工程学院教授,1985年毕业于西南交通大学,获得硕士学位。分别于1989—1991年和 1998—1999年在德国埃尔兰根大学和德国罗森多夫研究中心担任研究员和客座教授。研究方向包括生物材料的表界面、可降解的生物材料以及心血管装置。发明的一种血管支架已应用于临床。
引用本文:    
余东海, 熊开琴, 黄楠. 等离子体聚合聚环氧乙烷类涂层用于提高镁合金心血管支架抗腐蚀性能[J]. 材料导报, 2020, 34(6): 6166-6171.
YU Donghai, XIONG Kaiqin, HUANG Nan. Plasma Polymerized Poly (Ethylene Oxide)-like Coating for Enhancing Corrosion Resistance of Magnesium Alloy Cardiovascular Stents. Materials Reports, 2020, 34(6): 6166-6171.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19040174  或          http://www.mater-rep.com/CN/Y2020/V34/I6/6166
1 Luisada A A, Tyler D B. American Heart Journal, 1949, 18 (1),64.
2 Qi P K, Ying Y, Maitz F M, et al. Chinese Science Bulletin, 2013, 58 (35),4362.
3 Mani G, Feldman M D, Patel D, et al. Biomaterials, 2007, 28 (9),1689.
4 Erne P, Schier M, Resink T J. Cardiovascular & Interventional Radiology, 2006, 29 (1),11.
5 Heublein B, Rohde R, Kaese V, et al. Heart, 2003, 89 (6),651.
6 Nan Z, Zhu D. International Journal of Biomedical Engineering & Technology, 2013, 12 (4),382.
7 Maryam M, Diego M. International Journal of Molecular Sciences, 2011, 12 (7),4250.
8 Tang A T, Liu B, Pan F S, et al. Science in China Series E: Technological Sciences, 2009, 52 (1),155.
9 Liu H P, Cui L Y, Han Z Z, et al. Journal of Aeronautical Materials, 2019, 39 (1), 26 (in Chinese).
刘汉鹏, 崔蓝月, 韩壮壮, 等. 航空材料学报, 2019, 39 (1), 26.
10 Ding Z Y, Cui L Y, Zeng R C. Surface Technology, 2019, 48 (3),1 (in Chinese).
丁自友, 崔蓝月, 曾荣昌.表面技术, 2019, 48 (3),1.
11 Savage P, O'Donnell B P, Mchugh P E, et al. Annals of Biomedical Engineering, 2004, 32 (2),202.
12 Ring G, Bognár E, Dobránszky J, et al. Advances in Science and Technology, 2006, 49, 91.
13 Migliavacca F, Petrini L, Montanari V, et al. Medical Engineering & Physics, 2005, 27 (1),13.
14 Hornberger H, Virtanen S, Boccaccini A R. Acta Biomaterialia, 2012, 8 (7),2442.
15 Li L Y, Cui L Y, Zeng R C, et al. Acta biomaterialia, 2018, 79, 23.
16 Zhang C, Wyatt J, Weinkauf D H. Polymer, 2004, 45 (22),7665.
17 Ratner B D, Chilkoti A, Lopez G P, et al. Plasma deposition, treatment and etching of polymers, Elsevier Science, Holland,1990.
18 Qi P, Yang Y, Zhao S, et al. Materials & Design, 2016, 96,341.
19 Ko Y M, Choe H C, Jung S C, et al. Progress in Organic Coatings, 2013, 76 (12),1827.
20 Jeong D C, Javid A, Wen L, et al. Polymer, 2016, 92,133.
21 Banerjee I, Pangule R C, Kane R S. Advanced Materials, 2011, 23 (6), 690.
22 Yasuda H, Hirotsu T. Journal of Polymer Science Polymer Chemistry Edition, 1978, 16 (10),2587.
23 Palumbo F, Favia P, Vulpio M, et al. Plasmas and Polymers, 2001, 6 (3),163.
24 Cao L, Chang M, Lee C Y, et al. Journal of Biomedical Materials Research Part A, 2007, 81 (4),827.
25 Yang Z, Wang J, Li X, et al. Applied Surface Science, 2012, 258 (8),3378.
26 Socrates G. Infrared and raman characteristic group frequencies: tables and charts, 3rd edition, Proteomics, USA, 2004.
27 Lin-Vien D, Colthup N B, Fateley W G, et al. The handbook of infrared and Raman characteristic frequencies of organic molecules, Elsevier, USA, 1991.
28 Favia P, Creatore M, Palumbo F, et al. Surface & Coatings Technology, 2001, 142,1.
29 Choukourov A, Polonskyi O, Hanus J, et al. Plasma Processes & Polymers, 2009, 6 (S10),S21.
30 Muir B W, Tarasova A, Gengenbach T R, et al.Langmuir, 2008, 24 (8),3828.
31 Wang X, Chen Z, Shen Z.Science China Chemistry, 2005, 48 (6),553.
32 Mota R P, Bigansolli A R, Antunes E F, et al. Molecular Crystals and Liquid Crystals, 2002, 374 (1), 415.
33 Song G, Atrens A, St John D, et al. Corrosion Science, 1997, 39 (10),1981.
34 Shi Z, Liu M, Atrens A. Corrosion Science, 2010, 52 (2), 579.
35 Song G, Atrens A. Advanced Engineering Materials, 2010, 5 (12),837.
36 Chen Y, Wan G, Wang J, et al. Corrosion Science, 2013, 75, 280.
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