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材料导报  2026, Vol. 40 Issue (3): 25020118-7    https://doi.org/10.11896/cldb.25020118
  无机非金属及其复合材料 |
煤气化渣基流态固化土的制备、性能及水化机理
栗东平1, 角远烁1, 张凯帆2, 翟玉新3, *, 钱增志3, 王长龙1,*, 黄天勇4, 郑永超4, 白云翼1, 付兴帅1, 田京雷5, 孙宇佳5
1 河北工程大学土木工程学院,河北省建筑工程低碳建造与韧性提升重点实验室,河北 邯郸 056038
2 江西理工大学资源与环境工程学院,稀有金属资源安全高效开采江西省重点实验室,江西 赣州 341000
3 中铁建设集团有限公司,北京 100040
4 北京建筑材料科学研究总院有限公司,固废资源化利用与节能建材国家重点实验室,北京 100041
5 河钢集团有限公司,石家庄050023
Fabrication,Properties and Hydration Mechanism of Fluid Solidifying Soil Containing Coal Gasification Slag
LI Dongping1, JIAO Yuanshuo1, ZHANG Kaifan2, ZHAI Yuxin3,*, QIAN Zengzhi3, WANG Changlong1,*, HUANG Tianyong4, ZHENG Yongchao4, BAI Yunyi1, FU Xingshuai1, TIAN Jinglei5, SUN Yujia5
1 Hebei Province Key Laboratory for Low-Carbon Construction and Resilience Enhancement of Construction Engineering, School of Civil Engineering, Hebei University of Engineering, Handan 056038, Hebei, China
2 Jiangxi Provincial Key Laboratory of Safe and Efficient Mining of Rare Metal Resource, School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China
3 China Railway Construction Group Co.,Ltd., Beijing 100040, China
4 State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Science Research, Beijing 100041, China
5 HBIS Group Co., Ltd., Shijiazhuang 050023, China
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摘要 为了解决我国煤化工与冶金行业中的大量固体废弃物堆存问题,以煤气化渣、脱硫灰渣、矿渣、水泥为原料制备了固化剂,代替纯水泥后与黏土混合制备了流态固化土。采用粒度分析、力学性能测试、X射线衍射(XRD)及扫描电镜(SEM)等测试手段,研究了煤气化渣的粉磨特性、流态固化土的性能和固化剂的水化机理。结果表明:粉磨50 min的煤气化渣比表面积达到560 m2/kg,其28 d活性指数达65.9%;当固化剂中m煤气化渣m矿渣m脱硫灰渣m水泥=30∶30∶12∶28、m固化剂m黏土=12∶88、料浆浓度为80%、PC聚羧酸减水剂掺量为1.1%时,流态固化土3 d和28 d抗压强度分别达到1.64 MPa和2.31 MPa;固化剂的主要水化产物为C-S-H凝胶、Ca(OH)2、钙矾石(AFt)。
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栗东平
角远烁
张凯帆
翟玉新
钱增志
王长龙
黄天勇
郑永超
白云翼
付兴帅
田京雷
孙宇佳
关键词:  煤气化渣  粉磨特性  固化剂  流态固化土  水化机理    
Abstract: To address the significant issue of solid waste stockpiles between coal chemical and metallurgical industries in China, a curing agent was prepared by using coal gasification slag (CGS), flue gas desulfurization residue, slag, and cement as raw materials. This curing agent, instead of pure cement mixed with clay, was used to produce fluid solidifying soil. The grinding characteristics of CGS, the properties of fluid solidifying soil and the hydration mechanism of the curing agent were investigated by using particle size analysis, mechanical property tests, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The results showed that the specific surface area of CGS milled for 50 minutes reached 560 m2/kg and its 28-day activity index reached 65.9%. When the mass ratio of curing agent in CGS,slag,flue gas desulfurization residue,cement was 30∶30∶12∶28, the mass ratio of curing agent, clay was 12∶88, the slurry concentration was 80%, and the dosage of PC polycarboxylate superplasticizer was 1.1%, the 3 day and 28 day compressive strength of the fluid solidifying soil reached 1.64 MPa and 2.31 MPa, respectively; the main hydration products of the curing agent are C-S-H gel, Ca(OH)2, and ettringite (AFt).
Key words:  coal gasification slag (CGS)    grinding characteristics    curing agent    fluid solidifying soil    hydration mechanism
发布日期:  2026-02-13
ZTFLH:  TU528  
基金资助: 国家重点研发计划(2021YFC1910605);河北省自然科学基金(E2020402079);固废资源化利用与节能国家重点实验室开放基金(SWR-2023-007);国家环境保护矿冶资源利用与污染控制重点实验室开放基金(HB202306);河北省建筑工程低碳建造与韧性提升重点实验室开放基金(HKL-LRC-2024-2;HKL-LRC-2025-8)
通讯作者:  *翟玉新,博士,中铁建设集团正高级工程师,北京工业大学博士研究生导师。长期从事岩土环境材料的原理设计及关键技术方面的研究。
王长龙,博士,河北工程大学教授、博士研究生导师。长期从事固废高值利用理论及关键技术方面的研究。   
作者简介:  栗东平,博士,河北工程大学教授、硕士研究生导师。长期从事地基处理及基坑支护、煤炭开采及围岩稳定性控制、岩石力学及工程应用等方面的科学研究工作。
引用本文:    
栗东平, 角远烁, 张凯帆, 翟玉新, 钱增志, 王长龙, 黄天勇, 郑永超, 白云翼, 付兴帅, 田京雷, 孙宇佳. 煤气化渣基流态固化土的制备、性能及水化机理[J]. 材料导报, 2026, 40(3): 25020118-7.
LI Dongping, JIAO Yuanshuo, ZHANG Kaifan, ZHAI Yuxin, QIAN Zengzhi, WANG Changlong, HUANG Tianyong, ZHENG Yongchao, BAI Yunyi, FU Xingshuai, TIAN Jinglei, SUN Yujia. Fabrication,Properties and Hydration Mechanism of Fluid Solidifying Soil Containing Coal Gasification Slag. Materials Reports, 2026, 40(3): 25020118-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25020118  或          https://www.mater-rep.com/CN/Y2026/V40/I3/25020118
1 Liu F, Guo L F, Zhao L Z. Journal of China Coal Society, 2022, 47(1), 1(in Chinese).
刘峰, 郭林峰, 赵路正. 煤炭学报, 2022, 47(1), 1.
2 National Bureau of Statistics. Statistical bulletin on national economic and social development of the People’s Republic of China in 2023, China Statistical Publishing House, China, 2023, pp. 6 (in Chinese).
国家统计局. 中华人民共和国2023年国民经济和社会发展统计公报, 中国统计出版社, 2023, pp. 6.
3 Qi W Y, Han Y J, Duan G, et al. Construction and Building Materials, 2024, 425, 135970.
4 Zhang L H, Jin Y R, Cheng F Q. Chemical Industry and Engineering Progress, 2023, 42(8), 4447(in Chinese).
张丽宏, 金要茹, 程芳琴. 化工进展, 2023, 42(8), 4447.
5 Zhu J F, Li J, Yan L, et al. Clean Coal Technology, 2021, 27(6), 11(in Chinese).
朱菊芬, 李健, 闫龙, 等. 洁净煤技术, 2021, 27(6), 11.
6 Li Z Z, Zhang Y Y, Zhao H Y, et al. Construction and Building Materials, 2019, 213, 265.
7 Wu F, Li H, Yang K. Coatings, 2021, 11(8), 902.
8 Zhu M B, Xie G, Liu L, et al. Materials, 2022, 15(17), 6033.
9 Pan Y, Lang L, Yong L S, et al. Construction and Building Materials, 2023, 401, 132973.
10 Liu S, Liu W, Jiao F, et al. Environmental Pollution, 2021, 288, 117799.
11 Zhou M K, Chen P, Chen X, et al. Construction and Building Materials, 2020, 251, 118993.
12 Sun R, Wang D M, Wang Y R, et al. Cement and Concrete Composites, 2022, 131, 1.
13 Chen C S, Sulakshana S, Pan Y H, et al. Construction and Building Materials, 2024, 411, 134585.
14 Xie G, Liu L, Suo Y L, et al. Process Safety and Environmental Protection, 2024, 182, 127.
15 Han Y, Qi W, Pang H, et al. Construction and Building Materials, 2024, 420, 135591.
16 Ma Z, Sun Y, Duan S, et al. Construction and Building Materials, 2024, 420, 135581.
17 Tian Y, Wang Y, Chai H, et al. Construction and Building Materials, 2024, 414, 134864.
18 Xiang J C, Qi J P, Zhao Y Q, et al. Cement and Concrete Composites, 2024, 147, 105418.
19 Fang K Z, Zhang D J, Wang D M, et al. Journal of Building Engineering, 2023, 69, 106237.
20 Tian Y, Xie Z L, Xue K W, et al. Construction and Building Materials, 2023, 373, 130852.
21 Li Z Z, Li F, Xie H W, et al. Materials, 2022, 15(24), 8868.
22 Yang P, Suo Y L, Liu L, et al. Journal of Building Engineering, 2022, 62, 105318.
23 Fu B, Cheng Z Y, Wang D Z, et al. Construction and Building Materials, 2022, 323, 126587.
24 Tsivilis S, Parissakis G. Cement and Concrete Research, 1995, 25(1), 9.
25 Fuller W B, Thompson S E. Journal of the Society for Chemical Industry, 1934, 53(2), 107.
26 Ma J T. Research on the preparation of composite cementitious materials and concrete from metallurgical and coal based solid waste. Master’s Thesis, Hebei University of Engineering, China, 2023(in Chinese).
马锦涛. 冶金-煤基固废制备复合胶凝材料及混凝土的研究. 硕士学位论文, 河北工程大学, 2023.
27 Li X Z, Zhang H Z, Zhang S H, et al. Materials Reports, 2023, 37(8), 22040240 (in Chinese).
李小占, 张鸿泽, 张苏花, 等. 材料导报, 2023, 37(8), 22040240.
28 Zhang H Z, Qi Y, Jing J L, et al. Frontiers in Earth Science, 2023, 11, 1181974.
29 Wang C L, Qi Y, Jing J L, et al. Frontiers in Earth Science, 2023, 11, 1181952.
30 Wang F, Zheng Q Q, Zhang G Q, et al. Journal of New Materials for Electrochemical Systems, 2020, 23(1), 52.
31 Wang C L, Ren Z Z, Huo Z K, et al. Alexandria Engineering Journal, 2021, 60, 4961.
32 Zhang K F, Wang X J, Wang C L, et al. Materials Reports, 2025, 39(2), 23120264 (in Chinese).
张凯帆, 王晓军, 王长龙, 等. 材料导报, 2025, 39(2), 23120264.
33 Wang C L, Chen J L, Yang F H, et al. Science Technology and Engineering, 2023, 23(3), 1207(in Chinese).
王长龙, 陈敬亮, 杨丰豪, 等. 科学技术与工程, 2023, 23(3), 1207.
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