微波法制备碳纳米材料的机理及进展

doi:10.11896/cldb.22110109

材料导报

2024, Vol. 38

Issue (3): 22110109-6 https://doi.org/10.11896/cldb.22110109

无机非金属及其复合材料

微波法制备碳纳米材料的机理及进展

王加悦, 周涵^*

上海交通大学材料科学与工程学院,金属基复合材料国家重点实验室,上海 200240

Microwave Synthesis of Carbon Nanomaterials:Mechanisms and Recent Progress

WANG Jiayue, ZHOU Han^*

State Key Laboratory of Metal Matrix Composites, Department of Material Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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摘要微波法具有加热快速、易于控制、反应均匀等优点,是制备功能性碳纳米材料的重要技术。其制备原理是基于碳基材料优异的本征介电性能,碳基材料与微波电磁场相互作用产生介电损耗,快速形成局部高能场,实现高速制备。本文首先简要介绍了微波与物质的相互作用机理,然后分别从微波在制备过程中的作用、关键实验参数以及微波制备的碳材料的特征等方面详细介绍了微波作为能量输入制备一维碳纳米管、二维石墨烯以及三维纳米多孔碳的优势,最后对宏量快速制备多功能和高性能碳纳米材料的发展进行了展望。

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关键词: 微波法碳纳米材料碳纳米管石墨烯多孔碳

Abstract: Microwave method is an important technique for the synthesis of functional carbon nanomaterials, with advantages of rapid heating, easy to control and uniform reaction. The synthetic mechanism is based on the excellent intrinsic dielectric properties of carbon materials, which can have strong interactions with the microwave electromagnetic field, thus causing strong dielectric loss and localized high energy field for the fast synthesis. In this paper, we briefly introduce the interaction mechanism between microwave and matter. Then the advantages of microwave as energy input for the preparation of 1D carbon nanotubes, 2D graphene and 3D nano-porous carbon are introduced in detail from aspects of the microwave functions, key experimental parameters and the characteristics of carbon materials prepared by microwave. Finally, approaches for fast synthesis of multifunctional and high-performance carbon nanomaterials on large scale are prospected.

Key words: microwave carbon nanomaterial carbon nanotube graphene porous carbon

出版日期: 2024-02-10 发布日期: 2024-02-19

ZTFLH:

TB34

基金资助: 国家重点研发计划(2017YFE0127100)

通讯作者: *周涵,上海交通大学材料科学与工程学院及金属基复合材料国家重点实验室教授、博士研究生导师。2010年获得上海交通大学-美国加州大学戴维斯分校联合培养博士学位,2012—2013年在日本国立物质材料研究所从事博士后工作,2013—2014年在德国马普所胶体与界面研究所从事洪堡学者研究。近年来,在PNAS、Adv.Mater.、Adv.Funct.Mater.、ACS Nano等发表SCI文章70余篇,主要研究方向为仿生材料与智能材料、超材料、热调控材料。hanzhou_81@sjtu.edu.cn

作者简介: 王加悦,2019年6月于大连理工大学获得工学学士学位。现为上海交通大学材料科学与工程学院硕士研究生。目前主要研究领域为微波法功能材料的制备及性能。

引用本文:

王加悦, 周涵. 微波法制备碳纳米材料的机理及进展[J]. 材料导报, 2024, 38(3): 22110109-6.
WANG Jiayue, ZHOU Han. Microwave Synthesis of Carbon Nanomaterials:Mechanisms and Recent Progress. Materials Reports, 2024, 38(3): 22110109-6.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.22110109 或 https://www.mater-rep.com/CN/Y2024/V38/I3/22110109

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