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材料导报  2024, Vol. 38 Issue (3): 22060047-8    https://doi.org/10.11896/cldb.22060047
  无机非金属及其复合材料 |
石墨烯的分散方法及在水性环氧富锌涂料中的应用进展
桂晓露1,*, 程瑄1, 李芃飞1, 高古辉1, 孙丽娅2, 易汉平2
1 北京交通大学机械与电子控制工程学院,材料中心,北京 100044
2 鄂尔多斯市紫荆创新研究院,内蒙古 鄂尔多斯 017000
A Review of Dispersion Methods of Graphene and Its Applications in Waterborne Epoxy Zinc-rich Coatings
GUI Xiaolu1,*, CHENG Xuan1, LI Pengfei1, GAO Guhui1, SUN Liya2, YI Hanping2
1 School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044, China
2 Redbud Innovation Institute of Erdos, Ordos 017000, Inner Mongolia, China
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摘要 石墨烯具有高的比表面积、高的机械强度、优异的导热和导电性、低的化学反应活性、良好的物理阻隔性能等特性,在提升涂料/涂层防腐性能方面具有很大的潜力,因而受到了广泛关注,石墨烯水性环氧富锌涂料是其中的研究热点。但是,石墨烯较大的比表面积及层间范德华力的相互作用导致其在水性溶剂或聚合物基体中极易发生团聚,直接影响了其在水性涂料/涂层中性能的发挥。因此,如何改善石墨烯在水性溶剂或聚合物基体中的分散性是待解决的首要问题。本文综述了石墨烯在水性环氧富锌涂料中的研究进展,对比讨论了单一或多种分散方法对石墨烯在水性涂料特别是水性环氧涂料中分散效果的影响规律及适用范围,对现有文献中石墨烯环氧富锌涂料的防腐性能进行了汇总,分析了石墨烯类型、含量及其与锌粉的相对比例对涂料/涂层性能的影响规律及选择原则。最后,本文介绍了石墨烯在提高涂层屏蔽性能及阴极保护方面的作用机理,并对石墨烯水性环氧富锌涂料在工业化制备和应用方面面临的挑战和未来研究方向进行了简要讨论。
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桂晓露
程瑄
李芃飞
高古辉
孙丽娅
易汉平
关键词:  石墨烯  腐蚀  水性环氧富锌涂料  防腐机理    
Abstract: Graphene has attracted attention as a substrate for anticorrosion coatings owing to its large specific surface area, low chemical reactivity, extraordinary mechanical, thermal, and electrical properties, and good physical barrier properties. Environmentally friendly graphene waterborne zinc-rich coatings are among the most attractive anticorrosion coatings. However, the large specific surface area of graphene and van der Waals interactions between layers usually result in an irreversibly agglomerated structure in water and common organic solvents, complicating their use and liquid phase processing and limiting their potential applications. Therefore, methods to improve the dispersion of graphene in water-based solvents or polymer matrices are required. This review primarily focuses on the role of graphene in waterborne epoxy zinc-rich coatings. First, the effects of dispersion on the dispersibility of graphene in water-based coatings, particularly water-based epoxy coatings, and their applicability are compared and discussed. Second, the anticorrosion properties of graphene epoxy zinc-rich coatings are summarized based on exi-sting literature. The effects of graphene type, content, and its relative ratio to zinc powder on the anticorrosion performance of coatings are discussed. Finally, other topics covering the fundamentals of protection mechanisms, performance evaluation, challenges, and future research directions on zinc-rich epoxy composite coatings are briefly discussed.
Key words:  graphene    corrosion    waterborne zinc-rich coating    anticorrosion mechanism
出版日期:  2024-02-10      发布日期:  2024-02-19
ZTFLH:  TQ638  
基金资助: 内蒙古自治区科技重大专项(2020ZD0019)
通讯作者:  *桂晓露,北京交通大学实验师。2013年1月毕业于北京科技大学材料物理系,同年进入北京交通大学机电学院工作至今。主要从事石墨烯分散及水性涂料的开发工艺研究,在SCI和EI上发表论文20余篇。xlgui@bjtu.edu.cn   
引用本文:    
桂晓露, 程瑄, 李芃飞, 高古辉, 孙丽娅, 易汉平. 石墨烯的分散方法及在水性环氧富锌涂料中的应用进展[J]. 材料导报, 2024, 38(3): 22060047-8.
GUI Xiaolu, CHENG Xuan, LI Pengfei, GAO Guhui, SUN Liya, YI Hanping. A Review of Dispersion Methods of Graphene and Its Applications in Waterborne Epoxy Zinc-rich Coatings. Materials Reports, 2024, 38(3): 22060047-8.
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https://www.mater-rep.com/CN/10.11896/cldb.22060047  或          https://www.mater-rep.com/CN/Y2024/V38/I3/22060047
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