硅胶载体的制备及在聚烯烃催化剂领域中的应用

doi:10.11896/cldb.22040363

材料导报

2024, Vol. 38

Issue (1): 22040363-11 https://doi.org/10.11896/cldb.22040363

高分子与聚合物基复合材料

硅胶载体的制备及在聚烯烃催化剂领域中的应用

张玉金^1,†, 杨琦^2,†, 张瑞², 高宇新², 拜永孝^1,*

1 兰州大学材料与能源学院软物质与先进功能材料研究所,兰州 730000
2 中国石油天然气股份有限公司大庆化工研究中心,黑龙江大庆 163714

Preparation of Silica Gel Supports for Polyolefin Catalysts Application

ZHANG Yujin^1,, YANG Qi^2,, ZHANG Rui², GAO Yuxin², BAI Yongxiao^1,*

1 Institute of Soft Matter and Advanced Functional Materials, School of Materials and Energy, Lanzhou University, Lanzhou 730000, China
2 PetroChina Daqing Petrochemical Research Center, Daqing 163714, Heilongjiang, China

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摘要催化剂及催化技术的发展是聚烯烃产业技术进步的核心。硅胶作为聚烯烃催化剂常用的载体材料,在催化剂的合成及聚烯烃树脂的制备领域发挥着重要的作用。近年来,关于硅胶负载聚烯烃催化剂的研究已陆续发表。本文综述了硅胶载体的结构、制备方法以及硅胶载体与聚烯烃催化剂(Ziegler-Natta催化剂、茂金属催化剂、后过渡金属催化剂及铬基催化剂)负载化的研究进展,并介绍了催化剂的制备机理、优点及应用。

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关键词: 硅胶催化剂载体聚烯烃

Abstract: The evolution of catalyst and catalyst technologies is essential to the technological progress of the polyolefin industry. Silica gel, a common carrier material, plays an important role in catalyst synthesis and the industrial production of polyolefin plastics. Recently, several studies on the status and trend of silica gel-supported polyolefin catalystshave been published. This paper presents the silica gel support structure, preparation methods, and the research progress of silica gel-supported polyolefin catalysts (such as Ziegler-Natta, metallocene, post-transition metal, and chromium-based catalysts). Furthermore, the preparation mechanism, advantages and applications of catalysts are introduced.

Key words: silica gel catalyst carrier polyolefin

发布日期: 2024-01-16

ZTFLH:

TQ317

基金资助: 中国石油天然气股份有限公司大庆化工研究中心项目(DQZX-KY-20-006);兰州市科技计划项目(2021-1-44)

通讯作者: 拜永孝,兰州大学材料与能源学院教授、博士研究生导师。1997年于南京理工大学化学化工学院工业分析专业本科毕业,毕业后在中国石油天然气股份有限公司兰州化工研究中心工作。2006年于兰州大学化学化工学院高分子化学与物理专业博士毕业,毕业后在兰州大学工作至今。长期致力于聚烯烃催化剂载体和催化材料、聚合物基复合材料等领域的基础研究、技术开发和工程应用方面的研究工作。在ACS Applied Materials & Interfaces、Composites Science and Technology、Chemical Communications、Nanoscale、The Journal of Physical Chemistry C、Composite Part A、《材料导报》《化学通报》等期刊上发表了60余篇研究论文,30余项中国发明专利获得授权。baiyx@lzu.edu.cn

作者简介: †共同第一作者
张玉金,2017年6月、2020年6月分别于江苏理工学院和兰州大学获得工学学士学位和硕士学位。现为兰州大学材料与能源学院博士研究生,在拜永孝教授的指导下进行研究。目前主要研究领域为聚合物基复合材料。发表SCI论文4篇,包括ACS Applied Materials & Interfaces、Advanced Materials Interfaces、ACS Applied Nano Material 等,4项中国发明专利获得授权。
杨琦,2011年6月、2014年6月分别于四川大学和东北石油大学获得工学学士学位和硕士学位,现工作于中国石油天然气股份有限公司大庆化工研究中心。目前主要研究领域为聚烯烃催化剂及新产品开发等。

引用本文:

张玉金, 杨琦, 张瑞, 高宇新, 拜永孝. 硅胶载体的制备及在聚烯烃催化剂领域中的应用[J]. 材料导报, 2024, 38(1): 22040363-11.
ZHANG Yujin, YANG Qi, ZHANG Rui, GAO Yuxin, BAI Yongxiao. Preparation of Silica Gel Supports for Polyolefin Catalysts Application. Materials Reports, 2024, 38(1): 22040363-11.

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https://www.mater-rep.com/CN/10.11896/cldb.22040363 或 https://www.mater-rep.com/CN/Y2024/V38/I1/22040363

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