Abstract: Conventional tungsten alloy core materials struggle to meet the dual requirements of high-speed penetration and post-penetration damage effects due to defects such as poor plasticity and susceptibility to "mushrooming effect". In recent years, tungsten particle-reinforced Zr-based bulk metallic glass composites (Wp/Zr-BMGCs) have demonstrated significant potential in armor-piercing fragmentation core materials, owing to their high strength, superior hardness, favorable plasticity, and unique self-sharpening and energy release effects during penetration processes. However, the engineering applications of Wp/Zr-BMGCs remain hindered by challenges including insufficient understanding of penetration and post-penetration damage mechanisms, imperfect dynamic constitutive models, and complex fabrication processes. Based on the fundamental characteristics of Wp/Zr-BMGCs, this paper investigates the synergistic enhancement mechanism of strength and plasticity in tungsten particles within the composite, along with factors influencing the penetration mechanical behavior. Based on the fundamental characteristics of Wp/Zr-BMGCs, this study elucidates the synergistic enhancement mechanism of strength-plasticity in tungsten particles within the composite and identifies key factors influencing their penetration mechanical behavior. It systematically reviews research advancements in armor-piercing penetration and post-penetration damage behavior of Zr-based metallic glass composites reinforced with tungsten particles, provides critical analyses on numerical simulations of penetration dynamics and developments in fabrication techniques. Focusing on the application progress of Wp/Zr-BMGCs in armor-piercing fragmentation materials, the paper proposes three strategic research directions for future investigations, offering valuable insights for researchers in this field.
1 Geng H H, Liu R, Deng P, et al. Journal of Applied Physics, 2023, 133(11), 115104. 2 Jiao Y B, Ouyang C, Luo W M, et al. Journal of Armament Equipment Engineering, 2021, 42(12), 72 (in Chinese). 焦延博, 欧阳稠, 罗文敏, 等. 兵器装备工程学报, 2021, 42(12), 72. 3 Zbigniew H S, Wang G, Tan X H. An introduction to metallic glasses and amorphous metals, Higher Education Press, China, 2023, pp. 126 (in Chinese). 兹比格纽·斯塔祖奇, 王刚, 谭晓华. 金属玻璃和非晶合金导论, 高等教育出版社, 2023, pp. 126. 4 Zhang X F, Shi A S, Qiao L, et al. Journal of Applied Physics, 2013, 113(8), 083508. 5 Guha S, Kyriacou C, Withers J C, et al. Materials and Manufacturing Processes, 1994, 9(6), 1163. 6 Guha S, Baker I P. Munroe R. Materials Characterization, 1995, 34(3), 181. 7 Ryu H J, Hong S H, Baek W H. Materials Science and Engineering, 2000, 291(1-2), 91. 8 Ryu H J, Hong S H. Metals and Materials International, 2001, 7(3), 221. 9 Lawcock R L, Davies D J. Power Metallurgy, 1990, 33(2), 147. 10 Cao Y, Zhang C, Yang Z G, et al. Iron and Steel Research, 2012, 24(1), 54 (in Chinese). 曹悦, 张弛, 杨志刚, 等. 钢铁研究, 2012, 24(1), 54. 11 Dai J D, Li D Y, Hu M L. Materials Science and Technology, 2013, 21(6), 47 (in Chinese). 戴建东, 李大勇, 胡茂良. 材料科学与工艺, 2013, 21(6), 47. 12 Rong G L, Zhuge X, Li J, et al. Vibration and Shock, 2015, 34(1), 200 (in Chinese). 荣吉利, 诸葛迅, 李健, 等. 振动与冲击, 2015, 34(1), 200. 13 Yi R C, Wang J R, Yin L K, et al. Vibration and Impact, 2017, 36(6), 163 (in Chinese). 易荣成, 王坚茹, 印立魁, 等. 振动与冲击, 2017, 36(6), 163. 14 Yuan S Q, Zhang B Y, Chen Z M, et al. China Tungsten Industry, 2015, 30(2), 49 (in Chinese). 袁书强, 张保玉, 陈子明, 等. 中国钨业, 2015, 30(2), 49. 15 Yuan S P, Li S K, Song X G, et al. Material Engineering, 2007(9), 26 (in Chinese). 袁慎坡, 李树奎, 宋修纲, 等. 材料工程, 2007(9), 26. 16 Du Z H, Shen P H, Zhao G Z. Journal of Ballistics, 2006, 18(4), 51 (in Chinese). 杜忠华, 沈培辉, 赵国志. 弹道学报, 2006, 18(4), 51. 17 Liu T L, Shen P H, Xue J F. Journal of Vibration and Shock, 2019, 38(22), 251 (in Chinese). 刘铁磊, 沈培辉, 薛建锋. 振动与冲击, 2019, 38(22), 251. 18 Cheng H C, Shi M J, Luo X, et al. Journal of Central South University (Natural Science Edition), 2024, 55(8), 3129 (in Chinese). 成会朝, 石明君, 罗旭, 等. 中南大学学报(自然科学版), 2024, 55(8), 3129. 19 Chi J, Hu H, Jin H, et al. Journal of Non-Crystalline Solids, 2024, 625, 122777. 20 Sun B A, Wang W H. Progress in Materials Science, 2015, 74, 211. 21 Greer A L, Cheng Y Q, Ma E. Materials Science and Engineering R:Reports, 2013, 74(4), 71. 22 Shan Z, Chao W, Liang Y, et al. Materials Science & Engineering A, 2022, 840, 142978. 23 Pan J, Ivanov Y P, Zhou W H, et al. Nature, 2020, 578(7796), 559. 24 Hu H E, Kong X D, Su X H. Materials Development and Application, 2017, 32(3), 109 (in Chinese). 胡会娥, 孔小东, 苏小红. 材料开发与应用, 2017, 32(3), 109. 25 Zhang Y F, Luo X B. Journal of Ordnance Equipment Engineering, 2021, 42(6), 133 (in Chinese). 张云峰, 罗兴柏. 兵器装备工程学报, 2021, 42(6), 133. 26 Hu A B, Zhao C Y, Luo C J, et al. Journal of Ordnance Science, 2024, 45(12), 4407 (in Chinese). 胡敖博, 赵超越, 罗陈进, 等. 兵工学报, 2024, 45(12), 4407. 27 Li X, Wang W L, Liang Z F, et al. Journal of Ordnance Science, 2021, 42(4), 764 (in Chinese). 李鑫, 王伟力, 梁争峰, 等. 兵工学报, 2021, 42(4), 764. 28 Zhou S, Zhang J H, Yu Q B. Journal of Ordnance Science, 2023, 44 (8), 2263 (in Chinese). 周晟, 张甲浩, 余庆波. 兵工学报, 2023, 44(8), 2263. 29 Yin G X, Zhang Q, Chen P, et al. Journal of Physics: Conference Series, 2023, 2478(7), 072006. 30 Saida J, Setyawan A D H, Kato H, et al. Applied Physics Letters, 2005, 87(15), 151907. 31 Shan Z, Chao W, Liang Y, et al. Materials Science & Engineering A, 2022, 840, 142978. 32 Zhang Y, Lin X, Gao X, et al. Intermetallics, 2021, 136, 107256. 33 Hin S, Bernard C, Doquet V, et al. Materials Science and Engineering A, 2019, 740, 137. 34 Jin H, Hu H, Chi J, et al. Materials, 2023, 16(15), 5212. 35 Ma Y F, Gong P, Zhang M, et al. Rare Metals, 2024, 43(4), 1793. 36 Ma Y, Gong P, Yang X, et al. Journal of Alloys and Compounds, 2025, 1010, 177721. 37 Chi J, Hu H, Jin H, et al. Journal of Alloys and Compounds, 2024, 1008, 176730. 38 Xue Y, Zhong X, Wang L, et al. Materials Science and Engineering A, 2015, 639, 417. 39 Li Y Y, Hu H, Jin H, et al. Journal of Materials Research, 2008, 23(3), 745. 40 Conner R Dr, Dandliker R B, Scruggs V. International Journal of Impact Engineering, 2000, 24(5), 435. 41 Choi-Yim H, Conner R D, Szuecs F, et al. Scripta Materialia, 2001, 45(9), 1039. 42 Zhang X C, Chen X H, Zhang Y, et al. Rare Metal Materials & Engineering, 2008, 37, 786. 43 Chen S, Zhu H T, Wang J H, et al. Journal of Materials Research and Technology, 2025, 35, 3118. 44 Wang M L, Yang B. Transactions of Materials and Heat Treatment, 2012, 33, 7. 45 Lee S B, Lee S K, Lee S, et al. Metallurgical and Materials Transactions A, 2008, 39(4), 763. 46 Hu Z Q, Zhang H F. Acta Metallurgica Sinica, 2010, 46(11), 1391. 47 Dandlike R B, Conne R D, Johnson W L. Journal of Materials Research, 1998, 13(10), 2896. 48 Lei B, Huang D W, Yang M C, et al. Journal of Shenyang University of Science and Technology, 2008, 35(1), 72 (in Chinese). 雷波, 黄德武, 杨明川, 等. 沈阳理工大学学报, 2008, 35(1), 72. 49 Kirchberg S, Abdin Y, Ziegmann G I. Powder Technology, 2011, 207(1-3), 311. 50 Qiu K Q, Ren Y L. Rare Metal Materials and Engineering, 2006, 35(1), 66. 51 HE Z Q, Zhang T, Zhang Z, et al. Journal of Materials Science and Engineering, 2007, 25(1), 132 52 Zhang H F, Ma W J, Liu L Q, et al. Material China, 2010, 29, 8 53 Wu Z. Preparation and properties of short W fiber/Zr-based amorphous composites. Master’s Thesis, Shenyang University of Aeronautics and Astronautics, China, 2016 (in Chinese). 吴争. 钨丝/钨颗粒增强Zr基非晶复合材料的制备与性能. 硕士学位论文, 沈阳工业大学, 2020. 54 Choi-Yim H, Schroers J, Johnson W L. Applied Physics Letters, 2002, 80(11), 1906. 55 Sun P Y, Qiu C L, Ma Y F, et al. Materials Science and Engineering A, 2021, 815, 141312. 56 Chen X W, Li J C, Zhang F J, et al. Explosion and Shock Waves, 2012, 32(4), 346 (in Chinese). 陈小伟, 李继承, 张方举, 等. 爆炸与冲击, 2012, 32(4), 346. 57 Du Z H, Du C X, Zhu Z W, et al. Rare Metal Materials and Engineering, 2016, 45(9), 2359 (in Chinese). 杜忠华, 杜成鑫, 朱正旺, 等. 稀有金属材料与工程, 2016, 45(9), 2359. 58 Du C X, Du Z H, Zhu Z W. Rare Metal Materials and Engineering, 2017, 46(6), 1632 (in Chinese). 杜成鑫, 杜忠华, 朱正旺. 稀有金属材料与工程, 2017, 46(6), 1632. 59 Zou M M, Guo M, Chai D S, et al. Ordnance Material Science and Engineering, 2021, 44(2), 107 (in Chinese). 邹敏明, 郭珉, 柴东升, 等. 兵器材料科学与工程, 2021, 44(2), 107. 60 Yu X, Li J, Gai X, et al. Materials & Design, 2025, 251, 113703. 61 Deng J X, Hu H E, Su X H, et al. Journal of Ordnance Equipment Engineering, 2021, 42(5), 173 (in Chinese). 邓晶鑫, 胡会娥, 苏小红, 等. 兵器装备工程学报, 2021, 42(5), 173. 62 Hu H, Jin H, Chi J, et al. Intermetallics, 2025, 177, 108601. 63 Yang L, Yu S X, Fan Q B. Journal of Beijing Institute of Technology, 2023, 43(4), 417 (in Chinese). 杨林, 于述贤, 范群波. 北京理工大学学报, 2023, 43(4), 417. 64 Sharma A, Zadorozhnyy V. Metals, 2021, 11(12), 1933. 65 Zhou F, Chen J, Yuan Y, et al. Journal of Ballistics, 2024, 36(3), 75 (in Chinese). 周峰, 陈俊, 袁勇, 等. 弹道学报, 2024, 36(3), 75. 66 Jia J, Zhi X Q, Hao C J, et al. Journal of High Pressure Physics, 2024, 38 (2), 128 (in Chinese). 贾杰, 智小琦, 郝春杰, 等. 高压物理学报, 2024, 38(2), 128. 67 Zhang Y L, Shi D M, Zhang Y F, et al. Explosion and Shock Waves, 2021, 41(5), 58 (in Chinese). 张玉令, 施冬梅, 张云峰, 等. 爆炸与冲击, 2021, 41(5), 58. 68 Lin S, Ge S, Li W, et al. Journal of Non-Crystalline Solids, 2021, 553, 120508. 69 Zhang Z, Kong J, Liu X, et al. Intermetallics, 2021, 132, 107139. 70 Wang X D, Song S L, Liu D M, et al. Intermetallics, 2021, 136, 107253. 71 Wriggers O, Peter S, Moftah M. Finite Elements in Analysis and Design, 2006, 42(7), 623. 72 Liu T L, Xu Y X, Wang X F, et al. Journal of Military Engineering, 2022, 43 (4), 768 (in Chinese). 刘铁磊, 徐豫新, 王晓峰, 等. 兵工学报, 2022, 43(4), 768. 73 Cheng Y, Zhao T Y, Chen Z G, et al. Blasting Equipment, 2019, 48 (5), 52 (in Chinese). 程瑶, 赵太勇, 陈智刚, 等. 爆破器材, 2019, 48(5), 52. 74 Deng Y F, Zhang Y, An J D, et al. Vibration and Shock, 2020, 39 (18), 7077 (in Chinese). 邓云飞, 张永, 安静丹, 等. 振动与冲击, 2020, 39(18), 70. 75 Su X, Hu H, Kong X, et al. Journal of Physics: Conference Series, 2020, 1637(1), 012025. 76 Wu S G, Du C X, Zhou F, et al. Explosion and Impact, 2024, 44 (4), 111 (in Chinese). 吴烁罡, 杜成鑫, 周峰, 等. 爆炸与冲击, 2024, 44(4), 111. 77 Du C X. The penetration mechanism and optimization design of Wf/Zr-based amorphous composite rod bomb. Ph. D. Thesis, Nanjing University of Science and Technology, China, 2020 (in Chinese). 杜成鑫. Wf/Zr基非晶复合材料杆弹准细观侵彻机理及优化设计. 博士学位论文, 南京理工大学, 2020. 78 Dragoi D, stündag E, Clausen B, et al. Scripta Materialia, 2001, 45(2), 245. 79 Wang Z H. Wf/Zr-based block metal glass composites and their high-speed impact behavior. Ph. D. Thesis, Nanjing University of Science and Technology, China, 2006 (in Chinese). 王志华. Wf/Zr基块体金属玻璃复合材料及其高速冲击行为. 博士学位论文, 南京理工大学, 2006. 80 Li J G, Shi Q, Cao J D. Journal of Lanzhou University of Technology, 2012, 38(2), 164 (in Chinese). 李建光, 施琪, 曹结东. 兰州理工大学学报, 2012, 38(2), 164. 81 Xia L X. Study onpenetration behavior of tungsten fiber reinforced bulk metallic glass matrix Composites. Master’s Thesis, Nanjing University of Science and Technology, China, 2014. 夏龙祥. 钨纤维增强块体金属非晶复合材料侵彻行为研究. 硕士学位论文, 南京理工大学, 2014. 82 Li J C, Chen X W, Huang F L. International Journal of Impact Engineering, 2015, 86, 67. 83 Du C, Shu D, Du Z, et al. International Journal of Refractory Metals and Hard Materials, 2019, 85, 105042. 84 Meng Q, Wang Z. Engineering Fracture Mechanics, 2015, 142, 170. 85 Qi F, Ding H, Wang X, et al. Computational Materials Science, 2017, 137, 297. 86 Zheng Y S, Yang W L, Zheng S Q, et al. Weapon Materials Science and Engineering, 2018, 41 (4), 97 (in Chinese). 郑阳升, 杨伟苓, 郑顺奇, 等. 兵器材料科学与工程, 2018, 41(4), 97. 87 Yu Y, Su Y S, Yann B, et al. China Materials Progress, 2020, 39(3), 214 (in Chinese). 俞洋, 苏益士, Yann B, 等. 中国材料进展, 2020, 39(3), 214. 88 Choi-Yim H, Johnson W L. Applied Physics Letters, 1997, 71(26), 3808. 89 Zhuang C K, Ding H P, Ma Y F, et al. Rare Metal Materials and Engineering, 2021, 50(3), 1096 (in Chinese). 庄成康, 丁华平, 马云飞, 等. 稀有金属材料与工程, 2021, 50(3), 1096. 90 Gong P, Yu G Q, Ding H P, et al. Forging Technology, 2021, 46(9), 43 (in Chinese). 龚攀, 余国卿, 丁华平, 等. 锻压技术, 2021, 46(9), 43. 91 Qiu K Q, Ren Y L. Rare Metal Materials and Engineering, 2006, 35(1), 66 (in Chinese). 邱克强, 任英磊. 稀有金属材料与工程, 2006, 35(1), 66 92 Ma Y F. Preparation and properties of tungsten particle reinforced zirco-nium-based amorphous alloy composites. Master’s Thesis, Huazhong University of Science and Technologyy, China, 2019. 马云飞. 钨颗粒增强锆基非晶合金复合材料的制备与性能研究. 硕士学位论文, 华中科技大学, 2019. 93 Li Q. Preparation of Zr-basedamorphous composites by oermeation casting method and their properties research. Master’s Thesis, Shenyang University of Technology, China, 2018 (in Chinese). 李权. 渗流铸造法制备Zr基非晶复合材料及其性能研究. 硕士学位论文, 沈阳工业大学, 2018. 94 Yang X, Lei J X, Lu Q W, et al. Tianjin Metallurgy, 2016(5), 30 (in Chinese). 杨旭, 雷济旭, 路庆伟, 等. 天津冶金, 2016(5), 30. 95 Wu Z, Du P, Xiang T, et al. Intermetallics, 2021, 131, 107105. 96 Cheng I C, Kelly J P, Novitskaya E, et al. Advanced Engineering Materials, 2018, 20(9), 1800023. 97 Monson T C, Zheng B, Delany R E, et al. IEEE Magnetics Letters, 2019, 10, 1. 98 Jeng I K, Lin C K, Lee P Y. Intermetallics, 2006, 14(8-9), 957. 99 Jiang X D. Study on thepreparation and properties of particle reinforced Mg-Zn-Ca amorphous composites. Master’s Thesis, Hebei University of Technology, China, 2016 (in Chinese). 姜旭东. 颗粒增强Mg-Zn-Ca非晶复合材料的制备与性能研究. 硕士学位论文, 河北工业大学, 2016. 100 龚攀, 王新云, 马云飞, 等. 中国专利, CN108220643A, 2018. 101 Liu J Q, Pang J, Wang P, et al. China Metallurgy, 2022, 32(2), 1 (in Chinese). 刘佳奇, 庞靖, 王璞, 等. 中国冶金, 2022, 32(2), 1
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2026, Vol. 40 
