P/N/B协效阻燃剂的合成及在水性丙烯酸涂料中的应用

doi:10.11896/cldb.25030121

材料导报

2026, Vol. 40

Issue (4): 25030121-6 https://doi.org/10.11896/cldb.25030121

高分子与聚合物基复合材料

P/N/B协效阻燃剂的合成及在水性丙烯酸涂料中的应用

兰昊¹, 张强¹, 唐凌君¹, 胡英元¹, 谢凤鸣², 赵鑫^1,*

1 苏州科技大学化学与生命科学学院,江苏苏州 215009
2 苏州大学功能纳米与软物质研究院,江苏省碳基功能材料与器件重点实验室,江苏苏州 215123

Synthesis of P/N/B Synergistic Flame Retardant and Its Application in Aqueous Acrylic Coatings

LAN Hao¹, ZHANG Qiang¹, TANG Lingjun¹, HU Yingyuan¹, Xie Fengmin², ZHAO Xin^1,*

1 School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
2 Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou 215123, Jiangsu, China

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摘要本工作设计合成了一种新型的P/N/B协效阻燃剂PBPO,在表征其结构的基础上,研究了其在水性丙烯酸涂料中的阻燃性能和阻燃机理。研究表明,PBPO加入量为15%(质量分数)时制得的A/PBPO₁₅涂层的极限氧指数(LOI)达28.7%,与空白样相比,其LOI提高36.7%,热释放速率(HRR)降低26.1%,总热释放量(THR)从73.34 MJ/m²降至65.42 MJ/m²。阻燃机理研究表明,PBPO在热解后会生成大量的酸性物质和不燃性气体,促进了脱水炭化和炭层膨胀,同时硼酸热解生成的氧化硼在熔融后会增加炭层厚度和致密性,从而使PBPO表现出优良的协同阻燃性能。

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关键词: 协效阻燃剂合成阻燃性能水性丙烯酸涂料

Abstract: A novel P/N/B synergistic flame retardant PBPO was designed and synthesized. The structure of PBPO was characterized, and its flame-retardantproperties and mechanism in aqueous acrylic coatings were systematically investigated. Results demonstrate that the limiting oxygen index (LOI) of the A/PBPO₁₅ coating with 15wt% PBPO reached 28.7%, representing 36.7% increase, compared to the neat sample, and the heat release rate (HRR) decreased by 26.1%, the total heat release (THR) was reduced from 73.34 MJ/m² to 65.42 MJ/m². The investigation of flame-retardant mechanism indicates PBPO generates substantial abundant acidic substances and non-flammable gases during pyrolysis, promoting dehydration carbonization and carbon layer expansion. Meanwhile, boron oxide formed by thermal decomposition of boric acid enhances the thickness and density of the char layer through melting, thereby exhibiting excellent synergistic flame-retardant properties.

Key words: synergistic flame retardant synthesis flame-retardant properties aqueous acrylic coatings

出版日期: 2026-02-25 发布日期: 2026-02-13

ZTFLH:

TB332

基金资助: 国家自然科学基金(21905048;52303244);江苏省研究生研究创新项目(KYCX24_3462)

通讯作者: * 赵鑫,硕士,苏州科技大学教授、硕士研究生导师。目前主要从事有机功能材料的设计、合成及应用等方面的研究。zhaoxinsz@usts.edu.cn

作者简介: 兰昊,苏州科技大学化学与生命科学学院硕士研究生,师从赵鑫教授,开展水性丙烯酸阻燃材料的合成与性能的科研。

引用本文:

兰昊, 张强, 唐凌君, 胡英元, 谢凤鸣, 赵鑫. P/N/B协效阻燃剂的合成及在水性丙烯酸涂料中的应用[J]. 材料导报, 2026, 40(4): 25030121-6.
LAN Hao, ZHANG Qiang, TANG Lingjun, HU Yingyuan, Xie Fengmin, ZHAO Xin. Synthesis of P/N/B Synergistic Flame Retardant and Its Application in Aqueous Acrylic Coatings. Materials Reports, 2026, 40(4): 25030121-6.

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https://www.mater-rep.com/CN/10.11896/cldb.25030121 或 https://www.mater-rep.com/CN/Y2026/V40/I4/25030121

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